Citation: TANG Quan, SHAN Gui-Qian, WANG Xin-Yue, WANG Shu-Tong, WANG Ju-Qi, CHEN Bin, LIANG Li-Li, CHEN Ming-Gong. Butterfly-Shaped Monomers: Syntheses, Structures and Sensing of Harmful Ions in Aqueous Solution[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 201-209. doi: 10.11862/CJIC.2020.039 shu

Butterfly-Shaped Monomers: Syntheses, Structures and Sensing of Harmful Ions in Aqueous Solution

Department of Pharmaceutical Engineering, Bengbu Medical College, Bengbu, Anhui 233030, China

Corresponding author: LIANG Li-Li, liangjyt@163.com CHEN Ming-Gong, mgchen@aust.edu.cn
Received Date: 19 September 2019
Revised Date: 25 November 2019

Figures(10)

Solvothermal syntheses of benzimidazyl ligand(H₂L) with zinc and nickel ions resulted in two monomeric complexes, [Ni(HL)(HCOO)(H₂O)] (1) and[Zn(H₂L)(H₂O)₂](NO₃)₂ (2). The two monomeric complexes are butterfly-shaped, which are further connected into 2D or 3D networks through intermolecular hydrogen bonds. The two monomers are stable in aqueous solution and slight soluble in water. Fluorescence measurements showed that complex 2 had strong fluorescence properties in both solid state and aqueous solutions. A further study shows that both metal ion Hg²⁺ and anion Cr₂O₇^2- have high fluorescence quenching effect on in aqueous solution of 2, indicating that 2 could be used as a highly selective and sensitive detection probe for Hg²⁺ and Cr₂O₇^2-.
- crystal structure,
- complex,
- luminescence,
- chemical sensor
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