Citation: YANG Huang-Gen, CHEN Yuan, WANG Zhi-Wei, YANG Jia-Tian, ZHU Li-Gang, QIN Li-Qin, DAI Hong-Xing. Facile Solvothermal Synthesis of Porous Persimmon-like BiOBr Photocatalyst[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 333-344. doi: 10.11862/CJIC.2020.007 shu

Facile Solvothermal Synthesis of Porous Persimmon-like BiOBr Photocatalyst

1.
Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology, College of Chemistry and Food Science, Yulin Normal University, Yulin, Guangxi 537000, China
2.
Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Beijing on Regional Air Pollution Control, Key Laboratory of Advanced Functional Materials, Education Ministry of China, and Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

Corresponding author: CHEN Yuan, chenyuan197191@163.com DAI Hong-Xing, hxdai@bjut.edu.cn
Received Date: 16 May 2019
Revised Date: 14 November 2019

Figures(12)

Porous nanosheet-aggregated persimmon-like bismuth oxybromide (BiOBr) were successfully prepared for the first time using polyvinyl pyrrolidone (PVP)-assisted solvothermal strategy with bismuth nitrate and cetyltrimethyl ammonium bromide (CTAB) as Bi and Br sources. Physicochemical properties of the hierarchical microstructure BiOBr materials were characterized by means of numerous analytical techniques, and their photocatalytic activities were evaluated for the removal of methylene blue (MB) under visible-light illumination. It is found that the solvothermal time and PVP addition had a significant influence on the particle morphology and crystallinity of the product. The porous sheet-aggregated persimmon-like BiOBr sample could be obtained after solvothermal treatment at 120℃ for 12 h in the presence of 0.7 g PVP. The porous persimmon-like BiOBr sample with a surface area of 4 m²·g^-1 and a bandgap energy of 2.64 eV possessed good optical absorption property in visible-light regions and showed excellent visible-light-driven photocatalytic activity and stability for MB degradation. It is concluded that the high visible-light-driven catalytic performance of the porous sheet-aggregated persimmon-like BiOBr sample is associated with its high surface area, porous structure, and low bandgap energy as well as the unique particle morphology.
- solvothermal synthesis,
- persimmon-like BiOBr,
- hierarchical microstructure,
- visible-light-driven photocatalysis,
- organic dye degradation
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沈阳化工大学材料科学与工程学院沈阳 110142