Citation: WANG Lan, WEI Zhi-Li, YU Meng, PAN Ying-Qi, ZHANG Yang, DONG Wen-Kui. Multihalogen-Substituted Salamo-Type Mn(Ⅱ) Complexes: Syntheses, Crystal Structures, Hirshfeld Analyses and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1791-1804. doi: 10.11862/CJIC.2019.212 shu

Multihalogen-Substituted Salamo-Type Mn(Ⅱ) Complexes: Syntheses, Crystal Structures, Hirshfeld Analyses and Fluorescence Properties

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: DONG Wen-Kui, dongwk@126.com
Received Date: 15 January 2019
Revised Date: 6 August 2019

Figures(16)

Two manganese(Ⅱ) complexes[Mn(L¹)(H₂O)₂] (1) and[Mn(L²)(H₂O)₂]·0.37H₂O (2) were synthesized by the reactions of halogen-substituted salamo-type bisoxime ligands H₂L¹, H₂L¹ with manganese(Ⅱ) acetate tetrahydrate in organic solvents, and the two complexes were characterized by the means of elemental analyses, FT-IR, UV-visible absorption spectra, single-crystal X-ray diffractions, fluorescence spectra and Hirshfeld surfaces analyses. X-ray crystallography results indicated that the manganese(Ⅱ) ions in the two complexes are all six-coordinated, in which the N₂O₂ of the salamo-type ligand occupied the planar position, and two coordinated water molecules occupied the axial positions, forming distorted octahedral coordination geometries. Due to abundant hydrogen bonding interactions, infinite 1D and 2D supramolecular structures are formed in complexes 1 and 2, respectively.
- samalo-type ligand,
- complex,
- synthesis,
- fluorescence property,
- Hirshfeld surface analysis
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