Citation: ZHENG Hao, JIN Jia-Xin, CHENG Jing-Song, ZHAO Rong-Fei, LI Lin. Preparation and Electrochemical Properties of Co₃V₂O₈/graphene Composite of Anode Material for Lithium Storage[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 62-68. doi: 10.11862/CJIC.2020.010 shu

Preparation and Electrochemical Properties of Co₃V₂O₈/graphene Composite of Anode Material for Lithium Storage

1.
Key Laboratory of Functional Materials and Chemistry for Performance and Resource of Guizhou Education Department, Anshun University, Anshun, Guizhou 561000, China
2.
School of Chemical Engineering, Guizhou University of Engineering Science, Bijie, Guizhou 551700, China

Corresponding author: ZHENG Hao, zhengaho1986@126.com
Received Date: 9 June 2019
Revised Date: 21 August 2019

Figures(6)

We demonstrated the preparation of graphene oxide (GO) decorated Co₃V₂O₈ to form (Co₃V₂O₈/rGO) composite through a facile approach combining hydrothermal synthesis with thermal reduction. The XRD, Raman, XPS, SEM, (HR-)TEM, and electrochemical performance tests were used to study the relationship between the physical character and the electrochemical properties of the electrode material. As the anode material, the Co₃V₂O₈/rGO delivered excellent lithium storage properties, stable cycle performance, and high rate capability (1 208 mAh·g^-1 at 200 mA·g^-1 after 100 cycles). It is demonstrated that an enhanced cycle performance can be acquired because graphene can accelerate the electron diffusion among the Co₃V₂O₈ active particles, prevent the aggregation of Co₃V₂O₈ particles, and effectively accommodate the volume variation during the discharge/charge process and offer short pathways for the ions as well as electrons. Meanwhile, the incorporation of the Co₃V₂O₈ particles suppress the stack of graphene layer.
- Co₃V₂O₈,
- graphene,
- composite,
- anode material,
- lithium ion battery
1. [1]
  Shang H, Zuo Z C, Li L, et al. Angew. Chem., 2018, 3:774-778
2. [2]
  Pan H, Hu Y S, Chen L. Energy Environ. Sci., 2013, 6:2338-2360 doi: 10.1039/c3ee40847g
3. [3]
  Zhou L M, Zhang K, Hu Z, et al. Adv. Energy Mater., 2017:1701415
4. [4]
  Tang Y X, Zhang Y Y, Li W L. Chem. Soc. Rev., 2015, 44:5926-5940 doi: 10.1039/C4CS00442F
5. [5]
  Zhu G N, Liu H J, Zhuang J H, et al. Energy Environ. Sci., 2011, 4:4016-4022 doi: 10.1039/c1ee01680f
6. [6]
  Zheng M B, Tang H, Li L L, et al. Adv. Sci., 2018, 5:1700592 doi: 10.1002/advs.201700592
7. [7]
  Balogun M S, Zhu Y K, Qiu W T, et al. ACS Appl. Mater. Interfaces, 2015, 7:25991-26003 doi: 10.1021/acsami.5b09610
8. [8]
  Kasavajjula U, Wang C, Appleby A J. J. Power Sources, 2007, 163(2):1003-1039 doi: 10.1016/j.jpowsour.2006.09.084
9. [9]
  Park C M, Yoon S, Lee S I, et al. J. Electrochem. Soc., 2007, 154(11):S19-S25 doi: 10.1149/1.2775571
10. [10]
  Wu F F, Xiong S L, Qian Y T, et al. Angew. Chem., 2015, 127:10937-10941 doi: 10.1002/ange.201503487
11. [11]
  Zhang Q, Pei J, Chen G, et al. Electrochim. Acta, 2017, 238:227-236 doi: 10.1016/j.electacta.2017.04.013
12. [12]
  Guo A, Chen E, Wygant B R, et al. ACS Appl. Energy Mater., 2019, 25:3017-3020
13. [13]
  Wang S, Yang B, Chen H, et al. Energy Storage Mater., 2019, 16:619-624 doi: 10.1016/j.ensm.2018.07.013
14. [14]
  Yuan C Z, Wu H B, Xie Y, et al. Angew. Chem., Int. Ed., 2014, 53:1488-1504 doi: 10.1002/anie.201303971
15. [15]
  Raccichini R, Varzi A, Passerini S, et al. Nat. Mater., 2015, 14:271-279 doi: 10.1038/nmat4170
16. [16]
  Gao G, Lu S, Dong B, et al. J. Mater. Chem. A, 2016, 4:6264-6270 doi: 10.1039/C5TA10719A
17. [17]
  Pan L, Zhang Y, Lu F, et al. Energy Storage Mater., 2019, 19:39-47 doi: 10.1016/j.ensm.2018.10.007
18. [18]
  Yi T F, Zhu Y R, Tao W, et al. J. Power Sources, 2018, 399:26-41 doi: 10.1016/j.jpowsour.2018.07.086
19. [19]
  Han X, Gui X, Yi T F, et al. Curr. Opin. Solid State Mater. Sci., 2018, 22(4):109-126 doi: 10.1016/j.cossms.2018.05.005
20. [20]
  Xu L T, Lv W, Shi K, et al. Carbon, 2019, 149:257-262 doi: 10.1016/j.carbon.2019.04.025
21. [21]
  Han X Y, Zhao D L, Meng W J, et al. Appl. Surf. Sci., 2019, 484:11-20 doi: 10.1016/j.apsusc.2019.04.100
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrochemical Properties of Co3V2O8/graphene Composite of Anode Material for Lithium Storage

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通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Properties of Co₃V₂O₈/graphene Composite of Anode Material for Lithium Storage