Citation: ZHANG Mei-Li, ZHENG Yan-Jin, LIU Min, REN Yi-Xia, WANG Ji-Jiang, CUI Hua-Li, LIU Lin. Crystal Structure and Electrochemistry Properties of Three Co(Ⅱ) Complexes Based on Flexible Phenylenediacetate Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1813-1820. doi: 10.11862/CJIC.2019.214 shu

Crystal Structure and Electrochemistry Properties of Three Co(Ⅱ) Complexes Based on Flexible Phenylenediacetate Ligands

Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: ZHANG Mei-Li, ydzml2332041@163.com
Received Date: 12 April 2019
Revised Date: 2 August 2019

Figures(5)

Three new coordination complexes, {[Co_1.5(opda)_1.5(mbib)₂(H₂O)₂]·H₂O}_n (1), {[Co(mpda)(mbib)]·H₂O}_n (2) and {[Co(ppda)(mbib)]·H₂O}_n (3) (H₂opda=1, 2-phenylenediacetic acid, H₂mpda=1, 3-phenylenediacetic acid, H₂ppda=1, 4-phenylenediacetic acid, mbib=1, 3-bis(1-imidazoly)benzene), have been synthesized by using cobalt salt and bis(imidazole) ligand in the presence of different flexible phenylenediacetate blocks under hydrothermal conditions, and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray crystallography. Single-crystal X-ray diffraction analysis revealed that the diverse structures of these complexes are mainly attributed to various coordination geometries of the central cobalt(Ⅱ) cations, coordination modes and conformations of the flexible phenylenediacetic acid and bis(imidazole) ligands. Furthermore, thermal gravimetric analysis (TGA) and the electrochemistry properties of 1~3 are also investigated, and all of them have good cyclic voltammograms.
- coordination polymer,
- crystal structure,
- electrochemistry property
1. [1]
  Li D S, Wu Y P, Zhao J, et al. Coord. Chem. Rev., 2014, 261:1-27 doi: 10.1016/j.ccr.2013.11.004
2. [2]
  Zhao Y, Deng D S, Ma L F, et al. Chem. Commun., 2013, 49:10299-10301 doi: 10.1039/c3cc45310c
3. [3]
  Hu Z, Deibert B J, Li J. Chem. Soc. Rev., 2014, 43:5815-5840 doi: 10.1039/C4CS00010B
4. [4]
  Li C P, Wang S, Guo W, et al. Chem. Commun., 2016, 52:11060-11063 doi: 10.1039/C6CC05938D
5. [5]
  Yang X G, Yan D P. Adv. Opt. Mater., 2016, 4:897-905 doi: 10.1002/adom.201500666
6. [6]
  Li B, Wen H M, Cui Y, et al. Adv. Mater., 2016, 28:8819-8860 doi: 10.1002/adma.201601133
7. [7]
  Zhang Y, Yuan S, Day G, et al. Coord. Chem. Rev., 2018, 354:28-45 doi: 10.1016/j.ccr.2017.06.007
8. [8]
  Cui Y, Yue Y, Qian G, et al. Chem. Rev., 2011, 112:1126-1162
9. [9]
  Yu Y, Yue C, Lin X, et al. ACS Appl. Mater. Interfaces, 2016, 8:3992-3999 doi: 10.1021/acsami.5b11287
10. [10]
  Horcajada P, Gref R, Baati T, et al. Chem. Rev., 2012, 112:1232-1268 doi: 10.1021/cr200256v
11. [11]
  Zheng H, Zhang Y, Liu L, et al. J. Am. Chem. Soc., 2016, 138:962-968 doi: 10.1021/jacs.5b11720
12. [12]
  Fan J, Sun W Y, Okamura T, et al. Inorg. Chem., 2003, 42:3168-3175 doi: 10.1021/ic0206847
13. [13]
  Ma L F, Wang Y Y, Liu J Q, et al. CrystEngComm, 2009, 11:1800-1802 doi: 10.1039/b904977k
14. [14]
  Su K, Jiang F L, Qian J J, et al. Inorg. Chem., 2013, 52:3780-3786 doi: 10.1021/ic302367q
15. [15]
  Luo J H, Jiang F L, Wang R H, et al. Inorg. Chem. Commun., 2004, 7:638-642 doi: 10.1016/j.inoche.2004.03.007
16. [16]
  Zhang M L, Wang J J, Ma Z Z, et al. New J. Chem., 2017, 41:12139-12146 doi: 10.1039/C7NJ00645D
17. [17]
  Zhang M L, Zheng Y J, Ma Z Z, et al. Polyhedron, 2018, 146:180-186 doi: 10.1016/j.poly.2018.03.005
18. [18]
  Sheldrick G M. Acta Crystallogr. Sect. A:Found. Crystallogr., 2008, 64:112-122 doi: 10.1107/S0108767307043930
19. [19]
  Deilami A B, Salehi M, Arab A. Inorg. Chim. Acta, 2018, 476:93-100 doi: 10.1016/j.ica.2018.02.013
20. [20]
  Lim I T, Choi K Y. Molecules, 2013, 18:6608-6619 doi: 10.3390/molecules18066608
