Citation: TAO Yan-Li, CHEN Wei-Chao, WANG Xin-Long, SU Zhong-Min. Synthesis, Crystal Structures and Fluorescence Properties of Two Nanosized Zr-Based Molecular Capsules[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2108-2116. doi: 10.11862/CJIC.2019.224 shu

Synthesis, Crystal Structures and Fluorescence Properties of Two Nanosized Zr-Based Molecular Capsules

1.
Northeast Normal University, Changchun 130024, China
2.
Changchun University of Science and Technology, Changchun 130024, China

Corresponding author: CHEN Wei-Chao, chenwc061@nenu.edu.cn SU Zhong-Min, zmsu@nenu.edu.cn
Received Date: 29 July 2019
Revised Date: 9 September 2019

Figures(9)

Two nanosized zirconium-based molecular capsules (Zr-MCs), namely[Cp₃Zr₃(μ₃-O)(μ₂-OH)₃]₂(BPDC)₃Cl₂ ·H₂O (Zr-MC-1) and[Cp₃Zr₃(μ₃-O)(μ₂-OH)₃]₂(NDC)₃Cl₂·3H₂O (Zr-MC-2), have been synthesized by reacting zirconocenedichloride (Cp₂ZrCl₂) with 4, 4'-biphenyldicarboxylic acid (4, 4'-H₂BPDC) and 2, 6-naphthalenedicar-boxylic acid (2, 6-H₂NDC), respectively, which are constructed by two trinuclear zirconocene building blocks and three linear carboxylate ligands. They were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, IR spectroscopy, thermogravimetric analysis and N₂ adsorption-desorption tests. In addition, the fluorescence spectra indicate that Zr-MC-1 and Zr-MC-2 are deep-blue and blue emitting materials with emission peaks at 404 and 456 nm, respectively.
- molecular capsule,
- crystal structure,
- carboxylate ligand,
- fluorescence spectroscopy
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