Citation: WU Guo-Zhi, WANG Peng-Fei, LI Shan-Qing, FANG Xiao-Long. Metal Complexes Based on 3-Nitrophthalic Acid Involving in Situ Decarboxylaton: Syntheses, Crystal Structures and Physical Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 226-232. doi: 10.11862/CJIC.2020.035 shu

Metal Complexes Based on 3-Nitrophthalic Acid Involving in Situ Decarboxylaton: Syntheses, Crystal Structures and Physical Properties

1.
Key Laboratory of Micro-Nano Powder and Advanced Energy Materials of Anhui Higher Education Institute, School of Materials and Environmental Engineering, Chizhou University, Chizhou, Anhui 247000, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: WANG Peng-Fei, njuwangpf@163.com LI Shan-Qing, 103247284@qq.com
Received Date: 30 May 2019
Revised Date: 27 October 2019

Figures(8)

Two metal complexes, [Zn(3-NBA)(trz)]_n (1) and[Pb(3-NBA)(phen)₂]NO₃ (2), have been constructed through hydrothermal reaction using 3-nitrophthalic acid (3-NPAH₂), phen (1, 10-phenanthroline) or 1, 2, 4-triazole (Htrz), and ZnSO₄·7H₂O or Pb(NO₃)₂. During the reaction, the 3-HNBA resulted from the in situ decarboxylation of 3-nitrophthalic acid, and the experimental results have been confirmed by the theoretical calculation. Complexes 1~2 have been characterized by IR spectra, PXRD, elemental analyses and thermogravimetric analyses. Single-crystal X-ray diffraction analyses reveal that complex 1 exhibits a two-dimensional (2D) layered structure, which packs through weak N-O…π interactions. Complex 2 has a monomeric structure, which is assembled to a three-dimensional (3D) supramolecular structure through weak π…π interactions. Furthermore, the solid-state fluorescence of complexes 1~2 was recorded at room temperature.
- metal complex,
- crystal structure,
- fluorescent property,
- in situ reaction
1. [1]
  Zhao D, Liu X H, Sun W Y, et al. Inorg. Chem., 2018, 57:2695-2704 doi: 10.1021/acs.inorgchem.7b03099
2. [2]
  Lin R B, Xiang S C, Chen B L, et al. Coord. Chem. Rev., 2019, 378:87-103 doi: 10.1016/j.ccr.2017.09.027
3. [3]
  Yao Z Y, Guo J H, Sun W Y, et al. Coord. Chem. Rev., 2019, 378:262-280 doi: 10.1016/j.ccr.2018.02.009
4. [4]
  Cui Y J, Qian G D, Chen B L, et al. Chem. Rev., 2012, 12:1126-1162
5. [5]
  ZHANG Cui-Juan, NI Zhao-Ping, TONG Ming-Liang, et al. Chinese J. Inorg. Chem., 2019, 35(5):910-914
6. [6]
  Cai Z S, Bao S S, Zheng L M, et al. ACS Catal., 2018, 8:3895-3902 doi: 10.1021/acscatal.7b04276
7. [7]
  Zhao X H, Pattengale B, Xu C L, et al. ACS Enegy Lett., 2018, 3:2520-2526 doi: 10.1021/acsenergylett.8b01540
8. [8]
  Chen X M, Tong M L. Acc. Chem. Res., 2007, 40:162-170 doi: 10.1021/ar068084p
9. [9]
  Zhong J P, Liu B, Zeng M H, et al. Inorg. Chem., 2017, 56:10123-10126 doi: 10.1021/acs.inorgchem.7b01190
10. [10]
  Xiong K C, Jiang F L, Hong M C, et al. Cryst. Growth Des., 2012, 12:3335-3341 doi: 10.1021/cg300483c
11. [11]
  WU Xiao-Shuo, WANG Peng-Fei. Journal of Sichuan University:Natural Science Edition, 2018, 55(1):147-153
12. [12]
  SAINT, Program for Data Extraction and Reduction, Bruker AXS Inc., Madison, WI, USA, 2003.
13. [13]
  Sheldrick G M. SADABS, A Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 2008.
14. [14]
  Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
15. [15]
  Sheldrick G M. SHELXL-2018, Program for Crystal Structure Refinement, University of Göttingen, Germany, 2018.
16. [16]
  Song Z, Shi Z, Feng S H, et al. CrystEngComm, 2009, 11:1579-1584 doi: 10.1039/b901445d
17. [17]
  Chen K J, Zhang J P, Chen X M, et al. Cryst. Growth Des., 2013, 13:2118-2123 doi: 10.1021/cg400183s
18. [18]
  Fujisawa K, Letrun R, Matile S, et al. J. Am. Chem. Soc., 2015, 137:11047-11056 doi: 10.1021/jacs.5b05593
19. [19]
  Yang T, An J J, Wang X, et al. Phys. Chem. Chem. Phys., 2012, 14:10747-10753 doi: 10.1039/c2cp00025c
20. [20]
  Janiak C. J. Chem. Soc. Dalton Trans., 2000, 21: 3885-3896
21. [21]
  LI Yu, ZOU Xun-Zhong, CHENG Xiao-Ling, et al. Chinese J. Inorg. Chem., 2019, 35(2):329-336
22. [22]
  WANG Peng-Fei, WU Xiao-Shou, LU Peng-Peng, et al. Chinese J. Inorg. Chem., 2016, 32(6):1071-1077
23. [23]
  Shao Y L, Cui Y H, Gu J Z, et al. CrystEngComm, 2016, 18:765-778 doi: 10.1039/C5CE02254A
24. [24]
  Allendorf M D, Bauer C A, Bhakta R K, et al. Chem. Soc. Rev., 2009, 38:1330-1352 doi: 10.1039/b802352m
25. [25]
  Gu J Z, Gao Z Q, Tang Y. Cryst. Growth Des., 2012, 12:3312-3323 doi: 10.1021/cg300442b
26. [26]
  Wu Y P, Wu X Q, Wang J F, et al. Cryst. Growth Des., 2016, 16:2309-2316 doi: 10.1021/acs.cgd.6b00093
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
5. [5]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
6. [6]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
7. [7]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
8. [8]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
9. [9]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
10. [10]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
11. [11]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
12. [12]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
13. [13]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
14. [14]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
15. [15]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
16. [16]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
17. [17]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
18. [18]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
19. [19]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
20. [20]
  Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1837)
HTML views(223)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142