Citation: LI Yu, PAN Guang-Min, ZOU Xun-Zhong, FENG An-Sheng, YOU Ao, QIU Wen-Da. Syntheses, Crystal Structures, Luminescent and Magnetic Properties of One 0D Zinc(Ⅱ) and Two 1D Manganese(Ⅱ) Coordination Compounds Assembled from Pyridine-Tricarboxylate Blocks[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1853-1860. doi: 10.11862/CJIC.2019.206 shu

Syntheses, Crystal Structures, Luminescent and Magnetic Properties of One 0D Zinc(Ⅱ) and Two 1D Manganese(Ⅱ) Coordination Compounds Assembled from Pyridine-Tricarboxylate Blocks

LI Yu ¹ ,
PAN Guang-Min ² ,
ZOU Xun-Zhong ¹ ,
FENG An-Sheng ¹ ,
YOU Ao ^1,, ,
QIU Wen-Da ^1,,

1.
Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
School of Chemical Engineering and Light Industry, Guangdong University of Techlonogy, Guangzhou 510006, China

Corresponding author: YOU Ao, youao321@163.com QIU Wen-Da, Qiuwdgq@hotmail.com
Received Date: 23 May 2019
Revised Date: 14 June 2019

Figures(9)

One 0D zinic(Ⅱ) and two 1D manganese(Ⅱ) coordination compounds, namely[Zn(H₂biim)₂(H₂O)₂] [Zn(HL)(Hbiim)(H₂O)]₂·8H₂O (1), [Mn(μ-HL)(phen)(H₂O)]_n (2) and {[Mn(μ-HL)(2, 2'-bipy)(H₂O)]·0.5(2, 2'-bipy)}_n (3) have been constructed hydrothermally using H₃L (H₃L=4-(6-carboxy-pyridin-3-yl)-isophthalic acid), H₂biim (H₂biim=2, 2'-biimidazole), phen (phen=1, 10-phenanthroline), 2, 2'-bipy (2, 2'-bipy=2, 2'-bipyridine), and zinc or manganese chlorides. Single-crystal X-ray diffraction analyses reveal that three compounds crystallize in the monoclinic system, space groups P2₁/n or P2₁/c. Compound 1 shows a 0D structure composed of three monomer Zn(Ⅱ) units, which is arranged into a 3D supramolecular framework through O-H…O/N or N-H…O hydrogen bonds. Compounds 2 and 3 feature a 1D metal-organic chain, which is assembled to a 2D supramolecular network through O-H…O hydrogen bond. The luminescent and magnetic properties for three compounds were also investigated.
- coordination polymer,
- pyridine-tricarboxylic acid,
- luminescent properties,
- magnetic properties
1. [1]
  Gu J Z, Kirillov A M, Wu J, et al. CrystEngComm, 2013, 15:10287-10303 doi: 10.1039/c3ce41457d
2. [2]
  Gu J Z, Wen M, Cai Y, et al. Inorg. Chem., 2019, 58:2403-2412 doi: 10.1021/acs.inorgchem.8b02926
3. [3]
  Chen Q, Xue W, Lin J B, et al. Chem. Eur. J., 2016, 22:12088-12094 doi: 10.1002/chem.201601826
4. [4]
  Liu Z Q, Chen K, Zhao Y, et al. Cryst. Growth Des., 2018, 18:1136-1146 doi: 10.1021/acs.cgd.7b01572
5. [5]
  Hou L, Liu B, Jia L N, et al. Cryst. Growth Des., 2013, 13:701-707 doi: 10.1021/cg301413u
6. [6]
  Pal S, Pal T K, Bharadwaj P K. CrystEngComm, 2016, 18:1825-1831 doi: 10.1039/C5CE02540K
7. [7]
  Zhang L N, Zhang C, Zhang B, et al. CrystEngComm, 2015, 17:2837-2846 doi: 10.1039/C5CE00263J
8. [8]
  Gu J Z, Gao Z Q, Tang Y. Cryst. Growth Des., 2012, 12:3312-3323 doi: 10.1021/cg300442b
9. [9]
  Du M, Li C P, Liu C S, et al. Coord. Chem. Soc., 2013, 257:1282-1305 doi: 10.1016/j.ccr.2012.10.002
10. [10]
  Gu J Z, Cui Y H, Liang X X, et al. Cryst. Growth Des., 2016, 16:4658-4670 doi: 10.1021/acs.cgd.6b00735
11. [11]
  Wan J, Cai S L, Zhang K, et al. CrystEngComm, 2016, 18:5164-5176 doi: 10.1039/C6CE00853D
12. [12]
