Citation: LI Zhi-Xue, REN Tie-Qiang, GENG Zhong-Xing, YANG Zhan-Xu. Preparation and Electrocatalytic Performance of Flake Co₉S₈/ZnS/C Composites for Oxygen Evolution Reduction[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2318-2322. doi: 10.11862/CJIC.2019.266 shu

Preparation and Electrocatalytic Performance of Flake Co₉S₈/ZnS/C Composites for Oxygen Evolution Reduction

College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, Liaoning 113006, China

Corresponding author: YANG Zhan-Xu, zhanxuy@126.com
Received Date: 5 July 2019
Revised Date: 29 October 2019

Figures(7)

The flake Co₉S₈/ZnS/C composites were prepared by solvothermal method, through using cobalt hexahydrate[Co(NO₃)₂·6H₂O] as cobalt source, zinc hexahydrate nitrate[Zn(NO₃)₂·6H₂O] as zinc source and 2, 2'-thiodiacetic acid (C₄H₆O₄S) as sulfur source. The flake Co₉S₈/ZnS/C composites structure and morphology were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N₂ adsorption-desorption test. Meanwhile, the results of electrocatalytic oxygen evolution reaction for the flake Co₉S₈/ZnS/C composite showed that it had high electrocatalytic oxygen production performance, with the initial overpotential of 390 mV and the Tafel slope of 144 mV·dec^-1.
- Co₉S₈/C,
- ZnS,
- transition metal,
- water splitting,
- oxygen evolution reaction,
- solvothermal method
1. [1]
  Liu Y P, Yu G T, Li G D, et al. Angew. Chem. Int. Ed., 2015, 127(37):10902-10907 doi: 10.1002/ange.201504376
2. [2]
  Choi C, Feng J, Li Y G, et al. Nano. Res., 2013, 6:921-928 doi: 10.1007/s12274-013-0369-8
3. [3]
  Cheng L, Li Y G, Dai H J, et al. Angew. Chem. Int. Ed., 2014, 53(30):7860-7863 doi: 10.1002/anie.201402315
4. [4]
  Gong M, Zhou W, Jiang Z, et al. Nat. Commun., 2014, 5:4695-4700 doi: 10.1038/ncomms5695
5. [5]
  Feng L L, Yu G T, Wu Y Y, et al. J. Am. Chem. Soc., 2015, 137:14023-14026 doi: 10.1021/jacs.5b08186
6. [6]
  Matthew S F, Rafal D, Mark A L, et al. J. Am. Chem. Soc., 2014, 136:10053-10061 doi: 10.1021/ja504099w
7. [7]
  Mc-Closkey B D, Bethune D S, Shelby R M, et al. J. Phys. Chem. Lett., 2012, 3(20):3043-3047 doi: 10.1021/jz301359t
8. [8]
  Gewirth A A, Thorum M S. Inorg. Chem., 2010, 49(8):3557-3566 doi: 10.1021/ic9022486
9. [9]
  Mirzakulova E, Khatmullin R, Walpita J, et al. Nat. Chem., 2012, 4(10):794-801 doi: 10.1038/nchem.1439
10. [10]
  Xie J F, Zhang J J, Li S, et al. J. Chem. Soc., 2013, 135:17881-17888 doi: 10.1021/ja408329q
11. [11]
  Xia C, Jiang Q, Zhao C, et al. Adv. Mater., 2016, 28(1):77-85 doi: 10.1002/adma.201503906
12. [12]
  Han G Q, Li X, Zhao X, et al. J. Solid State Electrochem., 2016, 20(10):1-6
13. [13]
  Al-Mamun M, Zhu Z J, Yin H. Chem. Commun., 2016, 52(60):9450-9453 doi: 10.1039/C6CC04387A
14. [14]
  Peng S J, Han X P, Li L L, et al. Small, 2016, 12(10):1359-1368 doi: 10.1002/smll.201502788
15. [15]
  Zhang J, Zhang F, Wang L J. J. Mater. Chem. A, 2016, 4(17):6350-6356 doi: 10.1039/C6TA01995A
16. [16]
  Rao C N R, Pisharody K P R. Prog. Solid State Chem, 1976, 10:207-270 doi: 10.1016/0079-6786(76)90009-1
17. [17]
  Gu W L, Hu L Y, Hong W, et al. Chem. Sci., 2016, 7(7):4167-4173 doi: 10.1039/C6SC00357E
18. [18]
  Chang S H, Lu M D, Tung Y L. ACS Nano, 2013, 7(10):9443-9451 doi: 10.1021/nn404272j
19. [19]
  Feng L L, Fan M H, Wu Y Y, et al. J. Mater. Chem. A, 2016, 4(18):6860-6867 doi: 10.1039/C5TA08611F
