Citation: HU Ying-Lu, LU Wen-Jun, GUO Ming, WANG Jue. Preparation and Cadmium Ion Sensing Properties of Ionic Imprinted Materials Based on HNTs[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1755-1766. doi: 10.11862/CJIC.2019.213 shu

Preparation and Cadmium Ion Sensing Properties of Ionic Imprinted Materials Based on HNTs

HU Ying-Lu ¹ ,
LU Wen-Jun ² ,
GUO Ming ^1,3,, ,
WANG Jue ²

1.
College of Engineering, Zhejiang A & F University, Lin'an, Zhejiang 311300, China
2.
Forestry and Biotechnology College, Zhejiang A & F University, Lin'an, Zhejiang 311300, China
3.
College of Science, Zhejiang A & F University, Lin'an, Zhejiang 311300, China

Corresponding author: GUO Ming, guoming@zafu.edu.cn
Received Date: 2 April 2019
Revised Date: 9 August 2019

Figures(14)

We used surface imprinting polymerization to prepare the sensing material HNTs@ⅡPs modified by hyperbranched imprinting polymers (HNTs=halloysite nanotubes). Fourier transform infrared spectroscopy (FTIR), XRD, SEM, nuclear magnetic and thermogravimetry proved that HNTs@ⅡPs was successfully synthesized. Then, we used cyclic voltammetry, differential pulse voltammetry and electrochemical impedance spectroscopy to investigate the electrochemical properties and specific sensing properties to cadmium ion of HNTs@ⅡPs. The results showed that when c_Cd²⁺≤ 0.125 μmol·L^-1, the peak current of the sensing material had a good quantitative relationship with c_Cd²⁺, and the detection limit is 0.026 μmol·L^-1. The imprinting factor was 5.97 and the selective factor was 4.97, which indicates that the HNTs@ⅡPs have specificity and strong selective adsorption to Cd²⁺. It suggests that HNTs@ⅡPs can be used to detect the concentration of Cd²⁺. The equivalent electrical circuit model of the sensor was obtained by fitting the results of impedance spectrum analysis and the sensing mechanism was analyzed and illustrated.
- halloysite nanotubes,
- sensing material,
- cadmium ions,
- specificity
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