Citation: ZHU Ning, PAN Xun, LIN Sen, YANG Yu-Ping, XIN Xiu-Lan, LI Zhong-Feng, ZHANG Fan, JIN Qiong-Hua. Syntheses, Structures and Terahertz Time-Domain Spectroscopy of Two Diimine-Copper(Ⅰ)-Phosphine Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 183-191. doi: 10.11862/CJIC.2020.015 shu

Syntheses, Structures and Terahertz Time-Domain Spectroscopy of Two Diimine-Copper(Ⅰ)-Phosphine Complexes

ZHU Ning ^1,2 ,
PAN Xun ¹ ,
LIN Sen ¹ ,
YANG Yu-Ping ³ ,
XIN Xiu-Lan ⁴ ,
LI Zhong-Feng ¹ ,
ZHANG Fan ^1,, ,
JIN Qiong-Hua ^1,2,,

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China
2.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
3.
School of Science, Minzu University of China, Beijing 100081, China
4.
School of Food and Chemical Engineering, Beijing Technology and Business University, Beijing 100048, China

Corresponding author: ZHANG Fan, 3938@cnu.edu.cn JIN Qiong-Hua, jinqh@cnu.edu.cn
Received Date: 28 May 2019
Revised Date: 11 October 2019

Figures(11)

Herein, two novel copper(Ⅰ) complexes, [Cu(PPh₃)₂(dppz)]Ⅰ (1) and[Cu₂(dppm)₂(dppz)₂]Cl₂ (2) (PPh₃=triphenylphosphine, dppz=dipyrido[3, 2-a:2', 3'-c]phenazine, dppm=bis(diphenylphosphino) methane) have been synthesized, and the characterization of the complexes was carried out through single-crystal X-ray diffraction, elemental analysis, IR, ¹H/³¹P NMR spectroscopy, fluorescence spectra and THz time domain spectroscopy (THz-TDS). The results show that 1 is a mononuclear complex. The central Cu(Ⅰ) builds a distorted tetrahedral geometry by coordinating with two phosphine ligands (PPh₃) and one chelating N-donor ligand (dppz). Different from 1, 2 exhibits a dinuclear structure which was obtained by the reaction of CuCl and dppm with dppz in 1:1:1 molar ratio, where the diphosphine ligand (dppm) was utilized as a bridging ligand coordinating to two copper(Ⅰ) atoms. The luminescent spectra show that the emission mechanism belongs to metal-to-ligand charge transfer (MLCT). At the same time, the terahertz (THz) time-domain spectroscopy was used to represent these two complexes as well as the corresponding ligands.
- copper(Ⅰ) complex,
- structures,
- fluorescence,
- terahertz (THz) time-domain spectroscopy,
- dipyrido[3, 2-a:2', 3'-c]phenazine
1. [1]
  dos Santos C M G, Harte A J, Quinn S J, et al. Coord. Chem. Rev., 2008, 252:2512-2527 doi: 10.1016/j.ccr.2008.07.018
2. [2]
  Hu X, Wang F Y, Peng Q Q, et al. RSC Adv., 2019, 9:13048-13053 doi: 10.1039/C9RA01748H
3. [3]
  Farahani Y D, Safarifard V. J. Solid State Chem., 2019, 275:131-140 doi: 10.1016/j.jssc.2019.04.018
4. [4]
  Jana M K, Janke S M, Dirkes D J, et al. J. Am. Chem. Soc., 2019, 141:7955-7964 doi: 10.1021/jacs.9b02909
5. [5]
  Hayashi T, Kobayashi A, Ohara H, et al. Inorg. Chem., 2019, 54:8905-8913
6. [6]
  Huang X S, Hu M, Zhao X H, et al. Org. Lett., 2019, 21:3382-3386 doi: 10.1021/acs.orglett.9b01130
7. [7]
  Cao L D, Zhang H R, Zhou Z L, et al. Nanoscale, 2018, 10:20354-20365 doi: 10.1039/C8NR04626C
8. [8]
  Taha Z A, Ajlouni A M, Al Momani W. J. Lumin., 2012, 132:2832-2841 doi: 10.1016/j.jlumin.2012.05.041
9. [9]
  Gao H, Zhao X, Chen S J. Molecules, 2018, 23:419/1-419/20
10. [10]
  Zhang D D, Duan L. J. Phys. Chem. Lett., 2019, 10:2528-2537 doi: 10.1021/acs.jpclett.9b00526