20. [20]
  Falkowski J M, Surendranath Y. ACS Catal., 2015, 5:3411-3416 doi: 10.1021/acscatal.5b00449
21. [21]
  Yang J, Zhu G X, Liu Y J, et al. Adv. Funct. Mater., 2016, 26(26):4712-4721 doi: 10.1002/adfm.201600674
22. [22]
  Hisatomi T, Dotan H, Stefik M, et al. Adv. Mater., 2012, 24(20):2699-2702 doi: 10.1002/adma.201104868
23. [23]
  Mahvelati-Shamsabadi T, Goharshadi E K. Sol. Energy, 2018, 161:226-234 doi: 10.1016/j.solener.2017.12.048
24. [24]
  Dutta S, Ray C, Negishi Y C. ACS Appl. Mater. Interfaces, 2017, 9(9):8134-8141 doi: 10.1021/acsami.7b00030
25. [25]
  Gennari F C, Montini T, Hickey N, et al. Appl. Surf. Sci., 2006, 252(24):8456-8465 doi: 10.1016/j.apsusc.2005.11.062
26. [26]
  Peng W C, Zheng G X, Wang Y B, et al. Int. J. Hydrogen Energy, 2019, 44(36):19782-19791 doi: 10.1016/j.ijhydene.2019.05.101
27. [27]
  Jing H L, Hao H W, Xiao H Z, et al. J. Power Sources, 2018, 401:329-335 doi: 10.1016/j.jpowsour.2018.08.088
28. [28]
  Liu H, Sun S C, Xu C Y, et al. J. Electroanal. Chem., 2019, 835:67-72 doi: 10.1016/j.jelechem.2019.01.010
29. [29]
  Wang J, Ma R, Zhou Z, et al. Sci. Rep., 2015, 5:9304-9309 doi: 10.1038/srep09304
30. [30]
  Wu C, Zhang Y H, Dong D, et al. Nanoscale, 2017, 9(34):12432-12440 doi: 10.1039/C7NR03950F
31. [31]
  Zhong H X, Li K, Zhang Q, et al. NPG Asia Mater., 2016, 8(9):e308 doi: 10.1038/am.2016.132
1. [1]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
2. [2]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
3. [3]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
4. [4]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
5. [5]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
6. [6]
  Junmei FAN , Wei LIU , Ruitao ZHU , Chenxi QIN , Xiaoling LEI , Haotian WANG , Jiao WANG , Hongfei HAN . High sensitivity detection of baicalein by N, S co-doped carbon dots and their application in biofluids. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2009-2020. doi: 10.11862/CJIC.20240120
7. [7]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
8. [8]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
9. [9]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
10. [10]
  Yifan LIU , Zhan ZHANG , Rongmei ZHU , Ziming QIU , Huan PANG . A three-dimensional flower-like Cu-based composite and its low-temperature calcination derivatives for efficient oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 979-990. doi: 10.11862/CJIC.20240008
11. [11]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
12. [12]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
13. [13]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
14. [14]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
15. [15]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
16. [16]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
17. [17]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
18. [18]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
19. [19]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
20. [20]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(426)
HTML views(85)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrocatalytic Performance of Flake Co9S8/ZnS/C Composites for Oxygen Evolution Reduction

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Electrocatalytic Performance of Flake Co₉S₈/ZnS/C Composites for Oxygen Evolution Reduction