Citation: ZHAO Di, LIU Hong-Yan, LI Gui-Hua, LIU Yu-Yang, CUI Zi-Shuo. Preparation and Properties of Graphene-Oxide/Ag₃PO₄/Ni Composite Films with High Photocatalytic Activity under Visible Light[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 253-260. doi: 10.11862/CJIC.2020.012 shu

Preparation and Properties of Graphene-Oxide/Ag₃PO₄/Ni Composite Films with High Photocatalytic Activity under Visible Light

Faculty of Chemistry and Material Science, Langfang Normal University, Langfang, Hebei 065000, China

Corresponding author: ZHAO Di, xin-yin841006@163.com
Received Date: 25 July 2019
Revised Date: 22 October 2019

Figures(9)

Ag₃PO₄ based-GO/Ag₃PO₄/Ni composite thin films were prepared by electrochemical co-deposition using a mixture of ammonium phosphate and graphene oxide aqueous suspension as electrolyte. Scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), Raman and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS) were employed to analyze the morphology, crystallinity and optical characteristics of the composite films. The results showed that the GO/Ag₃PO₄/Ni composite films prepared by the optimum process exhibited GO-coated surface morphology outside Ag₃PO₄ nanospheres with a diameter of about 100 nm. The strong charge interactions existed between GO sheets and Ag₃PO₄ nanospheres. As compared to Ag₃PO₄ nanospheres alone, the attachments of GO sheets led to a band gap narrowing and a strong absorbance in visible region. The photocatalytic (PC) activity and stability of the GO/Ag₃PO₄/Ni thin films were investigated by following the degradation of rhodamine B (RhB) under visible light irradiation. The PC mechanism of the composite films was explored by fluorescence spectroscopy and trapping agent method. Notably, the incorporation of GO sheets not only significantly enhanced the PC activity but also improved the structural stability of Ag₃PO₄. The efficiency of PC degradation of RhB under visible light irradiation 60 min was 1.32 times greater than that observed when a Ag₃PO₄/Ni thin film was used. GO/Ag₃PO₄/Ni thin films could be reused seven times without any significant decrease in the catalytic activity of the film. The excellent charge conductivity of GO and the positive synergistic effect between Ag₃PO₄ nanospheres and GO sheets are proposed to contribute to the improved PC properties of the composite films.
- Ag₃PO₄ based-GO/Ag₃PO₄/Ni thin films,
- photocatalysis,
- electrochemical co-deposition,
- rhodamine B,
- visible light,
- reaction mechanism
1. [1]
  Bowker M. Green Chem., 2011, 13:2235-2246 doi: 10.1039/c1gc00022e
2. [2]
  Paracchino A, Laporte V, Sivula K, et al. Nat. Mater., 2011, 10:456-461 doi: 10.1038/nmat3017
3. [3]
  Yi Z G, Ye J H, Kikugawa N, et al. Nat. Mater., 2010, 9(7):559-564 doi: 10.1038/nmat2780
4. [4]
  Bi Y P, Hu H Y, Ye J H. et al. Chem. Commun., 2012, 48(31):3748-3750 doi: 10.1039/c2cc30363a
5. [5]
  Martin D J, Liu G G, Moniz S J A, et al. Chem. Soc. Rev., 2015, 44(50):7808-7828
6. [6]
  ZHAO Di, ZHANG Bo, DUAN Zhao-Juan, et al. Chinese J. Inorg. Chem., 2016, 32(12):2158-2164
7. [7]
  Bi Y P, Ouyang S, Ye J H, et al. Phys. Chem. Chem. Phys., 2011, 13(21):10071-10075 doi: 10.1039/c1cp20488b
8. [8]
  Xu H, Li H M, Xia J X, et al. ACS Appl. Mater. Interfaces, 2011, 3(1):22-29 doi: 10.1021/am100781n
9. [9]
  LI Ai-Chang, ZHAO Di, ZHANG Ping-Ping, et al. J. Chin. Ceram. Soc., 2017, 45(1):46-53
10. [10]
  LI Ai-Chang, LI Gui-Hua, JI Xiao-Yan, et al. Chinese J. Inorg. Chem., 2017, 33(12):2247-2254 doi: 10.11862/CJIC.2017.277
11. [11]
  Zhang L L, Zhang H C, Huang H, et al. New J. Chem., 2012, 36(8):1541-1544 doi: 10.1039/c2nj40206h
12. [12]
  Yao W F, Zhang B, Huang C P, et al. J. Mater. Chem., 2012, 22:4050-4055 doi: 10.1039/c2jm14410g
13. [13]
  ZHAO Di, DUAN Zhao-Juan, GUO Feng-Hua, et al. Chinese Journal of Nonferrous Metals, 2018, 28(11):2266-2273
14. [14]
  Xu H, Wang C, Song Y H, et al. Chem. Eng. J., 2014, 241:35-42 doi: 10.1016/j.cej.2013.11.065
15. [15]
  ZHAO Hui-Min, SU Fang, FAN Xin-Fei, et al. Chin. J. Catal., 2012, 33:777-782
16. [16]
