Citation: HU Ying-Lu, LU Wen-Jun, GUO Ming, WANG Jue. Preparation and Cadmium Ion Sensing Properties of Ionic Imprinted Materials Based on HNTs[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1755-1766. doi: 10.11862/CJIC.2019.213 shu

Preparation and Cadmium Ion Sensing Properties of Ionic Imprinted Materials Based on HNTs

HU Ying-Lu ¹ ,
LU Wen-Jun ² ,
GUO Ming ^1,3,, ,
WANG Jue ²

1.
College of Engineering, Zhejiang A & F University, Lin'an, Zhejiang 311300, China
2.
Forestry and Biotechnology College, Zhejiang A & F University, Lin'an, Zhejiang 311300, China
3.
College of Science, Zhejiang A & F University, Lin'an, Zhejiang 311300, China

Corresponding author: GUO Ming, guoming@zafu.edu.cn
Received Date: 2 April 2019
Revised Date: 9 August 2019

Figures(14)

We used surface imprinting polymerization to prepare the sensing material HNTs@ⅡPs modified by hyperbranched imprinting polymers (HNTs=halloysite nanotubes). Fourier transform infrared spectroscopy (FTIR), XRD, SEM, nuclear magnetic and thermogravimetry proved that HNTs@ⅡPs was successfully synthesized. Then, we used cyclic voltammetry, differential pulse voltammetry and electrochemical impedance spectroscopy to investigate the electrochemical properties and specific sensing properties to cadmium ion of HNTs@ⅡPs. The results showed that when c_Cd²⁺≤ 0.125 μmol·L^-1, the peak current of the sensing material had a good quantitative relationship with c_Cd²⁺, and the detection limit is 0.026 μmol·L^-1. The imprinting factor was 5.97 and the selective factor was 4.97, which indicates that the HNTs@ⅡPs have specificity and strong selective adsorption to Cd²⁺. It suggests that HNTs@ⅡPs can be used to detect the concentration of Cd²⁺. The equivalent electrical circuit model of the sensor was obtained by fitting the results of impedance spectrum analysis and the sensing mechanism was analyzed and illustrated.
- halloysite nanotubes,
- sensing material,
- cadmium ions,
- specificity
1. [1]
  Rao K M, Kumar A, Suneetha M, et al. Int. J. Biol. Macromol., 2018, 112:119-125 doi: 10.1016/j.ijbiomac.2018.01.163
2. [2]
  Zhang J, Liu T, Liu M. Microporous Mesoporous Mater., 2018, 266:155-163 doi: 10.1016/j.micromeso.2018.02.027
3. [3]
  Ghanbari M, Emadzadeh D, Lau W J, et al. Desalination, 2015, 358:33-41 doi: 10.1016/j.desal.2014.11.035
4. [4]
  Bottino M C, Yassen G H, Platt J A, et al. J. Tissue Eng. Regener. Med., 2015, 9(11):E116-E123 doi: 10.1002/term.1712
5. [5]
  Mills D K, Sun L. IEEE Engineering in Medicine and Biology Society Conference Proceedings. IEEE Ed. New York:IEEE, 2014:2920-2923
6. [6]
  Liu H Y, Du L, Zhao Y T, et al. J. Nanomater., 2015:1-9
7. [7]
  Ao G, Nepal D, Aono M, et al. ACS Nano, 2011, 5(2):1450-1458 doi: 10.1021/nn103225r
8. [8]
  Li XIA-Zhang, YIN Yu, YAO Chao, et al. Journal of the Chinese Ceramic Society, 2015, 43(4):482-487
