Citation: XU Zhong-Xuan, SHI Ming-Feng. Two Pairs of Homochiral Coordination Polymers with Helixes Formed from Lactic Acid Derivatives and Rigid Auxiliary Ligands: Syntheses, Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2346-2354. doi: 10.11862/CJIC.2019.265 shu

Two Pairs of Homochiral Coordination Polymers with Helixes Formed from Lactic Acid Derivatives and Rigid Auxiliary Ligands: Syntheses, Structures and Properties

XU Zhong-Xuan ^, ,
SHI Ming-Feng

School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China

Corresponding author: XU Zhong-Xuan, xuzhongxuan4201@163.com
Received Date: 23 May 2019
Revised Date: 26 October 2019

Figures(8)

Two pairs of novel homochiral coordination polymers (HCPs), formulated as {[Zn((R)-CBA)(1, 3-DIMB)]·H₂O}_n (1-D), {[Zn((S)-CBA)(1, 3-DIMB)]·H₂O}_n (1-L), [Zn₂((R)-CBA)₂(1, 4-BMIP)]_n (2-D) and[Zn₂((S)-CBA)₂(1, 4-BMIP)₂]_n (2-L) have been synthesized using lactic acid ligands ((R)-H₂CBA and (S)-H₂CBA) and Zn²⁺ under hydrothermal conditions. Crystallographic analysis reveals that all the complexes contain chiral helical chains, which are constructed by CBA^2- ligands and Zn(Ⅱ) ions. Meanwhile, the rigid auxiliary ligands 1, 3-DIMB and 1, 4-BMIP play important roles in structural diversity. Some physical characteristics, including thermal stabilities, solid-state circular dichroism (CD), and photoluminescent properties, were also carried out. The results show that the semi-rigid lactic acid ligand can used to effectively synthesize HCPs with a helical structure.
- homochiral,
- helical chain,
- lactic acid derivative,
- auxiliary ligand
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沈阳化工大学材料科学与工程学院沈阳 110142