Citation: LIU Yuan-Jun, YE Fen, WANG Wei, ZHANG Jun-Hao, YAN Chao, YUAN Ai-Hua. Fabrication of Honeycomb-like Ag Nanoparticles Film Used as Surface Enhanced Raman Scattering Substrate[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1861-1868. doi: 10.11862/CJIC.2019.221 shu

Fabrication of Honeycomb-like Ag Nanoparticles Film Used as Surface Enhanced Raman Scattering Substrate

LIU Yuan-Jun ^1,2,, ,
YE Fen ^1,2 ,
WANG Wei ^1,2 ,
ZHANG Jun-Hao ^1,2 ,
YAN Chao ³ ,
YUAN Ai-Hua ^1,2,,

1.
School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 202018, China
2.
Marine Equipment and Technology Institute, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China
3.
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China

Corresponding author: LIU Yuan-Jun, liuyuanjun@just.edu.cn YUAN Ai-Hua, aihua.yuan@just.edu.cn
Received Date: 31 May 2019
Revised Date: 21 August 2019

Figures(5)

Highly ordered polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) honeycomb-patterned film was prepared by a static breath figure method, which was used as a template for the preparation of metal particles array. Honeycomb-like Ag nanoparticles array film was prepared with this polymer pattern through a photochemical reduction route. The SERS performance of this Ag nanoparticle array film was investigated with rhodamine 6G (R6G) as model molecule, which provides enhancement factors (EF) as high as 1.31×10⁹. In addition, the substrate shows a lower limit of detection to 10^-10 mol·L^-1 for R6G and favorable uniformity through SERS mapping-scan spectra. The SERS signals collected at 120 points over a 30 μm×30 μm area present relative standard deviation of~12%.
- silver,
- nanoparticles,
- polymers,
- honeycomb-like array,
- SERS,
- breath figure method
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