11. [11]
  Tsuboyama A, Kuge K, Furugori M, et al. Inorg. Chem., 2007, 46:1992-2001 doi: 10.1021/ic0608086
12. [12]
  Xiao L, Chen Z, Qu B, et al. Adv. Mater., 2011, 23:926-952 doi: 10.1002/adma.201003128
13. [13]
  Hashimoto M, Igawa S, Yashima M, et al. J. Am. Chem. Soc., 2011, 133:10348-10351 doi: 10.1021/ja202965y
14. [14]
  Minaev B, Jansson E, Agren H, et al. J. Chem. Phys., 2006, 125:234704 doi: 10.1063/1.2388263
15. [15]
  Helander M G, Wang Z B, Qiu J, et al. Science, 2011, 332:944-947 doi: 10.1126/science.1202992
16. [16]
  Hamze R, Peltier J L, Sylvinson D, et al. Science, 2019, 363:601-606 doi: 10.1126/science.aav2865
17. [17]
  Brunner F, Martinez-Sarti L, Keller S, et al. Dalton Trans., 2016, 45:15180-15192 doi: 10.1039/C6DT02665F
18. [18]
  Linfoot C L, Leitl M J, Richardson P, et al. Inorg. Chem., 2014, 53:10854-10861 doi: 10.1021/ic500889s
19. [19]
  Adachi C, Baldo M A, Thompson M E, et al. J. Appl. Phys., 2001, 90:5048-5051 doi: 10.1063/1.1409582
20. [20]
  Tanaka D, Agata Y, Takeda T, et al. Jpn. J. Appl. Phys., 2007, 46:L117-L119 doi: 10.1143/JJAP.46.L117
21. [21]
  Zhang Y, Schulz M, Waechtler M, et al. Coord. Chem. Rev., 2018, 356:127-146 doi: 10.1016/j.ccr.2017.10.016
22. [22]
  Kuang S M, Cuttell D G, McMillin D R. Inorg. Chem., 2002, 41:3313-3322 doi: 10.1021/ic0201809
23. [23]
  Zhang Q S, Zhou Q G, Cheng Y X, et al. Adv. Mater., 2004, 16:432-436 doi: 10.1002/adma.200306414
24. [24]
  Bergmann L, Friedrichs J, Mydlak M, et al. Chem. Commun., 2013, 49:6501-6503 doi: 10.1039/c3cc42280a
25. [25]
  Chen X L, Yu R M, Zhang Q K, et al. Chem. Mater., 2013, 25:3910-3920 doi: 10.1021/cm4024309
26. [26]
  Mara M W, Jackson N E, Huang J, et al. J. Phys. Chem. B, 2013, 117:1921-1931 doi: 10.1021/jp311643t
27. [27]
  Garakyaraghi S, Danilov E O, McCusker C E, et al. J. Phys. Chem. A, 2015, 119:3181-3193 doi: 10.1021/acs.jpca.5b00901
28. [28]
  McCusker C E, Castellano F N. Inorg. Chem., 2013, 52:8114-8120http://med.wanfangdata.com.cn/Paper/Detail/PeriodicalPaper_PM23789625
29. [29]
  Green O, Gandhi B A, Burstyn J N. Inorg. Chem., 2009, 48:5704-5714http://med.wanfangdata.com.cn/Paper/Detail/PeriodicalPaper_PM19496591
30. [30]
  Kuang X N, Lin S, Liu J M, et al. Polyhedron, 2019, 165:51-62
31. [31]
  PAN Xun, KUANG Xiao-Nan, ZHU Ning, et al. Chinese J. Inorg. Chem., 2019, 35:361-368
32. [32]
  Zhang Y R, Yu X, Lin S, et al. Polyhedron, 2017, 138:46-56
33. [33]
  Wang Y, Kuang X N, Cui Y Z. Polyhedron, 2018, 155:135-143
34. [34]
  Sheldrick G M. SHELXTL NT Ver.5.1, University of Göttingen, Germany, 1997.
35. [35]
  Sheldrick G M. SHELXS-97 and SHELXL-97, Madison, WI, USA, 1997.
36. [36]
  Zhang L M, Yue S M, Li B, et al. Inorg. Chim. Acta, 2012, 384:225-232
37. [37]
  Villarreal W, Colina-Vegas L, Visbal G, et al. Inorg. Chem., 2017, 56:3781-3793
38. [38]
  Chen H F, Hung W Y, Chen S W, et al. Inorg. Chem., 2012, 51:12114-12121
39. [39]
  Tsukuda T, Nakamura A, Arai T, et al. Bull. Chem. Soc. Jpn., 2006, 79:288-290 doi: 10.1039/b608641a
40. [40]
  Ruina Y, Kunhua L, Yimin H, et al. Polyhedron, 1997, 16:4033-4038 doi: 10.1023/A:1018412524042
1. [1]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
2. [2]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
