Citation: ZHANG Shu, GUO Hong-Fei, LIU Xiu-Wu, CHEN Xue-Qing, ZHAO Bin, CAO Ji-Lin. Rapid Synthesis of Zeolite P with High Calcium and Magnesium Ion Exchange Properties by Like-Solid Phase Method[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2323-2330. doi: 10.11862/CJIC.2019.276 shu

Rapid Synthesis of Zeolite P with High Calcium and Magnesium Ion Exchange Properties by Like-Solid Phase Method

Hebei Provincial Key Lab of Green Chemical Technology and High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

Corresponding author: ZHAO Bin, 1990014@hebut.edu.cn CAO Ji-Lin, caojilin@eyou.com
Received Date: 21 July 2019
Revised Date: 29 September 2019

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The synthesis of zeolite P by like-solid phase method was studied, using silicon aluminum xerogels as silicon source and aluminum source, and the sodium hydroxide as the alkali source. The products were characterized and analyzed by methods such as X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results showed that the zeolite P product with uniform morphology and good crystallinity can be prepared, when the n_SiO₂/n_Al₂O₃ of the silicon aluminum xerogels was 5, the crystallization time and crystallization temperature were 3 h and 140℃, and the n_Na₂O/n_SiO₂ and n_H₂O/n_SiO₂ of the raw material were 0.26 and 18.51, respectively. Compared with the traditional hydrothermal method, the like-solid phase method greatly reduces the amount of water used in the synthesis process, shortens the crystallization time, improves the ion exchange performances of Ca²⁺ and Mg²⁺, and overall optimizes the synthesis process of zeolite P.
- like-solid phase method,
- zeolite P,
- water-silicon ratio,
- calcium and magnesium ion exchange properties
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