Citation: SUN Jing, LI Qiang, LIN Kun, LIU Zhan-Ning, XING Xian-Ran. Synthesis and Thermal Expansion in Nanosized Hafnium Oxide[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2073-2077. doi: 10.11862/CJIC.2019.249 shu

Synthesis and Thermal Expansion in Nanosized Hafnium Oxide

SUN Jing ^1,2 ,
LI Qiang ^1,2 ,
LIN Kun ^1,2 ,
LIU Zhan-Ning ^1,2 ,
XING Xian-Ran ^1,2,,

1.
Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing 100083, China
2.
Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China

Corresponding author: XING Xian-Ran, xing@ustb.edu.cn
Received Date: 31 August 2019
Revised Date: 9 October 2019

Figures(7)

HfO₂ nanoparticles with size of 4 nm were prepared through solvothermal process, and the lattice thermal expansion of nano and bulk HfO₂ was studied by X-ray atom pair distribution function (PDF) method. The results showed that in nanoscale HfO₂, the lattice thermal expansion along a and c axis increased, while b axis slightly decreased, and eventually volumetric thermal expansion increased. Meanwhile, the anisotropy of the thermal expansion of the nanosized HfO₂ is larger than that of the bulk. The origin was that size effect induced a large structural distortion, mainly the reduction of the next nearest neighbor Hf-O-Hf bond angle, and then heating process triggered the relaxation of the distortion to equilibrium position.
- hafnium oxide,
- nanoparticles,
- thermal expansion,
- pair distribution function
1. [1]
  Gilmer D C, Hegde R, Cotton R, et al. Microelectron. Eng., 2003, 69(2/3/4):138-144
2. [2]
  Hoffmann M, Fengler F P G, Herzig M, et al. Nature, 2019, 565(7740):464-467 doi: 10.1038/s41586-018-0854-z
3. [3]
  Park M H, Lee Y H, Kim H J, et al. Adv. Mater., 2015, 27(11):1811-1831 doi: 10.1002/adma.201404531
4. [4]
  Hong N H, Sakai J, Poirot N, et al. Phys. Rev. B, 2006, 73(13):132404 doi: 10.1103/PhysRevB.73.132404
5. [5]
  Monaghan S, Hurley P K, Cherkaoui K, et al. Solid-State Electron., 2009, 53(4):438-444 doi: 10.1016/j.sse.2008.09.018
6. [6]
  Ok I J, Kim H, Zhang M, et al. 2006 International Electron Devices Meeting. San Francisco:IEEE, 2006:1-4
7. [7]
  Aoki Y, Ueda T, Shirai H, et al. Digest. International Electron Devices Meeting. San Francisco:IEEE, 2002:831-834
8. [8]
  Gusev E P, Narayanan V, Frank M M. IBM J. Res. Dev., 2006, 50(4/5):387-410
9. [9]
  Pinna N, Garnweitner G, Antonietti M, et al. Adv. Mater., 2004, 16(23/24):2196-2200
10. [10]
11. [11]
  DING Yu-Jie, JIN Xing, LIU Qian, et al. Chinese. J. Inorg. Chem., 2019, 35(6):947-954
12. [12]
  Billinge S J L. J. Solid State Chem., 2008, 181(7):1695-1700 doi: 10.1016/j.jssc.2008.06.046
13. [13]
  Farrow C L, Juhas P, Liu J W, et al. J. Phys.-Condes. Matter, 2007, 19(33):335219 doi: 10.1088/0953-8984/19/33/335219
14. [14]
  Rong Y H. Curr. Opin. Solid State Mat. Sci., 2005, 9(6):287-295 doi: 10.1016/j.cossms.2006.07.003
15. [15]
  Patil R N, Subbarao E C. J. Appl. Crystallogr., 1969, 2(6):281-288 doi: 10.1107/S0021889869007217
16. [16]
  Haggerty R P, Sarin P, Apostolov Z D, et al. J. Am. Ceram. Soc., 2014, 97(7):2213-2222 doi: 10.1111/jace.12975
17. [17]
  Sun C Q. Prog. Solid State Chem., 2007, 35(1):1-159 doi: 10.1016/j.progsolidstchem.2006.03.001
1. [1]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
2. [2]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
3. [3]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
4. [4]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
5. [5]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
6. [6]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
7. [7]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
8. [8]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
9. [9]
  Gaofeng Zeng , Shuyu Liu , Manle Jiang , Yu Wang , Ping Xu , Lei Wang . Micro/Nanorobots for Pollution Detection and Toxic Removal. University Chemistry, 2024, 39(9): 229-234. doi: 10.12461/PKU.DXHX202311055
10. [10]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
11. [11]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
12. [12]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
13. [13]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
14. [14]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
15. [15]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
16. [16]
  Haiyu Nie , Chenhui Zhang , Fengpei Du . Ideological and Political Design for the Preparation, Characterization and Particle Size Control Experiment of Nanoemulsion. University Chemistry, 2024, 39(2): 41-46. doi: 10.3866/PKU.DXHX202306055
17. [17]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
18. [18]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
19. [19]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
20. [20]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(1212)
HTML views(125)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142