Citation: WANG Rui-Yu, LIU Ya-Li, FAN Xing, WEI Xian-Yong. Copper Supported Mesoporous Carbon Cu/CMK-3 for Catalytic Oxy-carbonylation of Methanol in Vapor Phase[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 769-776. doi: 10.11862/CJIC.2020.070 shu

Copper Supported Mesoporous Carbon Cu/CMK-3 for Catalytic Oxy-carbonylation of Methanol in Vapor Phase

1.
Low Carbon Energy Institute, China University of Mining & Technology, Xuzhou, Jiangsu 221006, China
2.
Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining & Technology, Xuzhou, Jiangsu 221116, China

Corresponding author: FAN Xing, fanxing@cumt.edu.cn
Received Date: 1 November 2019
Revised Date: 5 January 2020

Figures(6)

Ordered mesoporous carbon CMK-3 was synthesized via the nanocasting route, and used to prepare Cu/CMK-3 catalyst for dimethyl carbonate (DMC) synthesis by oxidative carbonylation of methanol in a gas-phase reaction. The effect of activation temperature on the catalyst structure and catalytic performance were investigated. N₂ adsorption-desorption, X-ray diffraction (XRD) and transmission electron microscopy (TEM) results revealed that the Cu/CMK-3 catalysts were mesoporous, the active copper species dispersed well in the surface and pore channels of CMK-3, their diameter were between 10~20 nm, far less than that of Cu/activated carbon (Cu/AC). The corresponding catalytic activity in a fixed-bed reactor increased with the activation temperature and the Cu/CMK-3 catalyst prepared at 450℃ exhibited the best catalytic activity. The space time yield (STY) was 286 mg·g^-1·h^-1 and the selectivity for DMC was 76% in 10 h running. A long periodic test also confirmed a better catalytic stability of Cu/CMK-3 compared to Cu/AC, the STY of DMC declined by 20% after 50 h reaction and 28% after 75 h reaction.
- heterogeneous catalysis,
- supported catalysts,
- nanocasting,
- mesoporous Cu/CMK-3,
- dimethyl carbonate,
- methanol,
- oxidative carbonylation
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沈阳化工大学材料科学与工程学院沈阳 110142