Citation: LU Yang, WANG Jing, SHI Zhong-Xiang, DAI Li-Jing, ZHANG Hong-Ming, SUN Zi-Ting, LIU Yong-Fu. Preparation and Upconversion Luminescence Properties of MgAl₂O₄: Er³⁺, Yb³⁺ Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 688-694. doi: 10.11862/CJIC.2020.075 shu

Preparation and Upconversion Luminescence Properties of MgAl₂O₄: Er³⁺, Yb³⁺ Phosphors

1.
Liaoning Key Laboratory for Fabrication and Application of Superfine Inorganic Powders, Dalian Jiaotong University, Dalian, Liaoning 116028, China
2.
Department of Materials Science and Engineering, Yingkou Institude of Technology, Yingkou, Liaoning 115014, China

Corresponding author: WANG Jing, wangjing@djtu.edu.cn
Received Date: 22 October 2019
Revised Date: 17 January 2020

Figures(9)

MgAl₂O₄:Er³⁺, Yb³⁺ upconversion phosphors was prepared by low-temperature hydrothermal method combined with calcination process and using urea as precipitant. The crystal structure, morphology and upconversion luminescence properties of the samples were investigated. The results show that the main morphology of the product changed from hexagonal flake structure to nanorod-like structure with the increase of urea content. Pure phase of Mg-Al spinel structure can be obtained after calcinating at 1 100℃. Er³⁺ and Yb³⁺ can enter into MgAl₂O₄ lattice effectively and occupy Mg²⁺ sites to form homogeneous solid solution. MgAl₂O₄:1.0%(n/n)Er³⁺, x%(n/n)Yb³⁺ (x=0~8.0) phosphors show green (524 and 545 nm) and strong red (658 nm) light emission under 980 nm laser diode excitation, the red and green light intensity reached the maximum at 5.0%(n/n)Yb³⁺ doping, but the intensity ratio of red light vs green light reached the maximum value of 5.2 at 7.0%(n/n)Yb³⁺ doping, which is attributed to the major role of cross relaxation (CR) between Er³⁺ and Er³⁺ in red light emission process. The color-tunable of yellow-green light can be realized basically by adjusting the doping content of Yb³⁺ in the phosphor.
- MgAl₂O₄:Er³⁺, Yb³⁺,
- low-temperature hydrothermal method,
- upconversion,
- cross relaxation
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Upconversion Luminescence Properties of MgAl2O4: Er3+, Yb3+ Phosphors

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通讯作者: 陈斌, bchen63@163.com

Preparation and Upconversion Luminescence Properties of MgAl₂O₄: Er³⁺, Yb³⁺ Phosphors