Citation: WANG Li-Li, YANG Qian-Ying, HAN Li-Zhi, ZHANG Xiao-Peng, CHEN Xin-Han, SHI Zai-Feng. Syntheses and Spectroscopic Properties of Chiral Dinuclear Eu(Ⅲ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 352-360. doi: 10.11862/CJIC.2020.020 shu

Syntheses and Spectroscopic Properties of Chiral Dinuclear Eu(Ⅲ) Complexes

1.
College of Chemistry and Chemical Engineering, Key Laboratory of Water Pollution Treatment&Resource Reuse of Hainan Province, Hainan Normal University, Haikou 571158, China
2.
College of Chemical Engineering, Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: ZHANG Xiao-Peng, xpzhang@hainnu.edu.cn CHEN Xin-Han, xhchen@njfu.edu.cn
Received Date: 1 July 2019
Revised Date: 6 October 2019

Figures(7)

Circularly polarized luminescence materials based on emissive Eu(Ⅲ) complexes have attracted considerable attention in 3D-displays and bioresponsive imaging. In this work, we design and report the syntheses of a pair of chiral carboxylic-containing 2, 2'-bipyridine ligands ((+)-L and (-)-L). Through reaction with highly emissive β-diketone Eu(Ⅲ) complexes[Eu(TTA)₃]·2H₂O (TTA=2-thenoyltrifluoroacetone), a couple of chiral dinuclear Eu(Ⅲ) enantiomers, [Eu₂((+)-L)₂(TTA)₂(C₂H₅OH)₂] ((+)-1) and[Eu₂((-)-L)₂(TTA)₂(C₂H₅OH)₂] ((-)-1), were prepared, and the structure of (+)-1 was confirmed by single-crystal X-ray diffraction. The absorption, emission and chiroptical properties of (+)-1 and (-)-1 were investigated, and distinct CPL activities were clearly detected.
- circularly polarized luminescence,
- dinuclear Eu(Ⅲ) complex,
- chiral complex,
- pinene group,
- carboxylic-containing 2, 2'-bipyridine
1. [1]
  Yang D, Duan P, Zhang L, et al. Nat. Commun., 2017, 8:15727 doi: 10.1038/ncomms15727
2. [2]
  Li M, Li S H, Zhang D, et al. Angew. Chem. Int. Ed., 2018, 57:2889-2893 doi: 10.1002/anie.201800198
3. [3]
  Wu Z G, Han H B, Yan Z P, et al. Adv. Mater., 2019, 31:1900524 doi: 10.1002/adma.201900524
4. [4]
  LI Meng, LIN Wei-Bin, FANG Lei, et al. Acta Chim. Sinica, 2017, 75:1150-1163
5. [5]
  Yuasa J, Ohno T, Miyata K, et al. J. Am. Chem. Soc., 2011, 133:9892-9902 doi: 10.1021/ja201984u
6. [6]
  Kitchen J A, Barry D E, Mercs L, et al. Angew. Chem. Int. Ed., 2012, 51:704-708 doi: 10.1002/anie.201106863
7. [7]
  Yeung C T, Yim K H, Wong H Y, et al. Nat. Commun., 2017, 8:1128 doi: 10.1038/s41467-017-01025-1
8. [8]
  Casanovas B, Zinna F, Bari L D, et al. Dalton Trans., 2017, 46:6349-6357 doi: 10.1039/C6DT04686J
9. [9]
  LI Jun-Feng, LIU Xun-Hua, CHEN Ying, et al. Acta Polym. Sin., 2015(3):252-258
10. [10]
  Lunkley J L, Shirotani D, Yamanari K, et al. J. Am. Chem. Soc., 2008, 130:13814-13815 doi: 10.1021/ja805681w
11. [11]
  Zinna F, Giovanella U, Bari L D, et al. Adv. Mater., 2015, 27:1791-1795 doi: 10.1002/adma.201404891
12. [12]
  Zinna F, Pasini M, Galeotti F, et al. Adv. Funct. Mater., 2017, 27:1603719 doi: 10.1002/adfm.201603719
13. [13]
  Ziegler M, Monney V, Stoeckli-Evans H, et al. J. Chem. Soc. Dalton Trans., 1999:667-676
14. [14]
  Sauers A L, Ho D M, Bernhard S, et al. J. Org. Chem., 2004, 69:8910-8915 doi: 10.1021/jo048515m
15. [15]
  Knof U, von Zelewsky A. Angew. Chem. Int. Ed., 1999, 38:302-322 doi: 10.1002/(SICI)1521-3773(19990201)38:3<302::AID-ANIE302>3.0.CO;2-G
16. [16]
  Malkov A V, Pernazza D, Bell M, et al. J. Org. Chem., 2003, 68:4727-4742 doi: 10.1021/jo034179i
