Citation: WANG Rui-Yu, LIU Ya-Li, FAN Xing, WEI Xian-Yong. Copper Supported Mesoporous Carbon Cu/CMK-3 for Catalytic Oxy-carbonylation of Methanol in Vapor Phase[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 769-776. doi: 10.11862/CJIC.2020.070 shu

Copper Supported Mesoporous Carbon Cu/CMK-3 for Catalytic Oxy-carbonylation of Methanol in Vapor Phase

1.
Low Carbon Energy Institute, China University of Mining & Technology, Xuzhou, Jiangsu 221006, China
2.
Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining & Technology, Xuzhou, Jiangsu 221116, China

Corresponding author: FAN Xing, fanxing@cumt.edu.cn
Received Date: 1 November 2019
Revised Date: 5 January 2020

Figures(6)

Ordered mesoporous carbon CMK-3 was synthesized via the nanocasting route, and used to prepare Cu/CMK-3 catalyst for dimethyl carbonate (DMC) synthesis by oxidative carbonylation of methanol in a gas-phase reaction. The effect of activation temperature on the catalyst structure and catalytic performance were investigated. N₂ adsorption-desorption, X-ray diffraction (XRD) and transmission electron microscopy (TEM) results revealed that the Cu/CMK-3 catalysts were mesoporous, the active copper species dispersed well in the surface and pore channels of CMK-3, their diameter were between 10~20 nm, far less than that of Cu/activated carbon (Cu/AC). The corresponding catalytic activity in a fixed-bed reactor increased with the activation temperature and the Cu/CMK-3 catalyst prepared at 450℃ exhibited the best catalytic activity. The space time yield (STY) was 286 mg·g^-1·h^-1 and the selectivity for DMC was 76% in 10 h running. A long periodic test also confirmed a better catalytic stability of Cu/CMK-3 compared to Cu/AC, the STY of DMC declined by 20% after 50 h reaction and 28% after 75 h reaction.
- heterogeneous catalysis,
- supported catalysts,
- nanocasting,
- mesoporous Cu/CMK-3,
- dimethyl carbonate,
- methanol,
- oxidative carbonylation
1. [1]
  Ferrer B, Alvaro M, Garcia H. Green Solvents I. Dordrecht:Springer, 2012:363-374
2. [2]
  Ono Y. Appl. Catal. A, 1997, 155:133-166 doi: 10.1016/S0926-860X(96)00402-4
3. [3]
  Huang S Y, Yan B, Wang S P, Ma X B. Chem. Soc. Rev., 2015, 44:3079-3116 doi: 10.1039/C4CS00374H
4. [4]
  Pacheco M A, Marshall C L. Energy Fuels, 1997, 11:2-29 doi: 10.1021/ef9600974
5. [5]
  Itoh H, Watanabe Y, Mori K, et al. Green Chem., 2003, 5:558-562 doi: 10.1039/B304618B
6. [6]
  Tomishige K, Sakaihori T, Sakai S I, et al. Appl. Catal. A, 1999, 181:95-102 doi: 10.1016/S0926-860X(98)00386-X
7. [7]
  Wang Y J, Zhao X Q, Yuan B G, et al. Appl. Catal. A, 1998, 171:255-260 doi: 10.1016/S0926-860X(98)00078-7
8. [8]
  Jiang R X, Wang S F, Zhao X Q, et al. Appl. Catal. A, 2003, 238:131-139 doi: 10.1016/S0926-860X(02)00345-9
9. [9]
  LI Zhong, WEN Chun-Mei, WANG Rui-Yu, et al. Chem. J. Chinese Univeristies, 2009, 30:2024-2031 doi: 10.3321/j.issn:0251-0790.2009.10.021
10. [10]
  Wang R Y, Li Z, Zheng H Y, et al. Chin. J. Catal., 2010, 31:851-856
11. [11]
  Yan B, Huang S Y, Wang S P, et al. ChemCatChem, 2014, 6:2671-2679 doi: 10.1002/cctc.201402201
12. [12]
  Ren J, Guo C J, Yang L L, et al. Chin. J. Catal., 2013, 34:1734-1744 doi: 10.1016/S1872-2067(12)60640-8
13. [13]
  Zheng H Y, Qin Y, Li Z, et al. Chin. J. Inorg. Chem., 2014, 30:2111-2118
14. [14]
  LI Zhong, WEN Chun-Mei, ZHENG Hua-Yan, et al. Chem. J. Chinese Universities, 2010, 31:145-152
15. [15]
  Zhang G J, Li Z, Zheng H Y, et al. Appl. Surf. Sci., 2016, 390:68-77 doi: 10.1016/j.apsusc.2016.08.054
16. [16]
  Shi K, Huang S Y, Zhang Z Y, et al. Chin. Chem. Lett., 2017, 28:70-74 doi: 10.1016/j.cclet.2016.06.005
17. [17]
  Yuan Y Z, Cao W, Weng W Z. J. Catal., 2004, 228:311-320 doi: 10.1016/j.jcat.2004.09.003
18. [18]
  Yao X J, Chen Y. Chin. J. Catal., 2013, 34:851-864 doi: 10.1016/S1872-2067(12)60592-0
19. [19]
  Ndamanisha J C, Guo L P. Anal. Chim. Acta, 2012, 747:19-28 doi: 10.1016/j.aca.2012.08.032
20. [20]
  Eftekhari A. Microporous Mesoporous Mater., 2017, 243:355-369 doi: 10.1016/j.micromeso.2017.02.055
21. [21]
  Taguchi A, Schüth F. Microporous Mesoporous Mater., 2005, 77:1-45 doi: 10.1016/j.micromeso.2004.06.030
22. [22]
  Jun S, Joo S H, Ryoo R, et al. J. Am. Chem. Soc., 2000, 122:10712-10713 doi: 10.1021/ja002261e
23. [23]
  Ryoo R, Joo S H, Kruk M, et al. Adv. Mater., 2001, 13:677-681 doi: 10.1002/1521-4095(200105)13:9<677::AID-ADMA677>3.0.CO;2-C
24. [24]
  Shi Y W, Zhang X W, Liu G Z. Fuel, 2015, 158:565-571 doi: 10.1016/j.fuel.2015.06.013
25. [25]
  Li X A, Forouzandeha F, Fürstenhauptc T, et al. Carbon, 2018, 127:707-717 doi: 10.1016/j.carbon.2017.11.049
26. [26]
  Zhao D Y. Science, 1998, 279:548-552 doi: 10.1126/science.279.5350.548
27. [27]
  Saini V K, Andrade M, Moisés L, et al. Sep. Purif. Technol., 2010, 75:366-376 doi: 10.1016/j.seppur.2010.09.006
28. [28]
  Wegrzyniak A, Jarczewski S, Wach A, et al. Appl. Catal. A, 2015, 508:1-9 doi: 10.1016/j.apcata.2015.10.002
29. [29]
  Radhakrishnan R, Thiripuranthagan S, Devarajan A, et al. Appl. Catal. A, 2017, 545:33-43 doi: 10.1016/j.apcata.2017.07.031
30. [30]
  LI Wen, ZHOU Jin, XING Wei, et al. Acta Phys-Chim. Sin., 2011, 27:620-626 doi: 10.3866/PKU.WHXB20110331
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