Citation: QIN Meng-Na, WANG Li-Dong, CHENG Mei-Ling, LIU Lu, LIU Qi, TANG Xiao-Yan. Syntheses, Crystal Structures and Luminescent Properties of Zn(Ⅱ) Complexes Based on 3, 4-Pyrazoledicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(3): 529-535. doi: 10.11862/CJIC.2020.046 shu

Syntheses, Crystal Structures and Luminescent Properties of Zn(Ⅱ) Complexes Based on 3, 4-Pyrazoledicarboxylic Acid

QIN Meng-Na ¹ ,
WANG Li-Dong ¹ ,
CHENG Mei-Ling ^1,, ,
LIU Lu ¹ ,
LIU Qi ^1,2 ,
TANG Xiao-Yan ^1,3

1.
School of Petrochemical Engineering, and Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou, Jiangsu 213164, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China
3.
School of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, Jiangsu 215500, China

Corresponding author: CHENG Mei-Ling, chengmeiling01@163.com
Received Date: 14 August 2019
Revised Date: 8 November 2019

Figures(2)

Treatment of H₃pdc with Zn(NO₃)₂·6H₂O under different reaction conditions afforded two complexes, [Zn(H₂pdc)₂(H₂O)₂]·2H₂O (1) and[Zn₂(Hpdc)₂(H₂O)₆]·2H₂O (2) (H₃pdc=3, 4-pyrazoledicarboxylic acid). X-ray diffraction analyses reveal that 1 and 2 contain mono-and dinuclear Zn(Ⅱ) components, respectively. The partly deprotonated H₃pdc ligand anions in 1 and 2 adopt N, O-chelating fashion (H₂pdc^-) and μ₂-κN, O:κN' bridging mode (Hpdc^2-), respectively. In both complexes, the adjacent zero-dimensional components are connected by intermolecular hydrogen bonds (O-H…O, N-H…O and C-H…O) to form a three-dimensional supramolecular architecture. The thermal and luminescent properties of complexes 1 and 2 have also been investigated.
- zinc(Ⅱ),
- 3, 4-pyrazoledicarboxylic acid,
- crystal structure,
- luminescent property,
- synthesis
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