Citation: SUN Jing, LI Qiang, LIN Kun, LIU Zhan-Ning, XING Xian-Ran. Synthesis and Thermal Expansion in Nanosized Hafnium Oxide[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2073-2077. doi: 10.11862/CJIC.2019.249 shu

Synthesis and Thermal Expansion in Nanosized Hafnium Oxide

SUN Jing ^1,2 ,
LI Qiang ^1,2 ,
LIN Kun ^1,2 ,
LIU Zhan-Ning ^1,2 ,
XING Xian-Ran ^1,2,,

1.
Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing 100083, China
2.
Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China

Corresponding author: XING Xian-Ran, xing@ustb.edu.cn
Received Date: 31 August 2019
Revised Date: 9 October 2019

Figures(7)

HfO₂ nanoparticles with size of 4 nm were prepared through solvothermal process, and the lattice thermal expansion of nano and bulk HfO₂ was studied by X-ray atom pair distribution function (PDF) method. The results showed that in nanoscale HfO₂, the lattice thermal expansion along a and c axis increased, while b axis slightly decreased, and eventually volumetric thermal expansion increased. Meanwhile, the anisotropy of the thermal expansion of the nanosized HfO₂ is larger than that of the bulk. The origin was that size effect induced a large structural distortion, mainly the reduction of the next nearest neighbor Hf-O-Hf bond angle, and then heating process triggered the relaxation of the distortion to equilibrium position.
- hafnium oxide,
- nanoparticles,
- thermal expansion,
- pair distribution function
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