Citation: CAO Han, PAN Hai-Hua, TANG Rui-Kang. Materials Enhanced by Biomimetic Mineralization[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 1957-1973. doi: 10.11862/CJIC.2019.250 shu

Materials Enhanced by Biomimetic Mineralization

CAO Han ^1,2 ,
PAN Hai-Hua ^2,, ,
TANG Rui-Kang ^1,2,,

1.
Department of Chemistry, Zhejiang University, Hangzhou 310027, China
2.
Qiushi Academy for Advanced Studies, Zhejiang University, Hangzhou 310027, China

Corresponding author: PAN Hai-Hua, panhh@zju.edu.cn TANG Rui-Kang, rtang@zju.edu.cn
Received Date: 15 August 2019
Revised Date: 7 October 2019

Figures(8)

In recent years, with the development of material science, organic-inorganic composites with excellent mechanical properties and specific functions have become a hot research topic. The natural processes of biomineralization have produced widely distributed biominerals with a wide variety of unique composite materials and excellent mechanical properties, such as tooth, bone, pearl, shellfish, sea urchin thorn, marine bloodworm jaw. The characteristics of biominerals structure and mineralization mechanisms in natural composite materials provide a theoretical basis for biomimetic design and synthesis of materials with specific structure, specific function and excellent mechanical properties. By learning the principle of biomineralization, biomimetic mineralization is a crystallization process, by which an organic matrix regulates the nucleation of inorganic minerals, and grows into organic-inorganic hybrid minerals with ordered structures and advanced functions. This paper reviews the natural reinforced composite materials with high hardness and high toughness fabricated by natural biomineralization process, and a number of artificial organic-inorganic reinforced composite materials inspired by the reinforcing and toughening mechanisms in biomineralization.
- biomimetic mineralization,
- reinforced composite material,
- organic-inorganic composite
1. [1]
  CUI Fu-Zhai. Biomineralization. Beijing:Tsinghua University Press, 2007.
2. [2]
  Jodaikin A, Weiner S, Talmon Y, et al. Int. J. Biol. Macromol., 1988, 10(6):349-352 doi: 10.1016/0141-8130(88)90027-X
3. [3]
  Fincham A G, Moradian-Oldak J, Diekwisch T G H, et al. J. Struct. Biol., 1995, 115(1):50-59 doi: 10.1006/jsbi.1995.1029
4. [4]
  Mann S. Biomimetic Materials Chemistry. Canada:Wiley-VCH, 1995.
5. [5]
  Weiner S, Wagner H D. Annu. Rev. Mater. Sci., 1998, 28(1):271-298
6. [6]
  Limeback H. Current Opinion in Dentistry, 1991, 1(6):826-835
7. [7]
  Pyun J, Matyjaszewski K. Chem. Mater., 2001, 13(10):3436-3448 doi: 10.1021/cm011065j
8. [8]
  Lowenstam H A, Weiner S. On Biomineralization. New York:Oxford University Press, 1989.