  WEI Long-Fu, YU Chang-Lin. Nonferrous Metals Science and Engineering, 2013, 4(3):34-39
17. [17]
  Wang C, Cao M H, Wang P F, et al. J. Taiwan Inst. Chem. E, 2014, 45(3):1080-1086 doi: 10.1016/j.jtice.2013.09.031
18. [18]
  Wang P Q, Chen T, Yu B Y, et al. J. Taiwan Inst. Chem. E, 2016, 62:267-274 doi: 10.1016/j.jtice.2016.02.016
19. [19]
  Wang C, Zhu J X, Wu X Y, et al. Ceram. Int., 2014, 40:8061-8070 doi: 10.1016/j.ceramint.2013.12.159
20. [20]
  YU Chang-Lin, WEI Long-Fu, LI Jia-De, et al. Acta Phys.-Chim. Sin., 2015, 31(10):1932-1938 doi: 10.3866/PKU.WHXB201509064
21. [21]
  Liang Q H, Shi Y, Ma W J, et al. Phys. Chem. Chem. Phys., 2012, 14:15657-15665 doi: 10.1039/c2cp42465g
22. [22]
  LI Ai-Chang, ZHAO Di, LU Yan-Hong, et al. Chinese J. Inorg. Chem., 2018, 34(11):2009-2018 doi: 10.11862/CJIC.2018.262
23. [23]
  Wang S, Liu C, Zheng L Z, et al. New J. Chem., 2016, 40:1323-1329 doi: 10.1039/C5NJ02728D
24. [24]
  Liu L, Liu J C, Sun D D. Catal. Sci. Technol., 2012, 2:2525-2532 doi: 10.1039/c2cy20483e
25. [25]
  Chen G D, Sun M, Wei Q, et al. J. Hazard. Mater., 2013, 244-245:86-93 doi: 10.1016/j.jhazmat.2012.11.032
26. [26]
  LI Ai-Chang, ZHAO Di, LIU Pan-Pan, et al. Chinese Journal of Nonferrous Metals, 2015, 25(8):2196-2204
27. [27]
  Loh K P, Bao Q L, Eda G, et al. Nat. Chem., 2010, 2:1015-1024 doi: 10.1038/nchem.907
28. [28]
  Cui H Y, Yang X F, Gao Q X, et al. Mater. Lett., 2013, 93:28-31 doi: 10.1016/j.matlet.2012.10.116
29. [29]
  Xu H, Wang C, Song Y H, et al. Chem. Eng. J., 2014, 241:35-42 doi: 10.1016/j.cej.2013.11.065
30. [30]
  Dong P Y, Wang Y H, Cao B C, et al. Appl. Catal. B, 2013, 132-133:45-53 doi: 10.1016/j.apcatb.2012.11.022
31. [31]
  LI Ai-Chang, ZHU Ning-Ning, LI Jing-Hong, et al. Chinese J. Inorg. Chem., 2015, 31(4):681-688
32. [32]
  Yeh T F, Chan F F, Hsieh C T, et al. J. Phys. Chem. C, 2011, 115:22587-22597 doi: 10.1021/jp204856c
33. [33]
  Yeh T F, Syu J M, Cheng C, et al. Adv. Funct. Mater., 2010, 20:2255-2262 doi: 10.1002/adfm.201000274
1. [1]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
2. [2]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
3. [3]
  Ling Fan , Meili Pang , Yeyun Zhang , Yanmei Wang , Zhenfeng Shang . Quantum Chemistry Calculation Research on the Diels-Alder Reaction of Anthracene and Maleic Anhydride: Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 133-139. doi: 10.3866/PKU.DXHX202309024
4. [4]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
5. [5]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
6. [6]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
7. [7]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
8. [8]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
9. [9]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
10. [10]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
11. [11]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
12. [12]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
13. [13]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
14. [14]
  Yong Wang , Yingying Zhao , Boshun Wan . Analysis of Organic Questions in the 37th Chinese Chemistry Olympiad (Preliminary). University Chemistry, 2024, 39(11): 406-416. doi: 10.12461/PKU.DXHX202403009
15. [15]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
16. [16]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
17. [17]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
18. [18]
  Wentao Lin , Wenfeng Wang , Yaofeng Yuan , Chunfa Xu . Concerted Nucleophilic Aromatic Substitution Reactions. University Chemistry, 2024, 39(6): 226-230. doi: 10.3866/PKU.DXHX202310095
19. [19]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
20. [20]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1889)
HTML views(275)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Properties of Graphene-Oxide/Ag3PO4/Ni Composite Films with High Photocatalytic Activity under Visible Light

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Properties of Graphene-Oxide/Ag₃PO₄/Ni Composite Films with High Photocatalytic Activity under Visible Light