Citation: HU Zhuo, LUO Ran, WANG Shu-Hua, ZHANG Ning, CHEN Chao. Two Metal-Organic Coordination Polymer for Fluorescence Detection of 4-Nitrophenol[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(9): 1586-1592. doi: 10.11862/CJIC.2019.191 shu

Two Metal-Organic Coordination Polymer for Fluorescence Detection of 4-Nitrophenol

Key Laboratory of Jiangxi Province for Environment and Energy, College of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: WANG Shu-Hua, shwang@ncu.edu.cn CHEN Chao, chaochen@ncu.edu.cn
Received Date: 15 April 2019
Revised Date: 21 June 2019

Figures(7)

Two new 1D chain luminescence metal-organic coordination polymers[Zn(H₂BBP)(BDC)]_n (1) and {[Cd₂(H₂BBP)₂(BDC)₂]·3H₂O}_n (2) were prepared by hydrothermal method using the rigid 2, 6-bis(benzimidazolyl)pyridine (H₂BBP) and ancillary ligand terephthalic acid (BDC) as the ligands. The metal ion in compound 1 was coordinated with the carboxyl group of the BDC ligand by the monodentate mode, while the metal ion in the compound 2 was monodentate-bidentate heterozygous coordination, which results in the different angles of 1D zigzag chain in compound 1 and compound 2. 4-Nitrophenol (4-NP) detection of compounds 1 and 2 was carried out by fluorescence spectroscopy. The results show that 4-NP has strong fluorescence quenching effect on compounds 1 and 2, and the detection limit of compound 1 could be as low as 30.96 μg·L^-1.
- metal-organic coordination polymer,
- crystal structure,
- fluorescence detection,
- 4-nitrophenol
1. [1]
  Huang Y B, Liang J, Wang X S, et al. Chem. Soc. Rev., 2017, 46(1):126-157 doi: 10.1039/C6CS00250A
2. [2]
  Doonan C, Ricco R, Liang K, et al. Acc. Chem. Res., 2017, 50(6):1423-1432 doi: 10.1021/acs.accounts.7b00090
3. [3]
  Yang Q, Xu Q, Jiang H L. Chem. Soc. Rev., 2017, 46(15):4774-4808 doi: 10.1039/C6CS00724D
4. [4]
  Yi F Y, Chen D, Wu M K, et al. ChemPlusChem, 2016, 81(8):675-690 doi: 10.1002/cplu.201600137
5. [5]
  Li J R, Sculley J, Zhou H C. Chem. Rev., 2012, 112(2):869-932 doi: 10.1021/cr200190s
6. [6]
  Chen B, Wang L, Xiao Y, et al. Angew. Chem. Int. Ed., 2009, 48(3):500-503 doi: 10.1002/anie.200805101
7. [7]
  Chen B L, Wang L, Qian G, et al. J. Am. Chem. Soc., 2008, 130(21):6718-6719 doi: 10.1021/ja802035e
8. [8]
  Singh D, Nagaraja C M. Dalton Trans., 2014, 43(48):17912-17915 doi: 10.1039/C4DT02841D
9. [9]
  Ye J, Zhao L, Bogale R F, et al. Chem. Eur. J., 2015, 21(5):2029-2037 doi: 10.1002/chem.201405267
10. [10]
  Buragohain A, Yousufuddin M, Sarma M, et al. Cryst. Growth Des., 2016, 16(2):842-851 doi: 10.1021/acs.cgd.5b01427
11. [11]
  Gogoi C, Biswas S. Dalton Trans., 2018, 47(41):14696-14705 doi: 10.1039/C8DT03058H
12. [12]
  Zhang Q, Lei M, Zhang J, et al. J. Lumin., 2016, 180:287-291 doi: 10.1016/j.jlumin.2016.08.055
13. [13]
  Berg M, Bolotin J, Hofstetter T B. Anal. Chem., 2007, 79(6):2386-2393 doi: 10.1021/ac0622577
14. [14]
  Yang J M, Hu X W, Liu Y X, et al. Microporous Mesoporous Mater., 2019, 274:149-154 doi: 10.1016/j.micromeso.2018.07.042
15. [15]
  Wang D, Sun L, Hao C, et al. RSC Adv., 2016, 6(64):57828-57834
16. [16]
  Sheldrick G M. SHELXTL-NT, Ver. 5.10, Bruker AXS Inc., Madison, WI, 1997.
17. [17]
  Wang W, Yang J, Wang R, et al. Cryst. Growth Des., 2015, 15(6):2589-2592 doi: 10.1021/acs.cgd.5b00381
18. [18]
  Liu X G, Tao C L, Yu H Q, et al. J. Mater. Chem. A, 2018, 6(12):2983-2988
19. [19]
  He H, Song Y, Sun F, et al. Cryst. Growth Des., 2015, 15(4):2033-2038 doi: 10.1021/acs.cgd.5b00229
20. [20]
  FU Lin-Jie, LUO Ran, WANG Shu-Hua, et al. Chem. J. Chinese Universities, 2019, 40(3):419-424
1. [1]
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18. [18]
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