Citation: LIU Shun-Qiang, XIE Ming-Jiang, GUO Xue-Feng, JI Wei-Jie. Preparation and Photocatalytic Degradation of Methylene Blue of Hierarchical Mixed-Phase Urchin-like TiO₂ Hollow Spheres[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 317-323. doi: 10.11862/CJIC.2020.037 shu

Preparation and Photocatalytic Degradation of Methylene Blue of Hierarchical Mixed-Phase Urchin-like TiO₂ Hollow Spheres

1.
Department of Medicine and Chemical Engineering, Lianyungang Technical College, Lianyungang, Jiangsu 222006, China
2.
Key Laboratory of Mesoscopic Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: JI Wei-Jie, jiwj@nju.edu.cn
Received Date: 9 September 2019
Revised Date: 14 December 2019

Figures(10)

Hierarchical urchin-like TiO₂ hollow spheres comprising rutile phase of thorn and anatase phase of hollow shell was synthesized via a simple H₂O₂ assisted hydrothermal method. The effects of the pH value of preparation medium and the hydrothermal treatment time on the resulting TiO₂ morphology and structure were systematically investigated. The density of the thorns on the surface of hollow spheres can be effectively modified by tuning the pH value of preparation medium. A possible growth mechanism of the hierarchical structure was proposed. Photocatalytic degradation of methylene blue over the obtained TiO₂ hollow spheres with different density of rutile thorn was explored. It was revealed that the TiO₂ hollow spheres with less thorns outperformed the well-known photocatalyst P25-TiO₂, and were much better than the TiO₂ hollow spheres with more thorns and the smooth TiO₂ hollow spheres.
- inorganic nonmetallic materials,
- hydrothermal method,
- photocatalysis,
- titanium dioxide,
- methylene blue,
- mixed-phase,
- hollow sphere
1. [1]
  Montazer M, Pakdel E, Behzadnia A. J. Appl. Polym. Sci., 2011, 121:3407-3413 doi: 10.1002/app.33858
2. [2]
  Boercker J E, Enache-Pommer E, Aydil E S. Nanotechnology, 2008, 19(9):095604(10 pages) doi: 10.1088/0957-4484/19/9/095604
3. [3]
  Chen J S, Tan Y L, Li C M, et al. J. Am. Chem. Soc., 2010, 132(17):6124-6130 doi: 10.1021/ja100102y
4. [4]
  Wang C X, Yin L W, Zhang L Y, et al. Langmuir, 2010, 26(15):12841-12848 doi: 10.1021/la100910u
5. [5]
  Paul T, Miller P L, Strathmann T. J. Environ. Sci. Technol., 2007, 41(13):4720-4727 doi: 10.1021/es070097q
6. [6]
  Bai X L, Xie B, Pan N, et al. J. Solid State Chem., 2008, 181(3):450-456 doi: 10.1016/j.jssc.2007.12.019
7. [7]
  Zhang Y C, Yang M, Zhang G, et al. Appl. Catal. B, 2013, 142-143:249-258 doi: 10.1016/j.apcatb.2013.05.023
8. [8]
  Zhang Y C, Li J, Xu H Y. Appl. Catal. B, 2012, 123-124:18-26 doi: 10.1016/j.apcatb.2012.04.018
9. [9]
  Ho W, Yu J C, Lee S. Chem. Commun., 2006, 10:1115-1117
10. [10]
  Han S J, Choi S H, Kim S S, et al. Small, 2005, 1:812-816 doi: 10.1002/smll.200400142
11. [11]
  Kondo Y, Yoshikawa H, Awaga K, et al. Langmuir, 2008, 24:547-550 doi: 10.1021/la702157r
12. [12]
  Ohno T, Sarukawa K, Tokieda K, et al. J. Catal., 2001, 203(1):82-86 doi: 10.1006/jcat.2001.3316
13. [13]
  Hou H, Shang M H, Wang L, et al. Sci. Rep., 2015, 5:15228(9 pages)
14. [14]
  Shen Q, Katayama K, Sawada T, et al. Chem. Phys. Lett., 2006, 419:464-468 doi: 10.1016/j.cplett.2005.11.109
15. [15]
  Zhu Q, Qian J, Pan H, et al. Nanotechnology, 2011, 22(39):395703(9 pages)
16. [16]
  Kawahara T, Konishi Y, Tada H, et al. Angew. Chem. Int. Ed., 2002, 41(15):2811-2812 doi: 10.1002/1521-3773(20020802)41:15<2811::AID-ANIE2811>3.0.CO;2-#
17. [17]
  SunB, Smirniotis P G. Catal. Today, 2003, 88:49-56 doi: 10.1016/j.cattod.2003.08.006
18. [18]
  Song X M, Wu J M, Tang M Z, et al. J. Phys. Chem. C, 2008, 112:19484-19492 doi: 10.1021/jp8076886
19. [19]
  Yan M C, Chen F, Zhang J L, et al. J. Phys. Chem. B, 2005, 109(18):8673-8678 doi: 10.1021/jp046087i
20. [20]
  Sever R R, Root T W. J. Phys. Chem. B, 2003, 107(38):10521-10530 doi: 10.1021/jp0343335
21. [21]
  Zhang Y, Wu L Z, Zeng Q H, et al. J. Phys. Chem. C, 2008, 112(42):16457-16462 doi: 10.1021/jp804524y
22. [22]
  Bojinova A, Kralchevska R, Poulios I, et al. Mater. Chem. Phys, 2007, 106(2):187-189
23. [23]
  Scotti R, Bellobono I R, Canevali C, et al. Chem. Mater., 2008, 20(12):4051-4061 doi: 10.1021/cm800465n
24. [24]
  Puddu V, Choi H, Dionysiou D D, et al. Appl. Catal. B, 2010, 94:211-218 doi: 10.1016/j.apcatb.2009.08.003
1. [1]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
2. [2]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
3. [3]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
4. [4]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
5. [5]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
6. [6]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
7. [7]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
8. [8]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
9. [9]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
10. [10]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
11. [11]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
12. [12]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
13. [13]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
14. [14]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
15. [15]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
16. [16]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
17. [17]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
18. [18]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
19. [19]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
20. [20]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1945)
HTML views(331)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Degradation of Methylene Blue of Hierarchical Mixed-Phase Urchin-like TiO2 Hollow Spheres

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Degradation of Methylene Blue of Hierarchical Mixed-Phase Urchin-like TiO₂ Hollow Spheres