Citation: TANG Xiao-Ning, SHAO Jiao-Jing. Preparation and Catalytic Properties of Nitrogen Doped Graphene/Copper-Based Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1767-1772. doi: 10.11862/CJIC.2019.219 shu

Preparation and Catalytic Properties of Nitrogen Doped Graphene/Copper-Based Catalyst

TANG Xiao-Ning ,
SHAO Jiao-Jing ^,

School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China

Corresponding author: SHAO Jiao-Jing, shaojiao_jing@163.com
Received Date: 24 May 2019
Revised Date: 26 July 2019

Figures(6)

Nitrogen doped graphene (N/GN) and nitrogen doped graphene/copper-based catalyst (Cu-N/GN) were fabricated by hydrothermal treatment and ultrasonic-assisted equal volume impregnation method, respectively. The microstructure, morphology and elemental composition of Cu-N/GN catalyst were respectively characterized by XRD, SEM, TEM, N₂ adsorption-desorption, XPS and XAES. The catalytic performance of Cu-N/GN toward acetylene hydrochlorination was investigated. The results shown that the size of Cu particles is small and Cu species uniform distribution loading N/GN sheets with relatively low amount of Cu (3.6%) in the catalyst. The Cu-N/GN catalyst exhibits good catalytic activity for the acetylene hydrochlorination, and its acetylene conversion and vinyl chloride selectivity are about 68% and 99%, respectively.
- acetylene hydrochlorination,
- nitrogen doped grapheme,
- copper-based catalyst,
- ultrasonic-assisted
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