9. [9]
  Sadjadi S, Heravi M M, Malmir M. Carbohydr. Polym., 2018, 186(15):25-34
10. [10]
  Xing X, Wang J, Hu W, et al. Colloids Surf. A, 2018, 553(20):305-311
11. [11]
  Paola M D, Quarta A, Pisani P, et al. IEEE Trans. Nanotechnol., 2016, 15(5):770-774 doi: 10.1109/TNANO.2016.2546955
12. [12]
  CHENG Zhi-Lin, CAO Bao-Chong, LIU Zan. Chinese J. Inorg. Chem., 2018, 34(10):43-51
13. [13]
  Farrokhi-Rad M, Mohammadalipour M, Shahrabi T. J. Eur. Ceram. Soc., 2018, 38(10):3650-3659 doi: 10.1016/j.jeurceramsoc.2018.03.048
14. [14]
  LI Jie, YAO Chao, ZHANG Shan, et al. Journal of the Chinese Ceramic Society, 2014, 42(2):241-247
15. [15]
  HU Cheng-Guo, WANG Wan-Lu. Journal of Functional Materials, 2005, 36(5):730-733 doi: 10.3321/j.issn:1001-9731.2005.05.027
16. [16]
  Sun Z, Yuan H, Liu Z, et al. Adv. Mater., 2010, 17(24):2993-2997
17. [17]
  SUN Xia, ZHAO Wen-Ping, LIU Zhong-He, et al. Food Science, 2012, 33(4):282-286
18. [18]
  El-Wakeel S T, El-Tawil R S, Abuzeid H A M, et al. J. Taiwan Inst. Chem. Eng., 2017, 72:95-103 doi: 10.1016/j.jtice.2017.01.008
19. [19]
  HAO Ying, YANG Qing-Xiang, QI Lian-Huai, et al. Polym. Mater. Sci. Eng., 2014, 30(5):154-158
20. [20]
  Sebastian M, Mathew B. J. Mater. Sci., 2018, 53(5):3557-3572 doi: 10.1007/s10853-017-1787-x
21. [21]
  Zhong S, Zhou C, Zhang X, et al. J. Hazard. Mater., 2014, 276(9):58-65
22. [22]
  Pan J, Hang H, Dai X, et al. J. Mater. Chem., 2012, 22(33):17167-17175 doi: 10.1039/c2jm32821f
23. [23]
  He H X, Gan Q, Feng C G. Chin. J. Polym. Sci., 2018, 36(4):462-471 doi: 10.1007/s10118-018-2063-5
24. [24]
  TANG Xue-Jiao, YAO Yan, MA Hong-Qing, et al. Technology of Water Treatment, 2011, 37(9):33-36
25. [25]
  Hande P E, Sanui A B, Kulkami P S. Environ. Sci. Pollut. Res. Int., 2015, 22(10):7375-7404 doi: 10.1007/s11356-014-3937-x
26. [26]
  Fu J, Chen L, Li J, et al. J. Mater. Chem. A, 2015, 3(26):13598-13627 doi: 10.1039/C5TA02421H
27. [27]
  Fayazi M, Taher M A, Afzali D, et al. Mater. Sci. Eng. C:Mater. Biol. Appl., 2016, 60(1):365-373
28. [28]
29. [29]
  GUO Ming, LIANG Dong-Jun, TAN Xian. Chinese Journal of Pesticide Science, 2014, 16(3):319-329 doi: 10.3969/j.issn.1008-7303.2014.03.12
30. [30]
  Calfum K, Aguirre M J, Villagra D. J. Solid State Electrochem., 2010, 14(6):1065-1072 doi: 10.1007/s10008-009-0916-0
31. [31]
32. [32]
  Zhang Z H, Yang X, Zhang H B, et al. J. Chromatogr. B, 2011, 879(19):1617-1624 doi: 10.1016/j.jchromb.2011.03.054
33. [33]
  WAN Xiao-Fan, WANG Xiao-Jun. Journal of South China University of Technology:Nat. Sci. Ed., 2008, 36(3):69-72
34. [34]
  GUO Ming, TAN Xian, LIANG Dong-Jun, et al. Chinese Journal of Pesticide Science, 2014, 16(5):559-569 doi: 10.3969/j.issn.1008-7303.2014.05.10
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