Citation: RAO Chong-Shun, ZHANG Xin, YANG Jing-Hao, LIU Qian, ZHOU Yi-Fan. Effect of C₁₀H₁₀Cl₂Ti on Hydrogen Storage Properties of 6LiBH₄-CaH₂-3MgH₂ System[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2233-2242. doi: 10.11862/CJIC.2019.275 shu

Effect of C₁₀H₁₀Cl₂Ti on Hydrogen Storage Properties of 6LiBH₄-CaH₂-3MgH₂ System

1.
Henan Key Laboratory of Advanced Magnesium Alloy, School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
2.
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
3.
Teaching and Research Office, PLA Army Academy of Artillery and Air Defense(Zhengzhou Campus), Zhengzhou 450000, China

Corresponding author: ZHOU Yi-Fan, zhouyf@zzu.edu.cn
Received Date: 27 April 2019
Revised Date: 25 September 2019

Figures(15)

C₁₀H₁₀Cl₂Ti was selected as an additive to improve the hydrogen storage properties of the 6LiBH₄-CaH₂-3MgH₂ sample, with optimum hydrogen storage performances by 5%(w/w) addition. The onset and ending temperatures for the dehydrogenation of the sample were 30 and 25℃, which were lower than those of the pristine sample, and its reversible hydrogen storage capacity was about 8.1%(w/w). The desorption rate of the C₁₀H₁₀Cl₂Ti-doped sample was 1.78 times faster than that of the pristine sample in the isothermal dehydrogenation mode at 360℃. The apparent activation energy (Ea) of the two-step reaction was calculated to be 131.4 and 138.8 kJ·mol^-1, which were 18.6% and 15.8% lower than the pristine sample, respectively. Further XPS analyses indicate that the multivalence state Ti compounds generate during thermal decomposition of C₁₀H₁₀Cl₂Ti, which plays an important role to improve the hydrogen storage properties of the 6LiBH₄-CaH₂-3MgH₂ system.
- hydrogen storage materials,
- C₁₀H₁₀Cl₂Ti,
- LiBH₄,
- dehydrogenation-hydrogenation properties,
- kinetics
1. [1]
  Schlapbach L, Züttel A. Nature, 2001, 414(6861):353-358
2. [2]
  ZHANG Si-Qi. Materials Research and Application, 2017, 11(4):211-215
3. [3]
  FU Jian-Long. Modern Chemical Research, 2018, 10:121-123
4. [4]
  ZHANG Xin, SHEN Zheng Yang, JIAN Ni, et al. Chinese J. Inorg. Chem., 2019, 35(1):101-108
5. [5]
  Jena P. J. Phys. Chem. Lett., 2011, 2(3):206-211 doi: 10.1021/jz1015372
6. [6]
  Jones R H, Thomas G. JOM, 2007, 59(12):50-55
7. [7]
  Liu J J, Li K, Cheng H H, et al. Int. J. Hydrogen Energy, 2017, 42(39):24904-24914 doi: 10.1016/j.ijhydene.2017.07.213
8. [8]
  Liu Y F, Du H F, Zhang X, et al. Chem. Commun., 2016, 52(4):705-708 doi: 10.1039/C5CC08801A
9. [9]
  Züttel A, Wenger P, Rentsch S, et al. J. Power Sources, 2003, 181(1):1-7
10. [10]
  Yan Y, Rentsch D, Remhof A. Phys. Chem. Chem. Phys., 2017, 19(11):7788-7792
11. [11]
  Mauron P, Buchter F, Friedrichs O, et al. J. Phys. Chem. B, 2008, 112(3):906-910
12. [12]
  Yang J, Sudik A, Wolverton C. J. Phys. Chem. C, 2007, 111(51):19134-19140 doi: 10.1021/jp076434z
13. [13]
  Au M, Spencer W, Jurgensen A, et al. J. Alloys Compd., 2008, 462(1):303-309
14. [14]
  Yu X B, Tang Z W, Sun D L, et al. Prog. Mater. Sci., 2017, 88:1-48 doi: 10.1016/j.pmatsci.2017.03.001
15. [15]
  Vajo J J, Skeith S L, Mertens F. J. Phys. Chem. B, 2005, 109(9):3719-3722 doi: 10.1021/jp040769o
16. [16]
  Vajo J J, Olson G L. Scr. Mater., 2007, 56(10):829-834 doi: 10.1016/j.scriptamat.2007.01.002
17. [17]
  Li Y, Li P, Qu X H. Sci. Rep., 2017, 7:41754 doi: 10.1038/srep41754
18. [18]
  Liu D M, Huang W J, Si T Z, et al. J. Alloys Compd., 2013, 551:8-11 doi: 10.1016/j.jallcom.2012.09.138
19. [19]
  Shim J H, Lim J H, Rather S U, et al. J. Phys. Chem. Lett., 2010, 1(1):59-63 doi: 10.1021/jz900012n
20. [20]
  Yu X B, Grant D M, Walker G S, et al. J. Phys. Chem. C, 2009, 113(41):17945-17949 doi: 10.1021/jp906519p
21. [21]
  Zhang B J, Liu B H. Int. J. Hydrogen Energy, 2010, 35(14):7288-7294 doi: 10.1016/j.ijhydene.2010.04.165
22. [22]
  Deprez E, Palomares F J, Soria F, et al. J. Appl Phys., 2011, 109(1):014913 doi: 10.1063/1.3525803
23. [23]
  Deprez E, Miguel A, Manuel A, et al. J. Phys. Chem. C, 2010, 114(7):3309-3317 doi: 10.1021/jp910955r
24. [24]
  Zhou Y F, Liu Y F, Zhang Y, et al. Dalton Trans., 2012, 41(36):10980-10987 doi: 10.1039/c2dt30945a
25. [25]
  Surrey A, Minella C B, Fechler N, et al. Int. J. Hydrogen Energy, 2016, 41(12):5540-5548 doi: 10.1016/j.ijhydene.2016.01.163
26. [26]
  Biesinger M C, Lau L W M, Gerson A R, et al. Appl. Surf. Sci., 2010, 257(3):887-893
27. [27]
  Zhang X, Ren Z H, Lu Y H, et al. ACS Appl. Mater. Interface, 2018, 10(18):15767-15777
1. [1]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
2. [2]
  Jing JIN , Zhuming GUO , Zhiyin XIAO , Xiujuan JIANG , Yi HE , Xiaoming LIU . Tuning the stability and cytotoxicity of fac-[Fe(CO)₃I₃]^- anion by its counter ions: From aminiums to inorganic cations. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 991-1004. doi: 10.11862/CJIC.20230458
3. [3]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
4. [4]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
5. [5]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
6. [6]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
7. [7]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
8. [8]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
9. [9]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
10. [10]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
11. [11]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
12. [12]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
13. [13]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
14. [14]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
15. [15]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
16. [16]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
17. [17]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
18. [18]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
19. [19]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
20. [20]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(465)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of C10H10Cl2Ti on Hydrogen Storage Properties of 6LiBH4-CaH2-3MgH2 System

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of C₁₀H₁₀Cl₂Ti on Hydrogen Storage Properties of 6LiBH₄-CaH₂-3MgH₂ System