Citation: ZHENG Hao, JIN Jia-Xin, CHENG Jing-Song, ZHAO Rong-Fei, LI Lin. Preparation and Electrochemical Properties of Co₃V₂O₈/graphene Composite of Anode Material for Lithium Storage[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 62-68. doi: 10.11862/CJIC.2020.010 shu

Preparation and Electrochemical Properties of Co₃V₂O₈/graphene Composite of Anode Material for Lithium Storage

1.
Key Laboratory of Functional Materials and Chemistry for Performance and Resource of Guizhou Education Department, Anshun University, Anshun, Guizhou 561000, China
2.
School of Chemical Engineering, Guizhou University of Engineering Science, Bijie, Guizhou 551700, China

Corresponding author: ZHENG Hao, zhengaho1986@126.com
Received Date: 9 June 2019
Revised Date: 21 August 2019

Figures(6)

We demonstrated the preparation of graphene oxide (GO) decorated Co₃V₂O₈ to form (Co₃V₂O₈/rGO) composite through a facile approach combining hydrothermal synthesis with thermal reduction. The XRD, Raman, XPS, SEM, (HR-)TEM, and electrochemical performance tests were used to study the relationship between the physical character and the electrochemical properties of the electrode material. As the anode material, the Co₃V₂O₈/rGO delivered excellent lithium storage properties, stable cycle performance, and high rate capability (1 208 mAh·g^-1 at 200 mA·g^-1 after 100 cycles). It is demonstrated that an enhanced cycle performance can be acquired because graphene can accelerate the electron diffusion among the Co₃V₂O₈ active particles, prevent the aggregation of Co₃V₂O₈ particles, and effectively accommodate the volume variation during the discharge/charge process and offer short pathways for the ions as well as electrons. Meanwhile, the incorporation of the Co₃V₂O₈ particles suppress the stack of graphene layer.
- Co₃V₂O₈,
- graphene,
- composite,
- anode material,
- lithium ion battery
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Properties of Co₃V₂O₈/graphene Composite of Anode Material for Lithium Storage