Citation: CHEN Ting, HU Xiao-Bo, XU Yan-Qiao, WANG Lian-Jun, JIANG Wan, JIANG Wei-Hui, XIE Zhi-Xiang. Hydrothermal Synthesis and Fluorescence Properties of AgInS₂/ZnS Core/Shell Quantum Dots[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 69-78. doi: 10.11862/CJIC.2020.024 shu

Hydrothermal Synthesis and Fluorescence Properties of AgInS₂/ZnS Core/Shell Quantum Dots

CHEN Ting ^1,2,, ,
HU Xiao-Bo ^1,3 ,
XU Yan-Qiao ¹ ,
WANG Lian-Jun ^2,3 ,
JIANG Wan ^2,3 ,
JIANG Wei-Hui ^1,2 ,
XIE Zhi-Xiang ¹

1.
School of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, Jiangxi 333001, China
2.
National Engineering Research Center for Domestic & Building Ceramics, Jingdezhen, Jiangxi 333001, China
3.
College of Materials Science and Engineering, Donghua University, Shanghai 201620, China

Corresponding author: CHEN Ting, chenting@jci.edu.cn
Received Date: 16 May 2019
Revised Date: 12 October 2019

Figures(10)

Water-soluble AgInS₂/ZnS (AIS/ZnS) core/shell quantum dots (QDs) were synthesized by hydrothermal method using thiourea (TU) as sulfur source, glutathione (GSH) and sodium citrate (SC) as ligands. The effects of reaction temperature and addition amount of ligands on the synthesis and fluorescence properties of AIS/ZnS QDs were systematically studied by XRD, TEM, UV-Vis absorption spectra and PL spectra, respectively, and their stability was also investigated. The results show that the emissive intensity of AIS/ZnS core/shell QDs is significantly improved by increasing the reaction temperature from 70 to 90℃. The increase of temperature promotes the growth of ZnS shell, on which the surface defects is effectively passivated. Meanwhile, the emissive peak showed a blue-shift from 600 nm to 580 nm. Furthermore, the ligands could balance the chemical reactivity of Zn²⁺, slow the growth rate of ZnS shell, inhibit the interface defects formation and eliminate the surface states. The AIS/ZnS core/shell QDs showed the strongest emission with n_GSH/n_Zn²⁺ of 2.0 and n_SC/n_Zn²⁺ of 2.5. Importantly, the obtained AIS/ZnS core/shell QDs exhibited excellent optical stability.
- quantum dot,
- hydrothermal synthesis,
- core-shell structure,
- emissive intensity,
- stability
1. [1]
  Mao B D, Chuang C H, McCleese C, et al. J. Phys. Chem. C, 2014, 118(25):13883-13889 doi: 10.1021/jp500872w
2. [2]
  Manna G, Jana S, Bose R, et al. J. Phys. Chem. Lett., 2012, 3(18):2528-2534 doi: 10.1021/jz300978r
3. [3]
  Mao B D, Chuang C H, Wang J W, et al. J. Phys. Chem. C, 2011, 115(18):8945-8954 doi: 10.1021/jp2011183
4. [4]
  Carvalho I C, Mansur A A P, Carvalho S M, et al. Int. J. Biol. Macromol., 2019, 133:739-753 doi: 10.1016/j.ijbiomac.2019.04.140
5. [5]
  Wang R L, Shang Y Q, Kanjanaboos P, et al. Energy Environ. Sci., 2016, 9(4):1130-1143 doi: 10.1039/C5EE03887A
6. [6]
  Liu Y, Kim D H, Morris O P, et al. ACS Nano, 2018, 12(3):2838-2845 doi: 10.1021/acsnano.8b00132
7. [7]
  Shay J L, Tell B, Schiavone L M, et al. Phys. Rev. B, 1974, 9(4):1719-1723 doi: 10.1103/PhysRevB.9.1719
8. [8]
  Hamanaka Y, Yukitoki D, Kuzuya T. Appl. Phys. Express, 2015, 8(9):095001 doi: 10.7567/APEX.8.095001
9. [9]
