Citation: YI Wen-Hai, HU Jun-Jie, ZHANG Jia-Li, WEN He-Rui, LIU Sui-Jun, LI Yun-Wu. Dy(Ⅲ) and Zn/Ni-Dy(Ⅲ) Complexes Derived from Polyamine Phenol Ligand with Slow Magnetic Relaxation and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 607-619. doi: 10.11862/CJIC.2020.085 shu

Dy(Ⅲ) and Zn/Ni-Dy(Ⅲ) Complexes Derived from Polyamine Phenol Ligand with Slow Magnetic Relaxation and Luminescent Properties

YI Wen-Hai ¹ ,
HU Jun-Jie ¹ ,
ZHANG Jia-Li ¹ ,
WEN He-Rui ^1,2,, ,
LIU Sui-Jun ^1,, ,
LI Yun-Wu ^3,,

1.
School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China
2.
School of Chemistry and Chemical Engineering, Jinggangshan University, Ji'an, Jiangxi 343009, China
3.
School of Chemistry and Chemical Engineering, Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng, Shandong 252000, China

Corresponding author: WEN He-Rui, wenherui63@163.com LIU Sui-Jun, sjliu@jxust.edu.cn LI Yun-Wu, lyw5251851@163.com
Received Date: 25 August 2019
Revised Date: 13 January 2020

Figures(10)

Four Dy(Ⅲ) and Zn/Ni-Dy(Ⅲ) complexes with polyamine phenol ligand were synthesized and structurally characterized, namely[Dy(CH₃OCH₃)L] (1), [Dy₂(μ-H₂O)L₂] (2), [Zn₂DyL₂]ClO₄·H₂O (3) and[Ni₂DyL₂]ClO₄·H₂O (4) (H₃L=N, N', N″-tris(3, 5-dimethyl-2-hydroxybenzyl)-1, 4, 7-triazacyclononane). X-ray crystallographic analysis reveals that 1 and 2 take mononuclear and binuclear structures, respectively, and both 3 and 4 take trinuclear M-Dy(Ⅲ)-M structures (M=Zn (3), Ni (4)). Magnetic measurements showed that complexes 1 and 2 exhibited field-induced slow magnetic relaxation behaviours, while 2 had multiple magnetic relaxation processes. However, no obvious slow magnetic relaxation behaviors were observed in 3 and 4. Fluorescence analyses reveal that complexes 1~3 have narrow-band characteristic emissions of Dy(Ⅲ) ions, but no significant emission was observed in 4 because of the fluorescence quenching effect of Ni(Ⅱ) ions.
- lanthanide complex,
- slow magnetic relaxation,
- luminescence,
- magnetic-luminescent material
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沈阳化工大学材料科学与工程学院沈阳 110142