21. [21]
  WANG Qin-Hua, YU Li-Li, LIU Qi, et al. Chinese J. Inorg. Chem., 2011, 27:989-995
1. [1]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
2. [2]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
3. [3]
  Yinxia SUN , Liping LIU , Xue BAI , Yu SUN , Wanhong SUN , Zhepeng DENG , Jianghai CHEN , Jianjun WANG , Li XU , Shuzhen ZHANG . Synthesis and crystal structures of Co(Ⅱ)/Cu(Ⅱ) coordination polymers based on solvent and ligand concentration regulation strategy. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 340-354. doi: 10.11862/CJIC.20250226
4. [4]
  Youbo HU , Donggang LI , Changhua SUN , Zhenzhong LU , Songjun GU . Coordination polymers based on anthracene- and pyrene-derived ligands: Crystal structure, fluorescent property, and framework isomerization. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1681-1688. doi: 10.11862/CJIC.20250004
5. [5]
  Xiaonan LI , Hui HAN , Yihan ZHANG , Jing XIONG , Tingting GUO , Juanzhi YAN . A viologen‐based Cd(Ⅱ) coordination polymer: Self‐assembly, thermochromism, and electrochemical property. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1439-1444. doi: 10.11862/CJIC.20240376
6. [6]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
7. [7]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
8. [8]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
9. [9]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
10. [10]
  Jing REN , Ruikui YAN , Xiaoli CHEN , Huali CUI , Hua YANG , Jijiang WANG . Synthesis and fluorescence sensing of a highly sensitive and multi-response cadmium coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 574-586. doi: 10.11862/CJIC.20240287
11. [11]
  Yu BAI , Jijiang WANG , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A cadmium(Ⅱ) coordination polymer based on a semirigid tetracarboxylate ligand for highly selective detection of Fe³⁺ and 4-nitrophenol. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1217-1226. doi: 10.11862/CJIC.20240457
12. [12]
  Hongren RONG , Gexiang GAO , Zhiwei LIU , Ke ZHOU , Lixin SU , Hao HUANG , Wenlong LIU , Qi LIU . High-performance supercapacitor based on 1D cobalt-based coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1183-1195. doi: 10.11862/CJIC.20250034
13. [13]
  Zihe SONG , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Crystal structure, thermal analysis, and luminescence properties of six heterocyclic lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 181-192. doi: 10.11862/CJIC.20250126
14. [14]
  Ruiyan CHEN , Yanping HE , Jian ZHANG . Synthesis and third-order nonlinear optical property of Ti₄L₆ cage-based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2149-2156. doi: 10.11862/CJIC.20250177
15. [15]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
16. [16]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
17. [17]
  Yingyue ZHANG , Liuqing KANG , Yating YANG , Xiaofen GUAN , Wenmin WANG . Crystal structure and antibacterial activity of two Gd₂ complexes based on polydentate Schiff-base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1867-1877. doi: 10.11862/CJIC.20250100
18. [18]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
19. [19]
  Jiarong ZHU , Xiaohua ZHANG , Xinting XIONG , Xuliang NIE , Xiuying SONG , Miaomiao ZHANG , Dayong PENG , Xiuguang YI . Crystal structure, Hirshfeld surface analysis, and antifungal activity of five complexes based on 2,5-bis(carboxymethoxy)terephthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2358-2370. doi: 10.11862/CJIC.20250150
20. [20]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(811)
HTML views(115)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142