9. [9]
  Aizenberg J, Tkachenko A, Weiner S, et al. Nature, 2001, 412(6849):819-822 doi: 10.1038/35090573
10. [10]
  Addadi L, Weiner S. Nature, 2001, 411(6839):753-755 doi: 10.1038/35081227
11. [11]
  Kamat S, Su X, Ballarini R, et al. Nature, 2000, 405(6790):1036-1040 doi: 10.1038/35016535
12. [12]
  Mann S. Nature, 1993, 365(6446):499-505 doi: 10.1038/365499a0
13. [13]
  Cha J N, Shimizu K, Zhou Y, et al. Proc. Natl. Acad. Sci. U.S.A., 1999, 96(2):361-365 doi: 10.1073/pnas.96.2.361
14. [14]
  Landis W J. Connective Tissue Research, 1996, 34(4):239-246 doi: 10.3109/03008209609005267
15. [15]
  Lowenstam H A. Science, 1967, 156(3780):1373-1375 doi: 10.1126/science.156.3780.1373
16. [16]
  Currey J D. J. Exp. Biol., 1999, 202(23):3285-3294
17. [17]
  Waters N E, Vincent J F V, Currey J D. The Mechanical Properties of Biological Materials. London:Cambridge Univ. Press, 1980, 34:99-136
18. [18]
  Currey J D. Science, 2005, 309(5732):253-254 doi: 10.1126/science.1113954
19. [19]
  Söllner C, Burghammer M, Busch-Nentwich E, et al. Science, 2003, 302(5643):282-286 doi: 10.1126/science.1088443
20. [20]
  Lichtenegger H C, Schöberl T, Bartl M H, et al. Science, 2002, 298(5592):389-392 doi: 10.1126/science.1075433
21. [21]
  Weiner S, Dove P M. Rev. Mineral. Geochem., 2003, 54(1):1-29 doi: 10.2113/0540001
22. [22]
  Addadi L, Raz S, Weiner S. Adv. Mater., 2003, 15(12):959-970 doi: 10.1002/adma.200300381
23. [23]
  Espinosa H D, Rim J E, Barthelat F, et al. Prog. Mater Sci., 2009, 54(8):1059-1100 doi: 10.1016/j.pmatsci.2009.05.001
24. [24]
  Kohn A J. Encyclopedia of Evolution:Molluscs. New York:Oxford University Press, 2002.
25. [25]
  Addadi L, Weiner S. Nature, 1997, 389(6654):912-913 doi: 10.1038/40010
26. [26]
  Weiss I M, Tuross N, Addadi L, et al. J. Exp. Zool., 2002, 293(5):478-491 doi: 10.1002/jez.90004
27. [27]
  Currey J D, Taylor J D. J. Zool., 1974, 173(3):395-406
28. [28]
  Lin A Y M, Chen P Y, Meyers M A. Acta Biomater., 2008, 4(1):131-138 doi: 10.1016/j.actbio.2007.05.005
29. [29]
  Gilbert P U P A, Abrecht M, Frazer B H. Rev. Mineral. Geochem., 2005, 59(1):157-185 doi: 10.2138/rmg.2005.59.7
30. [30]
  Huang W, Restrepo D, Jung J Y, et al. Adv. Mater., 2019, https://doi.org/10.1002/adma.201901561
31. [31]
  Gregoire C, Duchateau G, Florkin M. Annales de l'Institut Océanographique, 1955, 31:1-36
32. [32]
  Schäffer T E, Ionescu-Zanetti C, Proksch R, et al. Chem. Mater., 1997, 9(8):1731-1740 doi: 10.1021/cm960429i
33. [33]
  Meyers M A, Chen P Y, Lin A Y M, et al. Prog. Mater. Sci., 2008, 53(1):1-206 doi: 10.1016/j.pmatsci.2007.05.002
34. [34]
  Wang R Z, Suo Z, Evans A G, et al. J. Mater. Res., 2011, 16(9):2485-2493
35. [35]
  Evans A G, Suo Z, Wang R Z, et al. J. Mater. Res., 2011, 16(9):2475-2484
36. [36]
  Li X, Chang W C, Chao Y J, et al. Nano Lett., 2004, 4(4):613-617 doi: 10.1021/nl049962k
37. [37]
  Smith B L, Schffer T E, Viani M, et al. Nature, 1999, 399(6738):761-763 doi: 10.1038/21607
38. [38]
  Song F, Soh A K, Bai Y L. Biomaterials, 2003, 24(20):3623-3631 doi: 10.1016/S0142-9612(03)00215-1
39. [39]
  Watabe N. J. Ultrastruct. Res., 1965, 12(3):351-370 doi: 10.1016/S0022-5320(65)80104-6
40. [40]
  Weiner S, Traub W, Miller A, et al. Phil. Trans. R. Soc. Lond. B, 1984, 304(1121):425-434 doi: 10.1098/rstb.1984.0036
41. [41]
  Carpenter W. Report of the British Association for the Advancement of Science. 17th Meeting. 1847: 93-134
42. [42]
  Schmidt W. J. Die Bausteine des Tierkorpers in Polarisiertem Lichte. Bonn:Verlag von Friedrich Cohen, 1924.
