Citation: HU Zhuo, LUO Ran, WANG Shu-Hua, ZHANG Ning, CHEN Chao. Two Metal-Organic Coordination Polymer for Fluorescence Detection of 4-Nitrophenol[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(9): 1586-1592. doi: 10.11862/CJIC.2019.191 shu

Two Metal-Organic Coordination Polymer for Fluorescence Detection of 4-Nitrophenol

Key Laboratory of Jiangxi Province for Environment and Energy, College of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: WANG Shu-Hua, shwang@ncu.edu.cn CHEN Chao, chaochen@ncu.edu.cn
Received Date: 15 April 2019
Revised Date: 21 June 2019

Figures(7)

Two new 1D chain luminescence metal-organic coordination polymers[Zn(H₂BBP)(BDC)]_n (1) and {[Cd₂(H₂BBP)₂(BDC)₂]·3H₂O}_n (2) were prepared by hydrothermal method using the rigid 2, 6-bis(benzimidazolyl)pyridine (H₂BBP) and ancillary ligand terephthalic acid (BDC) as the ligands. The metal ion in compound 1 was coordinated with the carboxyl group of the BDC ligand by the monodentate mode, while the metal ion in the compound 2 was monodentate-bidentate heterozygous coordination, which results in the different angles of 1D zigzag chain in compound 1 and compound 2. 4-Nitrophenol (4-NP) detection of compounds 1 and 2 was carried out by fluorescence spectroscopy. The results show that 4-NP has strong fluorescence quenching effect on compounds 1 and 2, and the detection limit of compound 1 could be as low as 30.96 μg·L^-1.
- metal-organic coordination polymer,
- crystal structure,
- fluorescence detection,
- 4-nitrophenol
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