Citation: JIA Hai-Lang, PENG Zhi-Jie, LI Shan-Shan, GONG Bing-Quan, GUAN Ming-Yun. Self-Assembly with Zinc Porphyrin Antenna for Dye-Sensitized Solar Cells[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2337-2345. doi: 10.11862/CJIC.2019.274 shu

Self-Assembly with Zinc Porphyrin Antenna for Dye-Sensitized Solar Cells

School of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, China

Corresponding author: JIA Hai-Lang, jiahailang85@126.com
Received Date: 25 April 2019
Revised Date: 18 September 2019

Figures(7)

Two antenna molecules zinc porphyrin P2, P3 were prepared, and these antenna molecules have been successfully used in DSSCs (dye-sensitized solar cells) through supramolecular self-assembly. Compared with traditional D-π-A structure dyes, this strategy shows obvious advantages. This method can avoid complex synthesis steps, the light-harvesting ability of dyes can be improved and charge recombination can be reduced by adjusting the antenna molecules and anchoring groups. When 4-pyrid-4-ylbenzoic acid (A) was used as the anchoring group, after supramolecular self-assembly, the device of A-P2 displayed a PCE (power conversion efficiency) of 1.68%, and the V_oc was 526 mV, the J_sc was 5.39 mA·cm^-2. This indicates that the supramolecular self-assembly strategy has been successfully applied in DSSC. The device of A-P3 displayed the PCE of 0.79%, which is mainly due to the lower amount of dye loading. In addition, the optical properties, electrochemical properties, photovoltaic performance were also studied.
- dye-sensitized solar cells,
- zinc porphyrin,
- self-assembly,
- antenna molecule
1. [1]
  Ardo S, Meyer G J. Chem. Soc. Rev., 2009, 38:115-164 doi: 10.1039/B804321N
2. [2]
  Wu J, Lan Z, Lin J, et al. Chem. Rev., 2015, 115:2136-2173 doi: 10.1021/cr400675m
3. [3]
  YANG Ying, PAN De-Qun, GAO Jing, et al. Chinese J. Inorg. Chem., 2018, 34:615-626 doi: 10.11862/CJIC.2018.100
4. [4]
  Hagfeldt A, Boschloo G, Sun L, et al. Chem. Rev., 2010, 110:6595-6663 doi: 10.1021/cr900356p
5. [5]
  Zhang Q, Uchaker E, Candelariaza S L, et al. Chem. Soc. Rev., 2013, 42:3127-3171 doi: 10.1039/c3cs00009e
6. [6]
  Kakiage K, Aoyama Y, Yano T, et al. Chem. Commun., 2015, 51:15894-15897 doi: 10.1039/C5CC06759F
7. [7]
  Ragoussi M E, Torres T. Chem. Commun., 2015, 51:3957-3972 doi: 10.1039/C4CC09888A
8. [8]
  Li C T, Wu F L, Lee B H, et al. ACS Appl. Mater. Interfaces, 2017, 9:43739-43746 doi: 10.1021/acsami.7b15181
9. [9]
  ZHOU Wei-Nan, ZHAO Hong-Bin, CAI Zhuo-Di, et al. Chinese J. Inorg. Chem., 2016, 32:81-88
10. [10]
  Huang L, Ma P, Deng G, et al. Dyes Pigm., 2018, 159:107-114 doi: 10.1016/j.dyepig.2018.06.010
11. [11]
  Miao K, Liang M, Wang Z, et al. Phys. Chem. Chem. Phys., 2017, 19:1927-1936 doi: 10.1039/C6CP07335B
12. [12]
  Zeng K, Lu Y, Tang W, et al. Chem. Sci., 2019, 10:2186-2192 doi: 10.1039/C8SC04969F
13. [13]
  Lu J, Liu S, Wang M, et al. Front. Chem., 2018, 6:541 doi: 10.3389/fchem.2018.00541
14. [14]
  Boaretto R, Carli S, Caramori S, et al. Dalton Trans., 2017, 46:16390-16393 doi: 10.1039/C7DT03536E
15. [15]
  Patil D S, Sonigara K K, Jadhav M M, et al. New J. Chem., 2018, 42:4361-4371 doi: 10.1039/C7NJ04620K
16. [16]
  Tang Y, Wang Y, Li X, et al. ACS Appl. Mater. Interfaces, 2015, 7:27976-27985 doi: 10.1021/acsami.5b10624
17. [17]
  Cheng Y, Yang G, Jiang H, et al. ACS Appl. Mater. Interfaces, 2018, 10:38880-38891 doi: 10.1021/acsami.8b12883
18. [18]
  Song H, Liu Q, Xie Y, et al. Chem. Commun., 2018, 54:1811-1824 doi: 10.1039/C7CC09671B
19. [19]