  Gu J Z, Cai Y, Qian Z Y, et al. Dalton Trans., 2018, 47:7431-7444 doi: 10.1039/C8DT01299G
13. [13]
  Peng Y W, Wu R J, Liu M, et al. Cryst. Growth Des., 2019, 19:1322-1328 doi: 10.1021/acs.cgd.8b01709
14. [14]
  GU Wen-Jun, GU Jin-Zhong. Chinese J. Inorg. Chem., 2017, 33(2):227-236
15. [15]
  ZHAO Su-Qin, GU Jin-Zhong. Chinese J. Inorg. Chem., 2016, 32(9):1611-1618
16. [16]
  Gu J Z, Wen M, Liang X X. Crystals, 2018, 8:83 doi: 10.3390/cryst8020083
17. [17]
  Peng Y W, Wu R J, Liu M, et al. Cryst. Growth Des., 2019, 19:1322-1328 doi: 10.1021/acs.cgd.8b01709
18. [18]
  YOU Li-Xin, WANG Shu-Jü, XIONG Gang, et al. Chinese J. Inorg. Chem., 2015, 31(2):323-328
19. [19]
  Spek A L. Acta Crystallogr. Sect. C:Struct. Chem., 2015, C71:9-18
20. [20]
  Fisher M E. Am. J. Phys., 1964, 32:343-346 doi: 10.1119/1.1970340
1. [1]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
2. [2]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
3. [3]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
4. [4]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
5. [5]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
6. [6]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
7. [7]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
8. [8]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
9. [9]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
10. [10]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
11. [11]
  Chaochao Jin , Kai Li , Jiongpei Zhang , Zhihua Wang , Jiajing Tan . N,O-Bidentated difluoroboron complexes based on pyridine-ester enolates: Facile synthesis, post-complexation modification, optical properties, and applications. Chinese Chemical Letters, 2024, 35(9): 109532-. doi: 10.1016/j.cclet.2024.109532
12. [12]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
13. [13]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
14. [14]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
15. [15]
  Yue Mao , Zhonghang Chen , Tiankai Sun , Wenyue Cui , Peng Cheng , Wei Shi . Luminescent coordination polymers with mixed carboxylate and triazole ligands for rapid detection of chloroprene metabolite. Chinese Journal of Structural Chemistry, 2024, 43(9): 100353-100353. doi: 10.1016/j.cjsc.2024.100353
16. [16]
  Zhihao Gu , Jiabo Le , Hehe Wei , Zehui Sun , Mahmoud Elsayed Hafez , Wei Ma . Unveiling the intrinsic properties of single NiZnFeO_x entity for promoting electrocatalytic oxygen evolution. Chinese Chemical Letters, 2024, 35(4): 108849-. doi: 10.1016/j.cclet.2023.108849
17. [17]
  Wenzhong Zhang , Zirui Yan , Lingcheng Chen , Yi Xiao . Sn-fused perylene diimides: Synthesis, mechanism, and properties. Chinese Chemical Letters, 2024, 35(10): 109582-. doi: 10.1016/j.cclet.2024.109582
18. [18]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
19. [19]
  Yanbing Shen , Yuan Yuan , Yaxin Wang , Xiaonan Ma , Wensheng Yang , Yulan Chen . Dihydroanthracene bridged bis-naphthopyrans: A multimodal chromophore with mechano- and photo-chromic properties. Chinese Chemical Letters, 2024, 35(5): 108949-. doi: 10.1016/j.cclet.2023.108949
20. [20]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(215)
HTML views(45)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142