Citation: ZHOU Ying-Xi, WANG Hui-Feng, SUN Fu-Xing. Synthesis and Conductivity of Polypyrrole in CYCU-3[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2095-2100. doi: 10.11862/CJIC.2019.238 shu

Synthesis and Conductivity of Polypyrrole in CYCU-3

State Key Lab of Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

Corresponding author: SUN Fu-Xing, fxsun@jlu.edu.cn
Received Date: 15 September 2019
Revised Date: 27 September 2019

Figures(7)

Using a metal-organic framework (MOF) called CYCU-3 with one-dimensional (1D) mesoporous channels as the host material, the polymerization of pyrrole was carried out in the pores by iodine oxidation method to obtain the composite material PPy@CYCU-3. Powdered X-ray diffraction (PXRD), scanning electron microscopy (SEM), thermogravimetry (TG), infrared (IR), fluorescence spectroscopy, etc. were used to characterize the synthesized CYCU-3, Py@CYCU-3 which is obtained after adsorption of pyrrole and PPy@CYCU-3 in pores. It is demonstrated that the polymerization in the pores was successful. In addition, CYCU-3 remained structurally stable and its morphology did not change during the polymerization. The composite PPy@CYCU-3 is multifunctional material with porosity and electrical conductivity. Nitrogen adsorption measurement indicated that the material was a typical microporous material with a BET specific surface area of 420 m²·g^-1. Conductivity tests indicate that the material has a conductivity of 10^-7 S·cm^-1, which is six orders of magnitude higher than the conductivity of CYCU-3 (σ≈10^-13 S·cm^-1) and it is a semiconductor material.
- metal-organic frameworks,
- composites,
- conductivity
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