Citation: ZHONG Qin-Yue, LIU Yao, LIU Xin-Mei, ZHANG Wen-Kang, WANG Hai-Bo. Preparation and Photocatalytic Performance of CdS@g-C₃N₄ Core-Shell Composite Nanoparticles[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 864-874. doi: 10.11862/CJIC.2020.074 shu

Preparation and Photocatalytic Performance of CdS@g-C₃N₄ Core-Shell Composite Nanoparticles

School of Biological and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou, Guangxi 545006, China

Corresponding author: LIU Xin-Mei, xinmeiliu628@163.com
Received Date: 6 December 2019
Revised Date: 17 February 2020

Figures(16)

The CdS@g-C₃N₄ core-shell composite nanoparticles were successfully prepared by a hydrothermal method with the addition of ethylenediamine and EDTA-2Na. The nucleation and growth mechanism of CdS@g-C₃N₄ was also discussed. The specific surface area of CdS@g-C₃N₄ core-shell composite nanoparticles was 14 times larger than that of the pure CdS nanoparticles. CdS@g-C₃N₄, which was prepared under the reaction conditions of 180℃, 4 h and 1.9:1 (the mass ratio of CdS to g-C₃N₄), exhibited the best catalytic performance. The degradation efficiency of RhB with CdS@g-C₃N₄ composite reached 95.2% after 2 h of irradiation under 300 W xenon, which was significantly higher than that over pure CdS. After three cycles, CdS@g-C₃N₄ showed no obvious changes in the morphology, structure and photocatalytic performance.
- CdS,
- g-C₃N₄,
- nanohybrids,
- photocatalytic activity,
- rhodamine B
1. [1]
  ZHAO Xiao-Hua, SU Shuai, WU Guang-Li, et al. Chinese J. Inorg. Chem., 2017, 33(2):276-284
2. [2]
  Su J Z, Zhang T, Wang L, et al. Chin. J. Catal., 2017, 38(3):489-497
3. [3]
  Wang Z Y, Chen J X, Zhang F A, et al. Rare Met. Mater. Eng., 2008, 37(2):330-333
4. [4]
  Liu L, Hu P R, Cui W Q, et al. Int. J. Hydrogen Energy., 2017, 42(27):17435-17445 doi: 10.1016/j.ijhydene.2017.02.171
5. [5]
  LANG Di(郎笛). Thesis for the Doctorate of Huazhong Agricultural University(华中农业大学博士论文). 2016.
6. [6]
  Li X Y, Peng K. Appl. Clay Sci., 2018, 165:188-196 doi: 10.1016/j.clay.2018.08.017
7. [7]
  PAN Jin-Bo, LIU Jian-Jun, MA He-Cheng, et al. Chinese J. Inorg. Chem., 2018, 34(8):1421-1429
8. [8]
  WANG Xiao-Xue, GAO Jian-Ping, ZHAO Rui-Ru, et al. Chinese J. Inorg. Chem., 2018, 34(6):1059-1064
9. [9]
  LI Cao-Long, ZHAO Yu-Ting, CAO Fei, et al. Chinese J. Inorg. Chem., 2013, 29(12):2535-2542
10. [10]
  LI Na, WANG Ming, ZHAO Bei-Ping, et al. Chinese J. Inorg. Chem., 2016, 32(6):1033-1040
11. [11]
  Wang D K, Zeng H, Xiong X, et al. Sci. Bull. https://doi.org/10.1016/j.scib.2019.10.015.
12. [12]
  Zhou G, Zheng L L, Wang D K, et al. Chem. Commun., 2019, 55:4150-4153 doi: 10.1039/C9CC01161G
13. [13]
  Wang D K, Ye P, Li K L, et al. Appl. Catal. B, 2020, 260:118182-118191 doi: 10.1016/j.apcatb.2019.118182
14. [14]
  Wang D K, Li X, Zheng L L, et al. Nanoscale, 2018, 10:19509-19516 doi: 10.1039/C8NR06691D
15. [15]
  Yin C C, Cui L F, Pu T T, et al. Appl. Surf. Sci., 2018, 456:464-472 doi: 10.1016/j.apsusc.2018.06.137
16. [16]
  Li Y, Wei X, Li H, et al. RSC Adv., 2015, 5(19):14074-14080 doi: 10.1039/C4RA14690E
17. [17]
  WANG Zhi-Ping, ZHAO Jing, WANG Ke-Zhen. Acta Energiae Solaris Sinica, 2013, 34(8):1311-1316 doi: 10.3969/j.issn.0254-0096.2013.08.002
18. [18]
  SHEN Qian-Qian, TIAN Bin, XUE Jin-Bo, et al. Chinese J. Inorg. Chem., 2014, 30(8):1839-1844
19. [19]
  Chen D Y, Ji G, Ma Y, et al. ACS Appl. Mater. Interfaces, 2011, 3(8):3078-3083 doi: 10.1021/am200592r
20. [20]
  Wang H Y, Gong R, Qian X L. J. Membr. Sci., 2018, 8(1):14-21
21. [21]
  Kumar S, Baruah A, Tonda S, et al. Nanoscale, 2014, 6:4830-4843 doi: 10.1039/c3nr05271k
22. [22]
  WANG Yi-Lin, HUANG Xiao-Feng, LU Jian-Ping. Journal of Guangxi University:Natural Science Edition, 2007, 32(2):147-149, 162
23. [23]
  BAO Shu-Fen. Journal of Liaoning University, 2010, 37(2):148-151 doi: 10.3969/j.issn.1000-5846.2010.02.014
24. [24]
  Fu J, Chang B B, Tian Y L, et al. J. Mater. Chem. A, 2013, 1:3083-3090 doi: 10.1039/c2ta00672c
25. [25]
  Yang S B, Gong Y J, Zhang J S, et al. Adv. Mater., 2013, 25:2452-2456 doi: 10.1002/adma.201204453
26. [26]
