Citation: ZHONG Wei, XIA Ying-Fan, ZHAI Hang-Ling, GAO Yue, LI Shi-Hui, LÜ Chun-Xin. Preparation by Co-precipitation Method and Photocatalytic Performances on the Degradation of Dyes of Ce³⁺-Doped Nano-ZnO[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 40-52. doi: 10.11862/CJIC.2020.006 shu

Preparation by Co-precipitation Method and Photocatalytic Performances on the Degradation of Dyes of Ce³⁺-Doped Nano-ZnO

ZHONG Wei ^1,2,, ,
XIA Ying-Fan ² ,
ZHAI Hang-Ling ² ,
GAO Yue ² ,
LI Shi-Hui ² ,
LÜ Chun-Xin ^2,,

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
2.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China

Corresponding author: ZHONG Wei, weizhong@mail.zjxu.edu.cn LÜ Chun-Xin, chunxin0923@163.com
Received Date: 29 August 2019
Revised Date: 15 October 2019

Figures(16)

A series of nano-ZnO doped with different amounts of cerium were prepared by co-precipitation method with Zn(NO₃)₂·6H₂O and Ce(NO₃)₃·6H₂O as raw materials. The as-made samples were characterized by powder X-ray diffraction (XRD), infrared spectroscopy (IR), scanning electron microscope (SEM), energy dispersive spectrometer (EDS) and UV-visible diffuse reflectance spectroscopy (UV-Vis DRS). Some samples were further characterized by X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL). Photocatalytic activity of these materials toward photodegradation of methylene blue (MB) was evaluated under UV and sunlight irradiation, respectively. It was found that the sample with 3% Ce³⁺ doped ZnO, named as ZnO-3% Ce, exhibited highest photocatalytic activity among the prepared samples and its MB-degradation efficiency was over 98%. Then, the sample of ZnO-3% Ce was selected to further evaluate its photocatalytic activity toward photodegradation of rhodamine B (RhB) and methyl orange (MO) under both UV and sunlight irradiation. The results showed that the sample of ZnO-3% Ce presented good photodegradation activity under both UV and sunlight condition. The order of photodegradation efficiency under sunlight irradiation was as follows:MB > RhB > MO, while the photocatalytic activity under UV irradiation was increased by the following order RhB > MB > MO. The stability of ZnO-3%Ce catalyst was studied by cyclic experiments. The results showed that the photodegradation efficiency still retained more than 97% after three cycles, suggesting that the catalyst maintained its structure and component and presented good stability and application prospect.
- nano-ZnO,
- rare earth element,
- doping,
- photocatalysis,
- degradation,
- dyes
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation by Co-precipitation Method and Photocatalytic Performances on the Degradation of Dyes of Ce3+-Doped Nano-ZnO

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通讯作者: 陈斌, bchen63@163.com

Preparation by Co-precipitation Method and Photocatalytic Performances on the Degradation of Dyes of Ce³⁺-Doped Nano-ZnO