Citation: YANG Li-Guo, WANG Fang, GENG Cui-Huan, YU Zhi-Chao, WANG Xin, WANG Kai, ZHANG Yong-Hui, NIU Yong-Sheng, LI Da-Cheng. Heptanuclear Manganese Complexes with Schiff-Base Ligand: Syntheses, Crystal Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(9): 1651-1658. doi: 10.11862/CJIC.2019.164 shu

Heptanuclear Manganese Complexes with Schiff-Base Ligand: Syntheses, Crystal Structures and Magnetic Properties

1.
College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China
2.
School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252000, China

Corresponding author: YANG Li-Guo, lgyang@ayit.edu.cn
Received Date: 25 March 2019
Revised Date: 6 May 2019

Figures(8)

Two new mixed-valence heptanuclear manganese complexes, [Na₂Mn^ⅡMn₆^ⅢO₂(L)₆(N₃)₄(CH₃COO)₂]·4DMF (1) and[Na₂Mn^ⅡMn₆^ⅢO₂(L)₆(SCN)₄(CH₃COO)₂]·2DMF (²) (H₂L=3-ethoxy-6-(((2-hydroxyethyl)imino)methyl) phenol), were synthesized by treating the Schiff-base ligand with Mn(OAc)₂·4H₂O, and characterized by elemental analysis, IR spectra, thermogravimetric analyses and X-ray single crystal diffraction. X-ray single crystal diffraction analysis reveals that 1 and 2 have a similar new mixed-valence heptanuclear structure. The magnetic measurements indicate that 1 and 2 exhibit the antiferromagnetic interactions.
- manganese,
- Schiff base,
- crystal structures,
- magnetic properties
1. [1]
  Caneschi A, Gatteschi D, Sessoli R. J. Chem. Soc. Dalton Trans., 1997(21):3963-3970 doi: 10.1039/a704819j
2. [2]
  Wieghardt K. Angew. Chem. Int. Ed., 1994, 33(7):725-728 doi: 10.1002/anie.199407251
3. [3]
  Thomas L, Lionti F L, Ballou R, et al. Nature, 1996, 383(6596):145-147 doi: 10.1038/383145a0
4. [4]
  Squire R C, Aubin S M J, Folting K, et al. Inorg. Chem., 1995, 34(26):6463-6471 doi: 10.1021/ic00130a011
5. [5]
  Bhula R, Weatherburn D C. Angew. Chem. Int. Ed., 1991, 30(6):688-689 doi: 10.1002/anie.199106881
6. [6]
  Goldberg D P, Caneschi A, Delfs C D, et al. J. Am. Chem. Soc., 1995, 117(21):5789-5800 doi: 10.1021/ja00126a018
7. [7]
8. [8]
  (a) Milios C J, Vinslava A, Wernsdorfer W, et al. J. Am. Chem. Soc., 2007, 129(10): 2754-2755
  (b) Yang C I, Wernsdorfer W, Lee G H, et al. J. Am. Chem. Soc., 2007, 129(3): 456-457
  (c) Milios C J, Inglis R, Bagai R, et al. Chem. Commun., 2007(33): 3476-3478
  (d) Milios C J, Inglis R, Vinslava A, et al. J. Am. Chem. Soc., 2007, 129(41): 12505-12511
9. [9]
  (a) Brechin E K, Soler M, Christou G, et al. Chem. Commun., 2003(11): 1276-1277
  (b) Milios C J, Fabbiani F P A, Parsons S, et al. Dalton Trans., 2006(2): 351-356
10. [10]
  (a) Dendrinou-Samara C, Zaleski C M, Evagorou A, et al. Chem. Commun., 2003(21): 2668-2669
  (b) Boskovic C, Brechin E K, Streib W E, et al. Chem. Commun., 2001(5): 467-468
11. [11]
  Wu L J, Yang H, Zeng S Y, et al. Polyhedron, 2017, 129:77-81 doi: 10.1016/j.poly.2017.03.012
12. [12]
  Sheldrick G M. SADABS 2.05, University of Göttingen, 2000.
13. [13]
  Sheldrick G M. SHELXL Reference Manual, Ver.5.1, Madison, WI, Bruker Q16 Analytical X-Ray Systems, 1997.
14. [14]
  Milios C J, Gass I A, Vinslava A, et al. Inorg. Chem., 2007, 46(16):6215-6217 doi: 10.1021/ic7006638
15. [15]
  Cao F, Wei R M, Li J, et al. Inorg. Chem., 2016, 55(12):5914-5923 doi: 10.1021/acs.inorgchem.6b00255
1. [1]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
2. [2]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
3. [3]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
4. [4]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
5. [5]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
6. [6]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
7. [7]
  Tao Yu , Vadim A. Soloshonok , Zhekai Xiao , Hong Liu , Jiang Wang . Probing the dynamic thermodynamic resolution and biological activity of Cu(Ⅱ) and Pd(Ⅱ) complexes with Schiff base ligand derived from proline. Chinese Chemical Letters, 2024, 35(4): 108901-. doi: 10.1016/j.cclet.2023.108901
8. [8]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
9. [9]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
10. [10]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
11. [11]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
12. [12]
  Dong Cheng , Youyou Feng , Bingxi Feng , Ke Wang , Guoxin Song , Gen Wang , Xiaoli Cheng , Yonghui Deng , Jing Wei . Polyphenol-mediated interfacial deposition strategy for supported manganese oxide catalysts with excellent pollutant degradation performance. Chinese Chemical Letters, 2024, 35(5): 108623-. doi: 10.1016/j.cclet.2023.108623
13. [13]
  Yinyin Xu , Yuanyuan Li , Jingbo Feng , Chen Wang , Yan Zhang , Yukun Wang , Xiuwen Cheng . Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation. Chinese Chemical Letters, 2024, 35(4): 108838-. doi: 10.1016/j.cclet.2023.108838
14. [14]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
15. [15]
  Ming Huang , Xiuju Cai , Yan Liu , Zhuofeng Ke . Base-controlled NHC-Ru-catalyzed transfer hydrogenation and α-methylation/transfer hydrogenation of ketones using methanol. Chinese Chemical Letters, 2024, 35(7): 109323-. doi: 10.1016/j.cclet.2023.109323
16. [16]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323
17. [17]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
18. [18]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
19. [19]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
20. [20]
  Jun Lu , Jinrui Yan , Yaohao Guo , Junjie Qiu , Shuangliang Zhao , Bo Bao . Controlling solid form and crystal habit of triphenylmethanol by antisolvent crystallization in a microfluidic device. Chinese Chemical Letters, 2024, 35(4): 108876-. doi: 10.1016/j.cclet.2023.108876

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(179)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142