  Dong F, Wu L W, Sun Y J, et al. J. Mater. Chem., 2011, 21:15171-15174 doi: 10.1039/c1jm12844b
27. [27]
  Muhammad A, Li Q Y, Yao J C, et al. J. Environ. Chem. Eng., 2017, 5(6):5358-5368 doi: 10.1016/j.jece.2017.10.024
28. [28]
  Zhang S L, Hang N T, Zhang Z J, et al. J. Nanomater., 2017, 7(1):76-86
29. [29]
  ZHANG Li, LIANG Qing-Man, DAI Chao-Hua, et al. The Chinese Journal of Nonferrous Metals, 2018, 28(7):1335-1342
30. [30]
  GAO Ning, GUO Fan, ZHENG Wei-Wei, et al. Journal of Synthetic Crystals, 2005, 4:632-636
31. [31]
  LI Jiao-Jiao, ZHAO Wei-Feng, ZHANG Gai, et al. Chem. J. Chin. Univ., 2018, 39(12):2719-2724 doi: 10.7503/cjcu20180460
32. [32]
  Li Z, Zhou Z, Ma J W, et al. Appl. Catal. B, 2018, 237:288-294 doi: 10.1016/j.apcatb.2018.05.087
33. [33]
  Zou S, Fu Z H, Xiang C, et al. Chin. J. Catal., 2015, 36(7):1077-1085 doi: 10.1016/S1872-2067(15)60827-0
34. [34]
  ZHANG Wen-Kang, LIANG Yan-Yi, LIU Yao, et al. Journal of Guangxi University of Science and Technology, 2018, 29(4):66-73
35. [35]
  Zhang H G, Fen L J, Li C H, et al. J. Fuel Cell Sci., 2018, 46(7):871-878
36. [36]
  LIANG Hong-Yu, ZOU He, HU Shao-Zheng, et al. Journal of Molecular Catalysis, 2018, 32(2):152-162
37. [37]
  JIANG Jian-Gang, REN Wen-Yi, LI Xia, et al. Semiconductor Optoelectornics, 2019, 40(1):82-87
38. [38]
  Chong B, Chen L, Han D Z, et al. Chin. J. Catal., 2019, 40(6):959-968
39. [39]
  Liu X M, Huang W Y, Huang G X, et al. Ceram. Int., 2015, 41:11710-11718
40. [40]
  Yu H, Chen F Y, Chen F, et al. Appl. Surf. Sci., 2015, 6:86-91
41. [41]
  ZHAN Hong-Quan, DENG Ce, WU Chuan-Qi, et al. Journal of Synthetic Crystals, 2019, 48(2):190-195
42. [42]
  Bai Z M, Yan X Q, Li Y, et al. Adv. Energy Mater., 2016, 6(3):1459-1501
43. [43]
  XIONG Jian, HE Lu-Ying. Chinese Journal of Vacuum Science and Technology, 2017, 37(12):1160-1165
44. [44]
  Cui Y J, Ding Z X, Liu P. Phys. Chem. Chem. Phys., 2012, 14(4):1455-1462
45. [45]
  Wang X, Maeda K, Thomas A. Nat. Mater., 2009, 8(1):76-80
46. [46]
  Liu X M, Jiang Y, Guo W M, et al. Chem. Eng. J., 2013, 5(7):466-474
47. [47]
  ZHOU Wen-Jun, SHEN Bo-Xiong, ZHANG Qin, et al. Journal of Fuel Chemistry and Technology, 2019, 47(2):249-256
48. [48]
  HAO Yan-Zhong, CAO Yin-Hu, SUN Bao, et al. Acta Chim. Sinica, 2012, 70(10):1139-1144
49. [49]
  Long J, Liu H L, Wu S J, et al. ACS Catal., 2013, 3(4):647-654
1. [1]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
2. [2]
  Kaihui Huang , Boning Feng , Xinghua Wen , Lei Hao , Difa Xu , Guijie Liang , Rongchen Shen , Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204
3. [3]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
4. [4]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
5. [5]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
6. [6]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
7. [7]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
8. [8]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
9. [9]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
10. [10]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
11. [11]
  Deqi Fan , Yicheng Tang , Yemei Liao , Yan Mi , Yi Lu , Xiaofei Yang . Two birds with one stone: Functionalized wood composites for efficient photocatalytic hydrogen production and solar water evaporation. Chinese Chemical Letters, 2024, 35(9): 109441-. doi: 10.1016/j.cclet.2023.109441
12. [12]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
13. [13]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
14. [14]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
15. [15]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
16. [16]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
17. [17]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
18. [18]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
19. [19]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
20. [20]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1274)
HTML views(133)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Performance of CdS@g-C3N4 Core-Shell Composite Nanoparticles

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Performance of CdS@g-C₃N₄ Core-Shell Composite Nanoparticles