Citation: CHEN Li-Ya, CHENG Gao, LIU Guan-Liang, HAN Jia-Xi, FU Shu-Chai, HAN Sheng-Bo, SUN Ming, LAN Bang, YU Lin. Structure-Activity Relationship of Three-Dimensional Urchin-like MnO₂ Microspheres with Different Crystalline Phases for Oxygen Reduction Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(3): 458-466. doi: 10.11862/CJIC.2020.048 shu

Structure-Activity Relationship of Three-Dimensional Urchin-like MnO₂ Microspheres with Different Crystalline Phases for Oxygen Reduction Reaction

School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

Corresponding author: YU Lin, gych@gdut.edu.cn
Received Date: 14 October 2019
Revised Date: 6 December 2019

Figures(8)

Urchin-like MnO₂ microspheres with three different crystalline phases (α, γ and β) were prepared by hydrothermal and calcination methods, and the oxygen reduction reaction (ORR) properties were systematically studied. The results of electrocatalytic tests indicated that the ORR activities of these three MnO₂ microspheres followed a sequence:α-MnO₂ > γ-MnO₂ > β-MnO₂. The α-MnO₂ sample exhibited the best electrocatalytic performance towards ORR with an onset potential of 0.92 V (vs RHE) and a potential of 0.77 V (vs RHE) at -3 mA·cm^-2. The superior ORR activity of urchin-like α-MnO₂ microspheres was mainly related to the larger amount of Mn³⁺, more surface oxygen vacancies and better conductivity. Specially, the Mn³⁺ could promote the dissociation of O-O bond and conduce to one-electron transfer to adsorbed oxygen, thereby accelerating the exchange of O₂^2-/OH^- that regarded as the rate-limiting step of the ORR.
- oxygen reduction reaction,
- urchin-like MnO₂ microspheres,
- structure-activity relationships,
- electrochemistry
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Structure-Activity Relationship of Three-Dimensional Urchin-like MnO2 Microspheres with Different Crystalline Phases for Oxygen Reduction Reaction

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通讯作者: 陈斌, bchen63@163.com

Structure-Activity Relationship of Three-Dimensional Urchin-like MnO₂ Microspheres with Different Crystalline Phases for Oxygen Reduction Reaction