Citation: ZHAI Li-Jun, ZHANG Jie, GAO Ling-Ling, GAO Ting, JIA Jiao-Jiao, NIU Yu-Lan, HU Tuo-Ping. Two Coordination Polymers Constructed by Aromatic Tetracarboxylic Acid: Luminescent and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 173-182. doi: 10.11862/CJIC.2019.257 shu

Two Coordination Polymers Constructed by Aromatic Tetracarboxylic Acid: Luminescent and Magnetic Properties

ZHAI Li-Jun ^1,2 ,
ZHANG Jie ¹ ,
GAO Ling-Ling ¹ ,
GAO Ting ¹ ,
JIA Jiao-Jiao ^1,2 ,
NIU Yu-Lan ^2,, ,
HU Tuo-Ping ^1,,

1.
Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China
2.
Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China

Corresponding author: NIU Yu-Lan, niuyulan@163.com HU Tuo-Ping, hutuoping@nuc.edu.cn
Received Date: 26 June 2019
Revised Date: 1 October 2019

Figures(13)

Two new coordination polymers (CPs) based on H₄tptc, namely, {[Zn₂(tptc)(1, 4-bimb)₂]·H₂O}_n (1) and {[Ni(tptc)_0.5(1, 2-bimb)(H₂O)]·H₂O}_n (2) (H₄tptc=p-terphenyl-3, 3", 5, 5"-tetracarboxylic acid, 1, 4-bimb=1, 4-bis (imid-azol-1-ylmethyl) benzene, 1, 2-bimb=1, 2-bis (imidazol-1-ylmethyl) benzene), have been synthesized under solvo-thermal conditions. The structural analyses reveal that complex 1 shows a 3D structure with the symbol of (8⁶), while complex 2 presents a 2D layer network, which is further expanded into a 3D supramolecular structure through H-bonding interactions. Furthermore, the luminescence sensing of 1 for cations, anions as well as magnetic property of 2 have also been studied.
- aromatic tetracarboxylic acid,
- coordination polymers,
- luminescent properties,
- magnetic properties
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