43. [43]
  Beniash E, Aizenberg J, Addadi L, et al. Proceedings of the Royal Society B:Biological Sciences, 1997, 264(1380):461-465 doi: 10.1098/rspb.1997.0066
44. [44]
  Märkel K, Röser U, Mackenstedt U, et al. Zoomorphology, 1986, 106(4):232-243 doi: 10.1007/BF00312044
45. [45]
  Beniash E, Addadi L, Weiner S. J. Struct. Biol., 1999, 125(1):50-62 doi: 10.1006/jsbi.1998.4081
46. [46]
  Wilt F H. Zool. Sci., 2002, 19:253-261 doi: 10.2108/zsj.19.253
47. [47]
  Aizenberg J, Weiner S, Addadi L. Connective Tissue Research, 2003, 44(1):20-25 doi: 10.1080/03008200390152034
48. [48]
  Aizenberg J, Ilan M, Weiner S, et al. Connective Tissue Research, 1996, 34(4):255-261 doi: 10.3109/03008209609005269
49. [49]
  Weiner S, Price P A. Calcified Tissue International, 1986, 39(6):365-375 doi: 10.1007/BF02555173
50. [50]
  Moradian-Oldak J, Weiner S, Addadi L, et al. Connective Tissue Research, 1991, 25(3/4):219-228
51. [51]
  Stumm W. Chemistry of the Solid-Water Interface. New York:John Wiley & Sons Inc, 1992.
52. [52]
  Waychunas G A. Rev. Mineral. Geochem., 2001, 44(1):105-166 doi: 10.2138/rmg.2001.44.04
53. [53]
  Mai C, Militz H. Wood Sci. Technol., 2004, 37(5):339-348 doi: 10.1007/s00226-003-0205-5
54. [54]
  Aizenberg J, Weaver J C, Thanawala M S, et al. Science, 2005, 309(5732):275-278 doi: 10.1126/science.1112255
55. [55]
  Moreno M D, Ma K, Schoenung J, et al. Acta Biomater., 2015, 25:313-324 doi: 10.1016/j.actbio.2015.07.028
56. [56]
  Shimizu K, Cha J, Stucky G D, et al. Proc. Natl. Acad. Sci. U.S.A., 1998, 95(11):6234-6238 doi: 10.1073/pnas.95.11.6234
57. [57]
  Brunner E, Richthammer P, Ehrlich H, et al. Angew. Chem. Int. Ed., 2009, 48(51):9724-9727 doi: 10.1002/anie.200905028
58. [58]
  Ehrlich H. Int. Geol. Rev., 2010, 52(7/8):661-699
59. [59]
  Ehrlich H, Janussen D, Simon P, et al. J. Nanomater., 2008, 2008:670235
60. [60]
  Woesz A, Weaver J C, Kazanci M, et al. J. Mater. Res., 2006, 21(8):2068-2078 doi: 10.1557/jmr.2006.0251
61. [61]
  Fratzl P, Gupta H S, Fischer F D, et al. Adv. Mater., 2007, 19(18):2657-2661 doi: 10.1002/adma.200602394
62. [62]
  Lin A, Meyers M A. Mater. Sci. Eng. A, 2005, 390(1):27-41
63. [63]
  Mustoe G, Acosta M. Geosci., 2016, 6(2):25 doi: 10.3390/geosciences6020025
64. [64]
  Hillis W E, Silva D. Holzforschung-International Journal of the Biology, Chemistry, Physics and Technology of Wood, 1979, 33(2):47-53
65. [65]
  Bazylinski D A, Moskowitz B M. Rev. Mineral., 1997, 35:181-223
66. [66]
  Konhauser K O. FEMS Microbiol. Rev., 1997, 20(3/4):315-326
67. [67]
  Konhauser K O. Earth Sci. Rev., 1998, 43(3):91-121
68. [68]
  Lowenstam H A. Biomineralization in Lower Plants and Animals. New York:Oxford University Press, 1986, 30:1-17
69. [69]
  Bazylinski D A, Frankel R B. Rev. Mineral. Geochem., 2003, 54(1):217-247 doi: 10.2113/0540217
70. [70]
  Kirschvink J L, Hagadorn J W. Biomineralization Weinheim, Germany:Wiley-VCH Verlag GmbH, 2000:139-149
71. [71]
  Weaver J C, Wang Q, Miserez A, et al. Mater. Today, 2010, 13(1):42-52
72. [72]
  Devouard B, Pósfai M, Hua X, et al. Am. Mineral., 1998, 83(11/12):1387-1398
73. [73]
  Barber A H, Lu D, Pugno N M. Journal of the Royal Society Interface, 2015, 12(105):20141326 doi: 10.1098/rsif.2014.1326
74. [74]
  Gibbs P E, Bryan G W. Journal of the Marine Biological Association of the United Kingdom, 2009, 60(1):205-214
75. [75]
  Fong H, Sarikaya M, White S N, et al. Mater. Sci. Eng. C, 1999, 7(2):119-128 doi: 10.1016/S0928-4931(99)00133-2
76. [76]
  Vincent J F V. Structural Biomaterials. Princeton, NJ:Princeton Univ. Press, 1990.