17. [17]
  Sham K C, Yeung H L, Yiu S M, et al. Dalton Trans., 2010, 39:9469-9471 doi: 10.1039/c0dt00953a
18. [18]
  Mamula O, Lama M, Telfer S G, et al. Angew. Chem. Int. Ed., 2005, 44:2527-2531 doi: 10.1002/anie.200500094
19. [19]
  Lama M, Mamula O, Kottas G S, et al. Chem. Eur. J., 2007, 13:7358-7373 doi: 10.1002/chem.200700324
20. [20]
  Liu J, Wang K, Zheng W, et al. Prog. Photovoltaics Res. Appl., 2013, 21:668-675
21. [21]
  Liu J, Zhang X P, Wu T, et al. Inorg. Chem., 2012, 51:8649-8651 doi: 10.1021/ic3012475
22. [22]
  LIU Jian, ZHANG Xiao-Peng, LI Cheng-Hui. Chinese J. Inorg. Chem., 2017, 33:2060-2064
23. [23]
  WANG Ting-Wei, CHEN Hong-Jin, ZHANG Rui, et al. Chinese J. Inorg. Chem., 2018, 34:1007-1017
24. [24]
  Houminer Y, Southwick E W, Williams D L, et al. J. Org. Chem., 1989, 54:640-643 doi: 10.1021/jo00264a026
25. [25]
  SAINT-Plus, Ver. 6.02, Bruker Analytical X-ray System, Madison, WI, 1999.
26. [26]
  Sheldrick G M. SADABS, An Empirical Absorption Correction Program, Bruker Analytical X-ray Systems, Madison, WI, 1996.
27. [27]
  Sheldrick G M. Acta Crystallogr. Sect. A:Found. Crystallogr., 2008, 64:112-122 doi: 10.1107/S0108767307043930
28. [28]
  Li D P, Li C H, Wang J, et al. Eur. J. Inorg. Chem., 2009:4844-4849
29. [29]
  Cabral F M, Gálico D A, Mazali I O, et al. Inorg. Chem. Commun., 2018, 8:29-33
30. [30]
  Li X L, Chen C L, Gao Y L, et al. Chem. Eur. J., 2012, 18:14632-14637 doi: 10.1002/chem.201201190
1. [1]
  Zhao-Xia Lian , Xue-Zhi Wang , Chuang-Wei Zhou , Jiayu Li , Ming-De Li , Xiao-Ping Zhou , Dan Li . Producing circularly polarized luminescence by radiative energy transfer from achiral metal-organic cage to chiral organic molecules. Chinese Chemical Letters, 2024, 35(8): 109063-. doi: 10.1016/j.cclet.2023.109063
2. [2]
  Yongjing Deng , Feiyang Li , Zijian Zhou , Mengzhu Wang , Yongkang Zhu , Jianwei Zhao , Shujuan Liu , Qiang Zhao . Chiral induction and Sb³⁺ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(8): 109085-. doi: 10.1016/j.cclet.2023.109085
3. [3]
  Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
4. [4]
  Xue-Zhi Wang , Yi-Tong Liu , Chuang-Wei Zhou , Bei Wang , Dong Luo , Mo Xie , Meng-Ying Sun , Yong-Liang Huang , Jie Luo , Yan Wu , Shuixing Zhang , Xiao-Ping Zhou , Dan Li . Amplified circularly polarized luminescence of chiral metal-organic frameworks via post-synthetic installing pillars. Chinese Chemical Letters, 2024, 35(10): 109380-. doi: 10.1016/j.cclet.2023.109380
5. [5]
  Jingwen Zhao , Jianpu Tang , Zhen Cui , Limin Liu , Dayong Yang , Chi Yao . A DNA micro-complex containing polyaptamer for exosome separation and wound healing. Chinese Chemical Letters, 2024, 35(9): 109303-. doi: 10.1016/j.cclet.2023.109303
6. [6]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
7. [7]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
8. [8]
  Mengjuan Sun , Muye Zhou , Yifang Xiao , Hailei Tang , Jinhua Chen , Ruitao Zhang , Chunjiayu Li , Qi Ya , Qian Chen , Jiasheng Tu , Qiyue Wang , Chunmeng Sun . Reversibly size-switchable polyion complex micelles for antiangiogenic cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109110-. doi: 10.1016/j.cclet.2023.109110
9. [9]
  Yuanjin Chen , Xianghui Shi , Dajiang Huang , Junnian Wei , Zhenfeng Xi . Synthesis and reactivity of cobalt dinitrogen complex supported by nonsymmetrical pincer ligand. Chinese Chemical Letters, 2024, 35(7): 109292-. doi: 10.1016/j.cclet.2023.109292
