Citation: LIU Dong-Ning, WANG Cui-Juan, XIAO Yu-Mei, LIU Cheng, LUO Dan, ZHU Zi-Xin, CHEN Shuang, WANG Yao-Yu. Synthesis and Catalytic Properties of Co²⁺/Cd²⁺ Composite Materials[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2193-2199. doi: 10.11862/CJIC.2019.270 shu

Synthesis and Catalytic Properties of Co²⁺/Cd²⁺ Composite Materials

1.
Department of Chemistry and Chemical Engineering, School of Life Science and Bioengineering, Southwest Jiaotong University, Chengdu 610031, China
2.
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry, Northwest University, Xi'an 710069, China

Corresponding author: WANG Cui-Juan, ejuan6046@163.com
Received Date: 1 August 2019
Revised Date: 21 October 2019

Figures(6)

In the same reaction conditions, the isotactic metal-doped[Co_xCd_1-x(pypymba)₂]_n (0 ≤ x ≤ 1) (compounds 1~5) were synthesized based on ligand (Hpypymba=4-((3-(pyrazin-2-yl)-1H-pyrazol-1-yl)-methyl)benzoic acid) and a transition metal ion (Co(Ⅱ), Cd(Ⅱ)). The structure and morphology were characterized by powder X-ray diffraction (PXRD) and UV-visible scanning. The obtained MOFs were used as a catalyst carrier to carry Ag ions to carry out a reduction reaction of 4-nitrophenol. The results showed that the Compound 1 which contained Co²⁺ was the better catalyst carrier. As the proportion of Cd²⁺ in compounds increased, the reaction rate decreased, and even the reaction has a certain inhibitory effect. The maximum loading of the MOFs for Ag was 47%(w/w), and 96% of the catalytic efficiency after 4 cycles.
- coordination chemistry,
- metal-organic frameworks,
- metal-doped,
- catalyst
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Catalytic Properties of Co2+/Cd2+ Composite Materials

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Catalytic Properties of Co²⁺/Cd²⁺ Composite Materials