  Mao B D, Chuang C H, Lu F, et al. J. Phys. Chem. C, 2012, 117(1):648-656
10. [10]
  Suzuki S, Hattori Y, Kuwabata S, et al. J. Photochem. Photobiol. A, 2017, 332:371-375 doi: 10.1016/j.jphotochem.2016.08.034
11. [11]
  Pu Y, Cai F H, Wang D, et al. Ind. Eng. Chem. Res., 2018, 57(6):1790-1802 doi: 10.1021/acs.iecr.7b04836
12. [12]
  Regulacio M D, Win K Y, Lo S L, et al. Nanoscale, 2013, 5(6):2322-2327 doi: 10.1039/c3nr34159c
13. [13]
  TAO You-Rong, WU Xing-Cai, XIONG Wei-Wei. Experimental Technology and Manage-ment, 2017, 34(11):46-49
14. [14]
  LÜ Jian-Quan, HU Qin-Qin, DING Ran, et al. Chem. J. Chinese Universities, 2013, 34(11):2478-2482 doi: 10.7503/cjcu20130773
15. [15]
  Raevskaya A, Lesnyak V, Haubold D, et al. J. Phys. Chem. C, 2017, 121(16):9032-9042 doi: 10.1021/acs.jpcc.7b00849
16. [16]
  Jing L H, Kershaw S V, Li Y L, et al. Chem. Rev., 2016, 116(18):10623-10730 doi: 10.1021/acs.chemrev.6b00041
17. [17]
  Hu X B, Chen T, Xu Y Q, et al. J. Lumin., 2018, 200:189-195 doi: 10.1016/j.jlumin.2018.04.025
18. [18]
  Song J L Q, Ma C, Zhang W Z, et al. ACS Appl. Mater. Interfaces, 2016, 8(37):24826-24836 doi: 10.1021/acsami.6b07768
19. [19]
  Zeng B, Chen F, Liu Z Y, et al. J. Mater. Chem. C, 2019, 7(5):1307-1315 doi: 10.1039/C8TC05755A
20. [20]
  Holzwarth U, Gibson N. Nat. Nanotechnol., 2011, 6(9):534 doi: 10.1038/nnano.2011.145
21. [21]
  ZHU Yong-Ming, XIE Bin, LUO Xiao-Bing. Chin. Sci. Bull., 2017, 62(7):659-673
22. [22]
  Gunton J D. J. Stat. Phys., 1999, 95(5/6):903-923 doi: 10.1023/A:1004598332758
23. [23]
  Stroyuk O, Raevskaya A, Gaponik N. Chem. Soc. Rev., 2018, 47(14):5354-5422 doi: 10.1039/C8CS00029H
24. [24]
  Xiang W D, Xie C P, Wang J, et al. J. Alloys Compd., 2014, 588:114-121 doi: 10.1016/j.jallcom.2013.10.188
25. [25]
  Khan Z M S H, Khan S A, Zulfequar M. Mater. Sci. Semicond. Process., 2017, 57:190-196 doi: 10.1016/j.mssp.2016.10.022
26. [26]
  Zhang B T, Wang Y C, Yang C B, et al. Phys. Chem. Chem. Phys., 2015, 17(38):25133-25141 doi: 10.1039/C5CP03312H
27. [27]
  Karimzadeh A, Hasanzadeh M, Shadjou N, et al. TrAC Trends Anal. Chem., 2018, 108:110-121 doi: 10.1016/j.trac.2018.08.012
28. [28]
  Wang Y B, Liang X H, Ma X, et al. Appl. Surf. Sci., 2014, 316:54-61 doi: 10.1016/j.apsusc.2014.07.135
29. [29]
  Piegat A, El Fray M, Jawad H, et al. Adv. Appl. Ceram., 2008, 107(5):287-292 doi: 10.1179/174367508X297777
30. [30]
  Feng J, Yang X R. J. Nanopart. Res., 2012, 14(8):1044 doi: 10.1007/s11051-012-1044-9
31. [31]
  Wang Q S, Fang T T, Liu P, et al. Inorg. Chem., 2012, 51(17):9208-9213 doi: 10.1021/ic300473u
32. [32]
  Huang P C, Jiang Q, Yu P, et al. ACS Appl. Mater. Interfaces, 2013, 5(11):5239-5246 doi: 10.1021/am401082n
33. [33]
  Xiong W W, Yang G H, Wu X C, et al. J. Mater. Chem. B, 2013, 1(33):4160-4165 doi: 10.1039/c3tb20638f
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沈阳化工大学材料科学与工程学院沈阳 110142

Hydrothermal Synthesis and Fluorescence Properties of AgInS2/ZnS Core/Shell Quantum Dots

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通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis and Fluorescence Properties of AgInS₂/ZnS Core/Shell Quantum Dots