Citation: LI Ji-Kun, ZHAO Shuai-Heng, HU Chang-Wen. Polyoxometalate-Based Host-Guest Framework Materials POMs@MOFs(COFs)[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 1934-1956. doi: 10.11862/CJIC.2019.230 shu

Polyoxometalate-Based Host-Guest Framework Materials POMs@MOFs(COFs)

1.
College of Chemistry and Chemical Engineering, Taishan University, Tai'an, Shandong 271021, China
2.
School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Key Laboratory of Cluster Science Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic, Beijing 100081, China

Corresponding author: HU Chang-Wen, cwhu@bit.edu.cn
Received Date: 8 August 2019
Revised Date: 19 September 2019

Figures(29)

Due to the advantages of their easy regulated composition, structure and size along with the excellent electronic storage and redox activity, polyoxometalates have broad application prospects in the fields of catalytic, photoelectric, and magnetic, etc. It is much favored by chemists especially in the field of catalysis. Polyoxometalates are easy to deactivate due to the agglomeration in the catalytic process, and its specific surface area is low. The introduction of polyoxometalates into a well-structured, porous framework material can better solve the above problems. Therefore, these materials have become one of the research hotspots in the field of polyoxometalates chemistry. In this paper, the polyoxometalate-based host-guest framework materials are classified according to their synthetic methods, namely in situ synthesis, impregnation synthesis and mechanical grinding synthesis, and their advantages or disadvantages are discussed separately. We further summarize the performance and application of these materials in the fields of catalysis, dye adsorption and degradation, proton conduction and photoelectric sensing, and prospect its future development trend.
- polyoxometalates,
- host-guest framework materials,
- structure,
- catalysis,
- application
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