  Yun S, Qin Y, Uhl A R, et al. Energy Environ. Sci., 2018, 11:476-526 doi: 10.1039/C7EE03165C
20. [20]
  Yang L, Chen S, Zhang J, et al. J. Mater. Chem. A, 2017, 5:3514-3522 doi: 10.1039/C6TA10506H
21. [21]
  Nazeeruddin M K, Angelis F D, Fantacci S, et al. J. Am. Chem. Soc., 2005, 127:16835-16847 doi: 10.1021/ja052467l
22. [22]
  Yu Q J, Wang Y H, Yi Z H, et al. Acs, Nano., 2010, 4:6032-6038 doi: 10.1021/nn101384e
23. [23]
  Wang C L, Zhang M, Hsiao Y H, et al. Energy Environ. Sci., 2016, 9:200-206 doi: 10.1039/C5EE02505B
24. [24]
  Krishna J V S, Krishna N V, Chowdhury T H, et al. J. Mater. Chem. C, 2018, 6:11444-11456 doi: 10.1039/C8TC04370A
25. [25]
  Song H, Zhang J, Jin J, et al. J. Mater. Chem. C, 2018, 6:3927-3936 doi: 10.1039/C8TC00610E
26. [26]
  Ji J M, Zhou H, Kim H K, et al. J. Mater. Chem. A, 2018, 6:14518-14545 doi: 10.1039/C8TA02281J
27. [27]
  Yella, Lee H W, Tsao H N, et al. Science, 2011, 334:629-634 doi: 10.1126/science.1209688
28. [28]
  Mathew S, Yella A, Gao P, et al. Nat. Chem., 2014, 6:242-247 doi: 10.1038/nchem.1861
29. [29]
  Pei K, Wu Y, Li H, et al. ACS Appl. Mater. Interfaces, 2015, 7:5296-5304 doi: 10.1021/am508623e
30. [30]
  Qian X, Zhu Y Z, Chang W Y, et al. ACS Appl. Mater. Interfaces, 2015, 7:9015-9022 doi: 10.1021/am508400a
31. [31]
  Han M L, Zhu Y Z, Liu S, et al. J. Power Sources, 2018, 387:117-125 doi: 10.1016/j.jpowsour.2018.03.059
32. [32]
  Mao M, Li Q S, Zhang X L, et al. Dyes Pigm., 2017, 141:148-160 doi: 10.1016/j.dyepig.2017.02.017
33. [33]
  Yao Z, Wu H, Li Y, et al. Energy Environ. Sci., 2015, 8:3192-3197 doi: 10.1039/C5EE02822A
34. [34]
  Hung W I, Liao Y Y, Lee T H, et al. Chem. Commun., 2015, 51:2152-2155 doi: 10.1039/C4CC09294E
35. [35]
  Jradi F M, Kang X, O'Neil D, et al. Chem. Mater., 2015, 27:2480-2487 doi: 10.1021/cm5045946
36. [36]
  Subbaiyan N K, Hill J P, Ariga K, et al. Chem. Commun., 2011, 47:6003-6005 doi: 10.1039/c1cc10802f
37. [37]
  Nogueira A F, Furtado L F O, Formiga A L B, et al. Inorg. Chem., 2004, 43:396-398 doi: 10.1021/ic0345727
38. [38]
  Han F M, Yang J Y, Zhe Y, et al. Dalton Trans., 2016, 45:8862-8868 doi: 10.1039/C6DT00377J
39. [39]
  Panda D K, Goodson F S, Ray S, et al. Chem. Commun., 2014, 50:5358-5360 doi: 10.1039/C3CC47498D
40. [40]
  Zhao D X, Bian L Y, Luo Y X, et al. Dyes Pigm., 2017, 140:278-285 doi: 10.1016/j.dyepig.2017.01.051
41. [41]
  Zhang L Y, Zou S J, Sun X H, et al. RSC Adv., 2018, 8:6212-6217 doi: 10.1039/C7RA12229B
42. [42]
  Krishna N V, Krishna J V S, Singh S P, et al. J. Phys. Chem. C, 2017, 121:25691-25704 doi: 10.1021/acs.jpcc.7b07692
43. [43]
  Li C T, Wu F L, Lee B H. ACS Appl. Mater. Interfaces, 2017, 9:43739-43746 doi: 10.1021/acsami.7b15181
44. [44]
  Wu J, Li G, Zhang L, et al. J. Mater. Chem. A, 2016, 4:3342-3355 doi: 10.1039/C5TA09763K
45. [45]
  Chen Y F, Liu J M, Huang J F, et al. J. Mater. Chem. A, 2015, 3:8083-8090 doi: 10.1039/C5TA00332F
46. [46]
  Desta M B, Vinh N S, Kumar C P, et al. J. Mater. Chem. A, 2018, 6:13778-13789 doi: 10.1039/C8TA04774J
47. [47]
  Li W, Wu Y, Zhang Q, et al. ACS Appl. Mater. Interfaces, 2012, 4:1822-1830 doi: 10.1021/am3001049
48. [48]
  Babu D D, Su R, El-Shafei A, et al. RSC Adv., 2016, 6:30205-30216 doi: 10.1039/C6RA03866B
49. [49]
  Yen Y S, Ni J S, Hung W I, et al. ACS Appl. Mater. Interfaces, 2016, 8:6117-6126 doi: 10.1021/acsami.6b00806
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2. [2]
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4. [4]
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