Citation: XU Meng-Ying, SONG Gan-Lin, HAN Bao-Hang. Postsynthetic Modification of UiO-66 with Perfluoroalkyl for Adsorbing Organic Pollutants[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2136-2144. doi: 10.11862/CJIC.2019.247 shu

Postsynthetic Modification of UiO-66 with Perfluoroalkyl for Adsorbing Organic Pollutants

XU Meng-Ying ^1,2 ,
SONG Gan-Lin ^1,2 ,
HAN Bao-Hang ^1,2,,

1.
CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
2.
University of Chinese Academy of Science, Beijing 100049, China

Corresponding author: HAN Bao-Hang, hanbh@nanoctr.cn
Received Date: 19 August 2019
Revised Date: 6 October 2019

Figures(8)

Through postsynthetic modification (PSM) of metal-organic frameworks with perfluoroacetyl and perfluoropropionyl as functional groups, hydrophobic frameworks (UiO-66-F1 and UiO-66-F2) were obtained. Both frameworks exhibited lipophilicity, which indicates that they are potential absorbents for liposoluble solvent. The crystallinity, stability, and exceptional porosity of modified MOFs decreased slightly compared to those of UiO-66-NH₂. Their Brunauer-Emmett-Teller (BET) specific surface areas were 810 and 610 m²·g^-1 for UiO-66-F1 and UiO-66-F2, respectively. Suitable pore size and hydrophobic microenvironment made the frameworks easier to adsorb organic pollutants in water. Furthermore, they showed an obvious increase in adsorption capacity for a variety of organic solvents and endowed outstanding recycling performance without a significant reduction in adsorption capacity after recycle ten times.
- MOFs,
- postsynthetic modification,
- perfluoroalkyl,
- adsorption
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