77. [77]
  Suresh S, Olsson M, Giannakopoulos A E, et al. Acta Mater., 1999, 47(14):3915-3926 doi: 10.1016/S1359-6454(99)00205-0
78. [78]
  Suresh S. Science, 2001, 292(5526):2447-2451 doi: 10.1126/science.1059716
79. [79]
  Chujo Y. Curr. Opin. Solid State Mater. Sci., 1996, 1(6):806-811 doi: 10.1016/S1359-0286(96)80105-7
80. [80]
  Schmidt H. J. Non-cryst. Solids., 1985, 73(1/2/3):681-691
81. [81]
  Mark J E, Lee C Y C, Bianconi P A. Hybrid Organic-Inorganic Composite. Washington, DC:American Chemical Society, 1995.
82. [82]
  Novak B M. Adv. Mater., 1993, 5(6):422-433 doi: 10.1002/adma.19930050603
83. [83]
  Huang H H, Orler B, Wilkes G L. Macromolecules, 1987, 20(6):1322-1330 doi: 10.1021/ma00172a026
84. [84]
  Wilkes G L, Wen J. Polymeric Materials Encyclopedia: Vol. 6. Salamone J C. Ed., New York: CRC Press, 1996.
85. [85]
  Allcock H R. Chemical Processing of Advanced Materials. New York:Wiley & Son, 1992.
86. [86]
  Scobbo Jr J J. J. Appl. Polym. Sci., 1993, 47(12):2169-2175 doi: 10.1002/app.1993.070471211
87. [87]
  Menon N, Blum F D, Dharani L R. J. Appl. Polym. Sci., 1994, 54(1):113-123 doi: 10.1002/app.1994.070540112
88. [88]
  Hsu Y G, Lin F J. J. Appl. Polym. Sci., 2000, 75(2):275-283 doi: 10.1002/(SICI)1097-4628(20000110)75:2<275::AID-APP10>3.0.CO;2-I
89. [89]
  LeGeros R Z, LeGeros J P. An Introduction to Bioceramics (2nd Ed). London:Word Scientific, 1999:139-180
90. [90]
  Hench L L. Bioceramics-Applications of Ceramic and Glass Materials in Medicine. Switzerland:Trans Tech Publication, 1999:37-64
91. [91]
  Seal B L, Otero T C, Panitch A. Mater. Sci. Eng. R, 2001, 34(4):147-230
92. [92]
  Keaveny T M, Hayes W C. Bone Growth. Boca Raton, FL:CRC Press, 1993:285-344
93. [93]
  Giesen E B W, Ding M, Dalstra M, et al. J. Biomech., 2001, 34(6):799-803 doi: 10.1016/S0021-9290(01)00030-6
94. [94]
  Yeni Y N, Fyhrie D P. J. Biomech., 2001, 34(12):1649-1654 doi: 10.1016/S0021-9290(01)00155-5
95. [95]
  Hench L L, Kokubo T. Handbook of Biomaterial Properties. London:Chapman & Hall, 1998:355-363
96. [96]
  Hench L L. An Introduction to Bioceramics (2nd Ed). London:Word Scientific, 1999.
