Citation: JIANG Ju-Hui, LI Pei-Pei, LIU Sheng-Nan, LOU Xiang-Dong, FAN Jing, WANG Xiao-Bing. Preparation and Properties of Highly Electrochemically Active SnO₂/TiO₂ Hollow Microspheres[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2217-2225. doi: 10.11862/CJIC.2019.226 shu

Preparation and Properties of Highly Electrochemically Active SnO₂/TiO₂ Hollow Microspheres

1.
Key Laboratory for Yellow River and Huaihe River Water Environment and Pollution Control, Ministry of Education, Henan Key Laboratory for Environmental Pollution Control, School of Environment, Henan Normal University, Xinxiang, Henan 453007, China
2.
Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China

Corresponding author: LOU Xiang-Dong, chemenglxd@126.com FAN Jing, fanjing@htu.cn
Received Date: 22 April 2019
Revised Date: 29 August 2019

Figures(8)

The SnO₂/TiO₂ microspheres with hollow structure were synthesized by a simple template-free solvothermal method. The characterization results show that the size of SnO₂/TiO₂ microspheres is about 1 μm, and they are stacked together. The results of the synthesis process shows that the SnO₂/TiO₂ microspheres undergone from hollow, filled, split to a hollow structure again during formation process. Subsequently, the electrochemical performances of SnO₂/TiO₂ hollow microspheres are tested in lithium ion batteries. The initial discharge capacity of SnO₂/TiO₂ hollow microspheres can reach 1 484.9 mAh·g^-1 at a current density of 0.1 A·g^-1, with the coulombic effciency of 49.0%. After 600 cycles, the discharge capacity still reach 565.6 mAh·g^-1. These results show that the as-prepared SnO₂/TiO₂ hollow microspheres have high capacity and cycle stability.
- SnO₂/TiO₂ hollow microspheres,
- solvothermal method,
- synthesis mechanism,
- lithium ion battery
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Properties of Highly Electrochemically Active SnO2/TiO2 Hollow Microspheres

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通讯作者: 陈斌, bchen63@163.com

Preparation and Properties of Highly Electrochemically Active SnO₂/TiO₂ Hollow Microspheres