3. [3]
  Luyao Lu , Chen Zhu , Fei Li , Pu Wang , Xi Kang , Yong Pei , Manzhou Zhu . Ligand effects on geometric structures and catalytic activities of atomically precise copper nanoclusters. Chinese Journal of Structural Chemistry, 2024, 43(10): 100411-100411. doi: 10.1016/j.cjsc.2024.100411
4. [4]
  Zixi Zou , Jingyuan Wang , Yian Sun , Qian Wang , Da-Hui Qu . Controlling molecular assembly on time scale: Time-dependent multicolor fluorescence for information encryption. Chinese Chemical Letters, 2024, 35(7): 108972-. doi: 10.1016/j.cclet.2023.108972
5. [5]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
6. [6]
  Kangmin Wang , Liqiu Wan , Jingyu Wang , Chunlin Zhou , Ke Yang , Liang Zhou , Bijin Li . Multifunctional 2-(2′-hydroxyphenyl)benzoxazoles: Ready synthesis, mechanochromism, fluorescence imaging, and OLEDs. Chinese Chemical Letters, 2024, 35(10): 109554-. doi: 10.1016/j.cclet.2024.109554
7. [7]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
8. [8]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
9. [9]
  Xue Zhao , Mengshan Chen , Dan Wang , Haoran Zhang , Guangzhi Hu , Yingtang Zhou . Ultrafine nano-copper derived from dopamine polymerization & synchronous adsorption achieve electrochemical purification of nitrate to ammonia in complex water environments. Chinese Chemical Letters, 2024, 35(8): 109327-. doi: 10.1016/j.cclet.2023.109327
10. [10]
  Lei Wan , Yizhou Tong , Xi Lu , Yao Fu . Cobalt-catalyzed reductive alkynylation to construct C(sp)-C(sp³) and C(sp)-C(sp²) bonds. Chinese Chemical Letters, 2024, 35(7): 109283-. doi: 10.1016/j.cclet.2023.109283
11. [11]
  Zhenyang Lin . A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics. Chinese Journal of Structural Chemistry, 2024, 43(5): 100254-100254. doi: 10.1016/j.cjsc.2024.100254
12. [12]
  Jiale Zheng , Mei Chen , Huadong Yuan , Jianmin Luo , Yao Wang , Jianwei Nai , Xinyong Tao , Yujing Liu . Electron-microscopical visualization on the interfacial and crystallographic structures of lithium metal anode. Chinese Chemical Letters, 2024, 35(6): 108812-. doi: 10.1016/j.cclet.2023.108812
13. [13]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
14. [14]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
15. [15]
  Yu-Yu Tan , Lin-Heng He , Wei-Min He . Copper-mediated assembly of SO₂F group via radical fluorine-atom transfer strategy. Chinese Chemical Letters, 2024, 35(9): 109986-. doi: 10.1016/j.cclet.2024.109986
16. [16]
  Yuxiang Zhang , Jia Zhao , Sen Lin . Nitrogen doping retrofits the coordination environment of copper single-atom catalysts for deep CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100415-100415. doi: 10.1016/j.cjsc.2024.100415
17. [17]
  Tong Li , Leping Pan , Yan Zhang , Jihu Su , Kai Li , Kuiliang Li , Hu Chen , Qi Sun , Zhiyong Wang . Electrochemical construction of 2,5-diaryloxazoles via N–H and C(sp³)-H functionalization. Chinese Chemical Letters, 2024, 35(4): 108897-. doi: 10.1016/j.cclet.2023.108897
18. [18]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416
19. [19]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
20. [20]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(404)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142