Citation: YANG Li-Guo, WANG Fang, GENG Cui-Huan, YU Zhi-Chao, WANG Xin, WANG Kai, ZHANG Yong-Hui, NIU Yong-Sheng, LI Da-Cheng. Heptanuclear Manganese Complexes with Schiff-Base Ligand: Syntheses, Crystal Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(9): 1651-1658. doi: 10.11862/CJIC.2019.164 shu

Heptanuclear Manganese Complexes with Schiff-Base Ligand: Syntheses, Crystal Structures and Magnetic Properties

1.
College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China
2.
School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252000, China

Corresponding author: YANG Li-Guo, lgyang@ayit.edu.cn
Received Date: 25 March 2019
Revised Date: 6 May 2019

Figures(8)

Two new mixed-valence heptanuclear manganese complexes, [Na₂Mn^ⅡMn₆^ⅢO₂(L)₆(N₃)₄(CH₃COO)₂]·4DMF (1) and[Na₂Mn^ⅡMn₆^ⅢO₂(L)₆(SCN)₄(CH₃COO)₂]·2DMF (²) (H₂L=3-ethoxy-6-(((2-hydroxyethyl)imino)methyl) phenol), were synthesized by treating the Schiff-base ligand with Mn(OAc)₂·4H₂O, and characterized by elemental analysis, IR spectra, thermogravimetric analyses and X-ray single crystal diffraction. X-ray single crystal diffraction analysis reveals that 1 and 2 have a similar new mixed-valence heptanuclear structure. The magnetic measurements indicate that 1 and 2 exhibit the antiferromagnetic interactions.
- manganese,
- Schiff base,
- crystal structures,
- magnetic properties
1. [1]
  Caneschi A, Gatteschi D, Sessoli R. J. Chem. Soc. Dalton Trans., 1997(21):3963-3970 doi: 10.1039/a704819j
2. [2]
  Wieghardt K. Angew. Chem. Int. Ed., 1994, 33(7):725-728 doi: 10.1002/anie.199407251
3. [3]
  Thomas L, Lionti F L, Ballou R, et al. Nature, 1996, 383(6596):145-147 doi: 10.1038/383145a0
4. [4]
  Squire R C, Aubin S M J, Folting K, et al. Inorg. Chem., 1995, 34(26):6463-6471 doi: 10.1021/ic00130a011
5. [5]
  Bhula R, Weatherburn D C. Angew. Chem. Int. Ed., 1991, 30(6):688-689 doi: 10.1002/anie.199106881
6. [6]
  Goldberg D P, Caneschi A, Delfs C D, et al. J. Am. Chem. Soc., 1995, 117(21):5789-5800 doi: 10.1021/ja00126a018
7. [7]
8. [8]
  (a) Milios C J, Vinslava A, Wernsdorfer W, et al. J. Am. Chem. Soc., 2007, 129(10): 2754-2755
  (b) Yang C I, Wernsdorfer W, Lee G H, et al. J. Am. Chem. Soc., 2007, 129(3): 456-457
  (c) Milios C J, Inglis R, Bagai R, et al. Chem. Commun., 2007(33): 3476-3478
  (d) Milios C J, Inglis R, Vinslava A, et al. J. Am. Chem. Soc., 2007, 129(41): 12505-12511
9. [9]
  (a) Brechin E K, Soler M, Christou G, et al. Chem. Commun., 2003(11): 1276-1277
  (b) Milios C J, Fabbiani F P A, Parsons S, et al. Dalton Trans., 2006(2): 351-356
10. [10]
  (a) Dendrinou-Samara C, Zaleski C M, Evagorou A, et al. Chem. Commun., 2003(21): 2668-2669
  (b) Boskovic C, Brechin E K, Streib W E, et al. Chem. Commun., 2001(5): 467-468
11. [11]
  Wu L J, Yang H, Zeng S Y, et al. Polyhedron, 2017, 129:77-81 doi: 10.1016/j.poly.2017.03.012
12. [12]
  Sheldrick G M. SADABS 2.05, University of Göttingen, 2000.
13. [13]
  Sheldrick G M. SHELXL Reference Manual, Ver.5.1, Madison, WI, Bruker Q16 Analytical X-Ray Systems, 1997.
14. [14]
  Milios C J, Gass I A, Vinslava A, et al. Inorg. Chem., 2007, 46(16):6215-6217 doi: 10.1021/ic7006638
15. [15]
  Cao F, Wei R M, Li J, et al. Inorg. Chem., 2016, 55(12):5914-5923 doi: 10.1021/acs.inorgchem.6b00255
1. [1]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
2. [2]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
3. [3]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
4. [4]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
5. [5]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
6. [6]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
7. [7]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
8. [8]
  Tao Yu , Vadim A. Soloshonok , Zhekai Xiao , Hong Liu , Jiang Wang . Probing the dynamic thermodynamic resolution and biological activity of Cu(Ⅱ) and Pd(Ⅱ) complexes with Schiff base ligand derived from proline. Chinese Chemical Letters, 2024, 35(4): 108901-. doi: 10.1016/j.cclet.2023.108901
9. [9]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
10. [10]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
11. [11]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
12. [12]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
13. [13]
  Chen Chen , Jinzhou Zheng , Chaoqin Chu , Qinkun Xiao , Chaozheng He , Xi Fu . An effective method for generating crystal structures based on the variational autoencoder and the diffusion model. Chinese Chemical Letters, 2025, 36(4): 109739-. doi: 10.1016/j.cclet.2024.109739
14. [14]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
15. [15]
  Yunlong Sun , Wei Ding , Yanhao Wang , Zhening Zhang , Ruyun Wang , Yinghui Guo , Zhiyuan Gao , Haiyan Du , Dong Ma . New insight into manganese-enhanced abiotic degradation of microplastics: Processes and mechanisms. Chinese Chemical Letters, 2025, 36(3): 109941-. doi: 10.1016/j.cclet.2024.109941
16. [16]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
17. [17]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
18. [18]
  Jimin HOU , Mengyang LI , Chunhua GONG , Shaozhuang ZHANG , Caihong ZHAN , Hao XU , Jingli XIE . Synthesis, structures, and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 549-560. doi: 10.11862/CJIC.20240348
19. [19]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
20. [20]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(230)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142