10. [10]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
11. [11]
  Yingying Yan , Wanhe Jia , Rui Cai , Chun Liu . An AIPE-active fluorinated cationic Pt(Ⅱ) complex for efficient detection of picric acid in aqueous media. Chinese Chemical Letters, 2024, 35(5): 108819-. doi: 10.1016/j.cclet.2023.108819
12. [12]
  Jian Peng , Yue Jiang , Shuangyu Wu , Yanran Cheng , Jingyu Liang , Yixin Wang , Zhuo Li , Sijie Lin . A nonradical oxidation process initiated by Ti-peroxo complex showed high specificity toward the degradation of tetracycline antibiotics. Chinese Chemical Letters, 2024, 35(5): 108903-. doi: 10.1016/j.cclet.2023.108903
13. [13]
  Wenjuan Jin , Zelong Chen , Yi Wang , Jiaxuan Li , Jiahui Li , Yuxin Pei , Zhichao Pei . Nano metal-photosensitizer based on Aza-BODIPY-Cu complex for CDT-enhanced dual phototherapy. Chinese Chemical Letters, 2024, 35(7): 109328-. doi: 10.1016/j.cclet.2023.109328
14. [14]
  Jinyu Guo , Yandai Lin , Shaohua He , Yueqing Chen , Fenglu Li , Renjie Ruan , Gaoxing Pan , Hexin Nan , Jibin Song , Jin Zhang . Utilizing dual-responsive iridium(Ⅲ) complex for hepatocellular carcinoma: Integrating photoacoustic imaging with chemotherapy and photodynamic therapy. Chinese Chemical Letters, 2024, 35(9): 109537-. doi: 10.1016/j.cclet.2024.109537
15. [15]
  Zhengyi Shi , Jie Yin , Yang Xiao , Zhangrong Hou , Fei Song , Jianping Wang , Qingyi Tong , Changxing Qi , Yonghui Zhang . Unprecedented sesquiterpene-polycyclic polyprenylated acylphloroglucinol adduct against acute myeloid leukemia via inhibiting mitochondrial complex Ⅴ. Chinese Chemical Letters, 2024, 35(10): 109458-. doi: 10.1016/j.cclet.2023.109458
16. [16]
  Yu-Yu Tan , Lin-Heng He , Wei-Min He . Copper-mediated assembly of SO₂F group via radical fluorine-atom transfer strategy. Chinese Chemical Letters, 2024, 35(9): 109986-. doi: 10.1016/j.cclet.2024.109986
17. [17]
  Xue Zhao , Mengshan Chen , Dan Wang , Haoran Zhang , Guangzhi Hu , Yingtang Zhou . Ultrafine nano-copper derived from dopamine polymerization & synchronous adsorption achieve electrochemical purification of nitrate to ammonia in complex water environments. Chinese Chemical Letters, 2024, 35(8): 109327-. doi: 10.1016/j.cclet.2023.109327
18. [18]
  Xinghui Yao , Zhouyu Wang , Da-Gang Yu . Sustainable electrosynthesis: Enantioselective electrochemical Rh(III)/chiral carboxylic acid-catalyzed oxidative CH cyclization coupled with hydrogen evolution reaction. Chinese Chemical Letters, 2024, 35(9): 109916-. doi: 10.1016/j.cclet.2024.109916
19. [19]
  Boyuan Hu , Jian Zhang , Yulin Yang , Yayu Dong , Jiaqi Wang , Wei Wang , Kaifeng Lin , Debin Xia . Dual-functional POM@IL complex modulate hole transport layer properties and interfacial charge dynamics for highly efficient and stable perovskite solar cells. Chinese Chemical Letters, 2024, 35(7): 108933-. doi: 10.1016/j.cclet.2023.108933
20. [20]
  Hao Jiang , Yuan-Yuan He , Hai-Chao Liang , Meng-Jia Shang , Han-Han Lu , Chun-Hua Liu , Yin-Shan Meng , Tao Liu , Yuan-Yuan Zhu . Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100354-100354. doi: 10.1016/j.cjsc.2024.100354

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1532)
HTML views(115)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142