Citation: SUN Yun-Po, XIE Jian, ZHAO Xin-Bing, ZHUANG Da-Gao, ZHANG Gen-Lin. Prussian Blue Cathode Material: Preparation by Ion-Exchange Method and Electrochemical Potassium-Storage Performance[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 106-112. doi: 10.11862/CJIC.2020.008 shu

Prussian Blue Cathode Material: Preparation by Ion-Exchange Method and Electrochemical Potassium-Storage Performance

1.
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
2.
Shanghai Han Xing Science and Technology Co., Ltd., Shanghai 201322, China

Corresponding author: XIE Jian, xiejian1977@zju.edu.cn
Received Date: 4 July 2019
Revised Date: 11 November 2019

Figures(5)

Na-doped K-based Prussian blue (NKPB) material (K_1.9Na_0.1Mn[Fe(CN)₆]·0.4H₂O) was prepared by ion-exchange method using KCl and Na-based Prussian blue (NPB) material(Na_2-xMn[Fe(CN)₆]_z·yH₂O) as the precursors. The electrochemical tests reveal that compared with the K-based Prussian blue (KPB) material K_1.85Mn[Fe(CN)₆]_0.98□_0.02·0.7H₂O (□ is the[Fe(CN)₆] vacancy) prepared by a conversional coprecipitation route, the NKPB prepared by ion-exchange method shows higher capacity (the initial discharge capacity at 0.1C reached 136.3 mAh·g^-1), longer cycle life (the capacity retention after 100 cycles at 0.5C was 96.1%), and better rate capability (the capacities at 5C and 10C were 87.6 and 68.4 mAh·g^-1, respectively). The outstanding electrochemical performance of the NKPB material is ascribed to its high K content, good crystal integrity, Na-ion doping, nanosized particles and the unique open framework structure.
- potassium-ion battery,
- cathode material,
- Prussian blue material,
- ion-exchange method,
- electrochemical performance
1. [1]
  Reinhardt R, Christodoulou I, Gassó-Domingo S, et al. J. Environ. Manage., 2019, 245:432-446 doi: 10.1016/j.jenvman.2019.05.095
2. [2]
  Chu S, Cui Y, Liu N. Nat. Mater., 2016, 16(1):16-22
3. [3]
  Chen M Z, Liu Q N, Wang S W, et al. Adv. Energy Mater., 2019, 9(14):1803609 doi: 10.1002/aenm.201803609
4. [4]
  Wang Y R, Chen R P, Chen T, et al. Energy Storage Mater., 2016, 4:103-129 doi: 10.1016/j.ensm.2016.04.001
5. [5]
  Zhang J D, Liu T T, Cheng X, et al. Nano Energy, 2019, 60:340-361 doi: 10.1016/j.nanoen.2019.03.078
6. [6]
  ZHANG Ning, LIU Yong-Chang, CHEN Cheng-Cheng, et al. Chinese J. Inorg. Chem., 2015, 31(9):1739-1750
7. [7]
  Kubota K, Dahbi M, Hosaka T, et al. Chem. Rec., 2018, 18(4):459-479 doi: 10.1002/tcr.201700057
8. [8]
  Eftekhari A, Jian Z L, Ji X L. ACS Appl. Mater. Interfaces, 2017, 9(5):4404-4419 doi: 10.1021/acsami.6b07989
9. [9]
  Pramudita J C, Sehrawat D, Goonetilleke D, et al. Adv. Energy Mater., 2017, 7(24):1602911 doi: 10.1002/aenm.201602911
10. [10]
  Xu G L, Amine R, Abouimrane A, et al. Adv. Energy Mater., 2018, 8(14):1702403 doi: 10.1002/aenm.201702403
11. [11]
  Kim H, Kim J C, Bianchini M, et al. Adv. Energy Mater., 2018, 8(9):1702384 doi: 10.1002/aenm.201702384
12. [12]
  Bie X F, Kubota K, Hosaka T, et al. J. Mater. Chem. A, 2017, 5(9):4325-4330 doi: 10.1039/C7TA00220C
13. [13]
  Shadike Z, Shi D R, Wang T, et al. J. Mater. Chem. A, 2017, 5(14):6393-6398 doi: 10.1039/C7TA00484B
14. [14]
  Xue L G, Li Y T, Gao H C, et al. J. Am. Chem. Soc., 2017, 139(6):2164-2167 doi: 10.1021/jacs.6b12598
15. [15]
  Shen Z L, Guo S H, Liu C L, et al. ACS Sustainable Chem. Eng., 2018, 6(12):16121-16129 doi: 10.1021/acssuschemeng.8b02758
16. [16]
  Li W J, Han C, Cheng G, et al. Small, 2019:e1900470
17. [17]
  Baioun A, Kellawi H, Falah A. Curr. Nanosci., 2018, 14(3):227-233 doi: 10.2174/1573413714666180103153511
18. [18]
  CHEN Xin, XU Li, SHEN Zhi-Long, et al. Chinese J. Inorg. Chem., 2015, 31(9):1739-1750
19. [19]
  Song J, Wang L, Lu Y H, et al. J. Am. Chem. Soc., 2015, 137(7):2658-2664 doi: 10.1021/ja512383b
20. [20]
  Jiang X L, Liu H J, Song J, et al. J. Mater. Chem. A, 2016, 4(41):16205-16212 doi: 10.1039/C6TA06658E
21. [21]
  Jiang X, Zhang T R, Yang L Q, et al. ChemElectroChem, 2017, 4(9):2237-2242 doi: 10.1002/celc.201700410
22. [22]
  Jiang P, Shao H Z, Chen L, et al. J. Mater. Chem. A, 2017, 5(32):16740-16747 doi: 10.1039/C7TA04172A
23. [23]
  Chen T, Jin G P, Meng G J, et al. J. Environ. Chem. Eng., 2019, 7(1):102799 doi: 10.1016/j.jece.2018.10.070
24. [24]
  Bhatt P, Banerjee S, Anwar S, et al. ACS Appl. Mater. Interfaces, 2014, 6(20):17579-17588 doi: 10.1021/am503526c
25. [25]
  Bie X F, KubotaK, Hosaka T, J. et al. J. Mater. Chem. A, 2017, 5(9):43254330
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
3. [3]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
4. [4]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
5. [5]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
6. [6]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
7. [7]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
8. [8]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
9. [9]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
10. [10]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
11. [11]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
12. [12]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
13. [13]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
14. [14]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
15. [15]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
16. [16]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
17. [17]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
18. [18]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
19. [19]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
20. [20]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009

Get Citation

PDF

XML

Metrics

PDF Downloads(38)
Abstract views(2728)
HTML views(925)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142