Citation: HOU Xiao-Fei, ZHAO Wan-Nan, MA Jing, SUN Ji-Qiang, LI Yan-Hong. Synthesis and Luminescence Properties of Eu³⁺ doped LaBO₃ Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 276-282. doi: 10.11862/CJIC.2020.016 shu

Synthesis and Luminescence Properties of Eu³⁺ doped LaBO₃ Phosphors

School of Material Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China

Corresponding author: LI Yan-Hong, lyhciom@126.com
Received Date: 3 August 2019
Revised Date: 8 November 2019

Figures(9)

LaBO₃:Eu³⁺ phosphors with different crystal phase were prepared by heat treatment precursor prepared by hydrothermal method. The structure, morphology and luminescence properties of the samples were characterized with X-ray diffraction (XRD), field emission scanning electron microscopy (SEM), infrared spectroscopy and fluorescence spectroscopy. The effects of boric acid dosage, heat treatment temperature, and initial solution pH of precursor on structure and luminescence properties of the samples were studied. The results of XRD showed that the phosphors with orthogonal structure, monoclinic structure and both phase mixed structure can be obtained. LaBO₃ with pure orthogonal structure can be obtained by heating treatment at 700℃ for precursors synthesized with initial solution pH=8 and molar ratio of rare earth ions to boric acid of 1:3 and 1:4, respectively. It is convenient to obtained phosphors with orthogonal structure at proper boric acid dosage, higher heat treatment temperature and higher initial solution pH value. Infrared spectra showed that the change of initial solution pH and boric acid dosage effected the composition of precursor, and the heat treatment temperature effected the crystal phase transformation. SEM showed that particle size of LaBO₃:Eu³⁺ phosphor decreased with the increase of initial solution pH, which were consistent with the results calculated from XRD. The excitation spectra of samples consisted of the broad band in a range of 200~350 nm and another weak narrow lines in a range of 350~450 nm, which were assigned to O^2--Eu³⁺ charge transfer band and f-f transitions of Eu³⁺ ions, respectively. The emission spectra of samples consisted of sharp lines ranging from 500 to 750 nm, which are associated with the transitions from the excited ⁵D₀-⁷F_J (J=1, 2, 3, 4) of Eu³⁺ ions. The main emission peak at 615 nm was due to the ⁵D₀-⁷F₂ transitions of Eu³⁺, the peak at 593 nm was attributed to ⁵D₀-⁷F₁ transitions of Eu³⁺. The excitation and emission intensities are related to the structure of the samples. LaBO₃:Eu³⁺ with orthogonal structure has higher ultraviolet absorption and higher emission intensity with pure red light.
- phosphors,
- LaBO₃:Eu³⁺,
- hydrothermal method,
- heat treatment,
- luminescence
1. [1]
  NING Hong-Yu, CHEN Zhi-Yuan, DONG Chao, et al. Chinese Journal of Luminescence, 2018, 39(8):1087-1094
2. [2]
  WU Zhan-Chao, WANG Shuai, LIU Jie. New Chemical Materials, 2015, 43(13):13-15
3. [3]
  Wang D Y, Chen T M, Cheng B M. Inorg. Chem., 2012, 51:2961-2965 doi: 10.1021/ic202241h
4. [4]
  Wei H W, Shao L M, Jiao H, et al. Opt. Mater., 2018, 75:442-447 doi: 10.1016/j.optmat.2017.10.011
5. [5]
  Lakshmanan A, Bhaskar R S, Thomas P C, et al. Mater. Lett., 2010, 64:1809-1812 doi: 10.1016/j.matlet.2010.05.034
6. [6]
  ZHU Fan, YOU Fang-Tian, SHI Qiu-Feng, et al. Chinese Journal of Luminescence, 2015, 36(7):751-756
7. [7]
  Srivastava S, Mondal A, Sahu N K, et al. RSC Adv., 2015, 5:11009-11012 doi: 10.1039/C4RA12745E
8. [8]
  GAO Rong, ZHANG Zhi-Jun, ZHAO Jing-Tai. J. Chin. Rare Earth Soc., 2014, 32(4):387-396
9. [9]
  MA Jing, ZHAO Wan-Nan, LI Yan-Hong. Chinese Journal of Luminescence, 2018, 39(9):1213-1219
10. [10]
  ZHAO Wan-Nan, MA Jing, ZHANG Zhen-Qian, et al. Journal of the Chinese Ceramic Society, 2017, 45(4):526-541
11. [11]
  Sari S, Senberber F T, Meral Y, et al. Mater. Chem. Phys., 2017, 200:196-203 doi: 10.1016/j.matchemphys.2017.07.056
12. [12]
  Liang P, Liu J W, Liu Z H. RSC Adv., 2016, 6:89113-89123 doi: 10.1039/C6RA19101K
13. [13]
  Grzyb T, Kubasiewicz K, Szczeszak A, et al. Dalton Trans., 2015, 44:4063-4069 doi: 10.1039/C4DT03667K
14. [14]
  Yi H, Wu L, Wu L W, et al. Inorg. Chem., 2016, 55:6487-6495 doi: 10.1021/acs.inorgchem.6b00552
15. [15]
  LI Qi-Hua, LIU Li-Min, ZENG Li-Hua, et al. Chinese Journal of Luminescence, 2006, 27(2):183-186 doi: 10.3321/j.issn:1000-7032.2006.02.009
16. [16]