97. [97]
  Kokubo T. An Introduction to Bioceramics (2nd Ed). London:Word Scientific, 1999:75-88
98. [98]
  Jones J R, Ehrenfried L M, Hench L L. Biomaterials, 2006, 27(7):964-973 doi: 10.1016/j.biomaterials.2005.07.017
99. [99]
  Okii N, Nishimura S, Kurisu K, et al. Neurologia Medico-Chirurgica, 2001, 41(2):100-104 doi: 10.2176/nmc.41.100
100. [100]
  Chen Y P, Dang B K, Jin C D, et al. ACS Nano, 2019, 13(1):371-376 doi: 10.1021/acsnano.8b06409
101. [101]
  Kuo D, Nishimura T, Kajiyama S, et al. ACS Omega, 2018, 3(10):12722-12729 doi: 10.1021/acsomega.8b02014
102. [102]
  Salvetat J P, Bonard J M, Thomson N H, et al. Appl. Phys. A, 1999, 69(3):255-260 doi: 10.1007/s003390050999
103. [103]
  Subramoney S. Adv. Mater., 1998, 10(15):1157-1171 doi: 10.1002/(SICI)1521-4095(199810)10:15<1157::AID-ADMA1157>3.0.CO;2-N
104. [104]
  Baughman R H, Zakhidov A A, Heer W A. Science, 2002, 297(5582):787-792 doi: 10.1126/science.1060928
105. [105]
  Thostenson E T, Ren Z F, Chou T W. Compos. Sci. Technol., 2001, 61:1899-1912 doi: 10.1016/S0266-3538(01)00094-X
106. [106]
  Safadi B, Andrews R, Grulke E A, et al. J. Appl. Polym. Sci., 2002, 84(14):2660-2669 doi: 10.1002/app.10436
107. [107]
  Andrews R, Jacques D, Rao A M, et al. Appl. Phys. Lett., 1999, 75(9):1329-1331 doi: 10.1063/1.124683
108. [108]
  Andrews R, Jacques D, Minot M, et al. Macromol. Mater. Eng., 2002, 287:395-403 doi: 10.1002/1439-2054(20020601)287:6<395::AID-MAME395>3.0.CO;2-S
109. [109]
  Zhang H, Wang Z G, Zhang Z N. Adv. Mater., 2007, 19(5):698-704 doi: 10.1002/adma.200600442
110. [110]
  Zhang H, Wu J, Zhang J, et al. Macromolecules, 2005, 38:8272-8277 doi: 10.1021/ma0505676
111. [111]
  Rai U S, Singh R K. Mater. Lett., 2004, 58(1):235-240
112. [112]
  Yang K, Yang Q, Li G X, et al. Mater. Lett., 2006, 60(6):805-809 doi: 10.1016/j.matlet.2005.10.020
113. [113]
  Neville A M. Properties of Concrete. London:Sir Isaac Pitman, 1963.
114. [114]
  Picker A, Nicoleau L, Burghard Z, et al. Sci. Adv., 2017, 3(11):e1701216 doi: 10.1126/sciadv.1701216
115. [115]
  Fratzl P, Kolednik O, Fischer F D, et al. Chem. Soc. Rev., 2016, 45(2):252-267 doi: 10.1039/C5CS00598A
116. [116]
  ZHAO Min, ZHENG Qi-Xin, GUO Xiao-Dong, et al. Chinese Journal of Biomedical Engineering, 2005, 24(2):145-149 doi: 10.3969/j.issn.0258-8021.2005.02.004
117. [117]
  Munch E, Launey M E, Alsem D H, et al. Science, 2008, 322(5907):1516-1520 doi: 10.1126/science.1164865
118. [118]
  Chen S M, Gao H L, Sun X H, et al. Matter, 2019, 1(2):412-427 doi: 10.1016/j.matt.2019.03.012
119. [119]
  Yin Z, Hannard F, Barthelat F. Science, 2019, 364(6447):1260-1263 doi: 10.1126/science.aaw8988
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