Citation: ZHANG Pei-Qing, LIU Si-Cheng, ZHENG Shu-Qin. Synthesis of Small Particle Size ZSM-5 Zeolite with Kaolin by in-Situ Solvent Free Method[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 289-294. doi: 10.11862/CJIC.2020.028 shu

Synthesis of Small Particle Size ZSM-5 Zeolite with Kaolin by in-Situ Solvent Free Method

Hunan Institute of Science and Technology, Yueyang, Hunan 414000, China

Corresponding author: ZHENG Shu-Qin, zhengshuqin37@163.com
Received Date: 5 August 2019
Revised Date: 9 November 2019

Figures(8)

By effectively combining in-situ crystallization and solvent-free method, the ZSM-5 zeolite was synthesized by seed induction and optimal synthesis conditions in a green and efficient manner on the basis of kaolin as raw material without adding organic template agent and solvent. The optimal synthesis conditions for the synthesis of ZSM-5 was:n_Na₂O/n_SiO₂ was 0.18~0.22, amount of seeds added was 5%(w/w) and reaction time was 70 h. The ZSM-5 zeolite was characterized by X-ray diffraction, N₂ adsorption-desorption, scanning electron microscope, transmission electron microscope and NH₃ programmed temperature desorption. Compared with ZSM-5 zeolite synthesized by hydrothermal method of in-situ crystallization, ZSM-5 zeolite by in-situ solvent free method obtained higher crystallinity, smaller crystal size, slightly higher acid strength and little difference in pore structure. In addition, the in-situ solvent-free method not only solved the problems of large pressure of the synthesis system and waste liquid discharge, but also improved the utilization rate of the reactor volume.
- zeolites,
- synthesis design,
- synthesis methods,
- mechanochemical synthesis,
- solvent-free,
- template-free,
- in-situ crystallization,
- kaolin
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