  Rambabu U, Han S D. RSC Adv., 2013, 3:1368-1379 doi: 10.1039/C2RA21304D
17. [17]
  DONG Yan, JIANG Jian-Qing, XIAO Rui, et al. J. Chin. Rare Earth Soc., 2004, 22(4):201-205
18. [18]
  Zeng Y B, Li Z Q, Liang Y F, et al. Inorg. Chem., 2013, 52:9590-9596 doi: 10.1021/ic401299h
19. [19]
  YIN Xin-Hao, LI Yun-Hui, GAO Ying, et al. Chinese J. Inorg. Chem., 2014, 30(9):2064-2074
20. [20]
  GUO Fan, FU Pei-Zhen, WANG Jun-Xin, et al. J. Synth Cryst, 2000, 29(5):16
21. [21]
  LI Lin-Yan, LI Bao-Guo, LIAO Fu-Hui, et al. Acta Phys.-Chim. Sin., 2005, 21(7):769-773 doi: 10.3866/PKU.WHXB20050714
22. [22]
  Jia G, Zhang C M, Wang C Z, et al. CrystEngComm, 2012, 14:579-584 doi: 10.1039/C1CE05973D
23. [23]
  Gadsden J A. Infrared Spectra of Minerals and Related Inorganic Compounds. London:Butterworth, 1975.
24. [24]
  Qin C X, Qin L, Chen G Q, et al. J. Nanopart. Res., 2013, 15:1827-1836 doi: 10.1007/s11051-013-1827-7
25. [25]
  Shmyt'ko I M, Kiryakin I N, Strukova G K. Phys. Solid State, 2013, 55(7):1468-147 doi: 10.1134/S1063783413070305
26. [26]
  Cansin B, Okan E, Aysen Y. Solid State Sci., 2012, 14:1710-1716 doi: 10.1016/j.solidstatesciences.2012.07.026
1. [1]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
2. [2]
  Cuiping HE , Zhuxuan LI , Yuqing SUN , Jie LIU , Shicheng XU , Zhanchao WU . Ca²⁺ doping induced crystal phase transition and spectral regulation of Ba₃P₄O₁₃: Eu²⁺ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2299-2306. doi: 10.11862/CJIC.20250074
3. [3]
  Tong WANG , Xuefang ZHU , Qi GAO , Hongbo ZHANG , Chao REN , Lixia GE . Luminescence and thermal stability of Tb³⁺-Eu³⁺ doped glass-ceramics containing Na_8.12Y_1.293Si₆O₁₈ crystal phase. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2237-2250. doi: 10.11862/CJIC.20250137
4. [4]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
5. [5]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
6. [6]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
7. [7]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
8. [8]
  Shuting Zhuang , Lida Zhao . Teaching through Research: A Comprehensive Experiment on Carbon Quantum Dots from Microplastic Waste. University Chemistry, 2025, 40(10): 217-224. doi: 10.12461/PKU.DXHX202412010
9. [9]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
10. [10]
  Ruixin XU , Hongtuo LI , Chen SHI , Yanhong YAN . Factors influencing the spectral properties of composite luminescent materials SrTiO₃: Eu³⁺/SrAl₂O₄: Eu²⁺, Dy³⁺. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2307-2316. doi: 10.11862/CJIC.20250055
11. [11]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
12. [12]
  Hengyi ZHU , Liyun JU , Haoyue ZHANG , Jiaxin DU , Yutong XIE , Li SONG , Yachao JIN , Mingdao ZHANG . Efficient regeneration of waste LiNi_0.5Co_0.2Mn_0.3O₂ cathode toward high-performance Li-ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 625-638. doi: 10.11862/CJIC.20240358
13. [13]
  Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320
14. [14]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
15. [15]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
16. [16]
  Wanting CHEN , Chufei MIAO , Yan LIU , Bobi ZHENG , Xiaoyu ZHENG , Han XU , Jumei TIAN . Syntheses, characterization, and luminescence properties of Yb(Ⅲ)-based one-dimensional chain coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1672-1680. doi: 10.11862/CJIC.20250013
17. [17]
  Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079
18. [18]
  Hongzhi Zhang , Hong Li , Asif Ali Haider , Junpeng Li , Zhi Xie , Hongming Jiang , Conglin Liu , Rui Wang , Jing Zhu . An unexpected role of lanthanide substitution in thermally responsive phosphors NaLnTe2O7: Eu3+ (Ln = Y and Gd). Chinese Journal of Structural Chemistry, 2025, 44(2): 100509-100509. doi: 10.1016/j.cjsc.2024.100509
19. [19]
  Siyu Zong , Xiaowei Yu , Yining Yang , Xin Yang , Jiyang Li . Multi-mode luminescence anti-counterfeiting and visual iron(Ⅲ) ions RTP detection constructed by assembly of CDs&Eu³⁺ in porous RHO zeolite. Chinese Chemical Letters, 2025, 36(6): 110343-. doi: 10.1016/j.cclet.2024.110343
20. [20]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388

Get Citation

PDF

XML

Metrics

PDF Downloads(25)
Abstract views(3436)
HTML views(630)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Luminescence Properties of Eu3+ doped LaBO3 Phosphors

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and Luminescence Properties of Eu³⁺ doped LaBO₃ Phosphors