Citation: LIU Zhuo-Cheng, GUO Rui-Hua, RUAN Fei, HU Feng, ZHANG Jie-Yu, AN Sheng-Li. Synthesis of Ce-Mg-Ni/C Nano-Composite Hydrogen Storage Materials by Solvent-Thermal Method[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2284-2290. doi: 10.11862/CJIC.2019.259 shu

Synthesis of Ce-Mg-Ni/C Nano-Composite Hydrogen Storage Materials by Solvent-Thermal Method

LIU Zhuo-Cheng ^1,, ,
GUO Rui-Hua ^1,2,, ,
RUAN Fei ² ,
HU Feng ² ,
ZHANG Jie-Yu ¹ ,
AN Sheng-Li ²

1.
College of Materials Science and Engineering, Shanghai University, Shanghai 200072, China
2.
Institute of materials and metallurgy, Inner Mongolia University of Science and Technology, Baotou, Inner Mongolia 014010, China

Corresponding author: LIU Zhuo-Cheng, liuzhuo567@126.com GUO Rui-Hua, grh7810@163.com
Received Date: 4 July 2019
Revised Date: 13 October 2019

Figures(10)

The hydrothermal method was taken to preparing uniform C-sphere from glucose as the C source, then using ethylene glycol as the solvent, and nickel acetate, magnesium acetate and cerium chloride were added successively. Finally, the Ce-Mg-Ni/C nano-composite for hydrogen storage was producing. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were employed to analyze the phase composition and morphology of the solvent-thermal synthesis the nano-composites. Hydrogen adsorption-desorption measurements were performed by an automatic controlled Sieverts. SEM analysis indicated that the pre-fabricated composites with atom radios of 2:1:2 and 23:4:7 presented a nano-scale structure in uniform C-sphere templates. The XRD analysis showed that Ce₂MgNi₂ and Ce₂₃Mg₄Ni₇ have been formed as nano-composite with carbon, and the peaks of the second phase CeMg₃ and CeNi₃ were presented in XRD patterns. P-C-T (pressure-composition-temperature) test date revealed that the hydrogen adsorption capacity of Ce₂MgNi₂/C and Ce₂₃Mg₄Ni₇/C composites reached 1.54% and 1.05%(w/w) at 50℃, respectively.
- Ce-Mg-Ni/C composites,
- solvent-thermal synthesis,
- nano-composite structure,
- hydrogen storage
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沈阳化工大学材料科学与工程学院沈阳 110142