Citation: LAI Chu-Jun, REN Xiao-Xu, HE Tian-Qu, YUE Lin-Hai, HOU Zhao-Yin. Synthesis and Application in Degradation of Rhodamine B of Layered Cu_yFe_6-yAl₂O_x Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(3): 451-457. doi: 10.11862/CJIC.2020.057 shu

Synthesis and Application in Degradation of Rhodamine B of Layered Cu_yFe_6-yAl₂O_x Catalysts

Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemistry, Zhejiang University, Hangzhou 310028, China

Corresponding author: HOU Zhao-Yin, zyhou@zju.edu.cn
Received Date: 3 September 2019
Revised Date: 21 December 2019

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A series of layered Cu_yFe_6-yAl₂O_x catalysts were prepared via the controlled calcination of Cu_yFe_6-yAl₂-LDH and applied in the Fenton degradation reaction of high concentrated rhodamine B (RhB, 450 mg·L^-1) under neutral conditions at room temperature. It was found that Cu₅FeAl₂O_x-500, which was prepared at a calcination temperature of 500℃, was most active for the degradation RhB. Over Cu₅FeAl₂O_x-500 catalyst (with 0.1%(w/w) loading), RhB could be completely degraded within 150 min, and the chemical oxygen demand (COD) removal efficiency reached 86.5%. The characterizations indicated that both Cu and Fe have a good synergistic effect for the degradation reaction as the formation of CuFe₂O₄. At the same time, the catalyst with larger specific surface area and bigger pore volume was also favorable for the degradation of RhB and COD removal. It was also confirmed that Cu₅FeAl₂O_x-500 catalyst was capable for the degradation of a variety of pollutants.
- Fenton reaction,
- hydrotalcite,
- copper iron catalyst,
- degradation of pollutants,
- acidity
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Synthesis and Application in Degradation of Rhodamine B of Layered CuyFe6-yAl2Ox Catalysts

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Synthesis and Application in Degradation of Rhodamine B of Layered Cu_yFe_6-yAl₂O_x Catalysts