Citation: LIU Ling-Zhi, YU Meng, LI Xiao-Yan, KANG Quan-Peng, DONG Wen-Kui. Syntheses, Structures, Hirshfeld Analyses and Fluorescent Properties of Two Ni(Ⅱ) and Zn(Ⅱ) Complexes Constructed From a Bis(salamo)-like Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1283-1294. doi: 10.11862/CJIC.2019.158 shu

Syntheses, Structures, Hirshfeld Analyses and Fluorescent Properties of Two Ni(Ⅱ) and Zn(Ⅱ) Complexes Constructed From a Bis(salamo)-like Ligand

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: DONG Wen-Kui, dongwk@126.com
Received Date: 20 January 2019
Revised Date: 29 April 2019

Figures(11)

Two new homo-trinuclear Ni(Ⅱ) and Zn(Ⅱ) complexes, [Ni₃(L)(μ-OAc)₂(CH₃OH)₃]·CH₃OH·0.25CHCl₃ (1) and[Zn₃(L)(μ-OAc)₂(CH₃OH) (H₂O)]·2CH₃OH (2) with a newly synthesized C-type bis(salamo)-like ligand H₄L have been prepared and structurally characterized. The structures of complexes 1 and 2 were fully characterized by elemental analyses, FT-IR, UV-visible spectroscopy, single crystal X-ray crystallography, thermal analyses (TGA) and Hirshfeld surfaces analyses, and their luminescence properties were also discussed. The X-ray crystallography analyses demonstrated that complex 1 is an asymmetric trinuclear structure, and all Ni(Ⅱ) ions are hexa-coordinated, forming distorted octahedral geometries. Meanwhile, complex 2 is a symmetric trinuclear structure, the central Zn2 ion is hexa-coordinated and possesses a distorted octahedral coordination geometry. However, the terminal Zn1 and Zn1#1 ions are both penta-coordinated environments and adopt distorted trigonal bipyramidal geometries. In addition, 3D supramolecular architectures of complexes 1 and 2 were formed by hydrogen bonding and C-H…π interactions. Most importantly, the fluorescent property of complex 2 is totally different from that of complex 2.
- bis(salamo)-like ligand,
- complex,
- synthesis,
- Hirshfeld analysis,
- fluorescence property
1. [1]
  Akine S, Varadi Z, Nabeshima T. Eur. J. Inorg. Chem., 2013, 35:5987-5998
2. [2]
  Sun Y X, Wang X Y, Dong Z L, et al. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2013, 43:599-603 doi: 10.1080/15533174.2012.751424
3. [3]
  Wu H L, Bai Y H, Zhang Y H, et al. Z. Anorg. Allg. Chem., 2014, 640:2062-2071 doi: 10.1002/zaac.v640.10
4. [4]
  Akine S, Miyashita M, Piaob S, et al. Inorg. Chem. Front., 2014, 1:53-57 doi: 10.1039/C3QI00067B
5. [5]
  Wu H L, Wang H, Wang X L, et al. New J. Chem., 2014, 38:1052-1061 doi: 10.1039/c3nj01145c
6. [6]
  Song X Q, Peng Y J, Chen G Q, et al. Inorg. Chim. Acta, 2015, 427:13-21 doi: 10.1016/j.ica.2014.12.008
7. [7]
  Song X Q, Liu P P, Liu Y A, et al. Dalton Trans., 2016, 45:8154-8163 doi: 10.1039/C6DT00212A
8. [8]
  Zhou J J, Song X Q, Liu Y A, et al. RSC Adv., 2017, 7:25549-25559 doi: 10.1039/C7RA02386C
9. [9]
  Liu P P, Sheng L, Song X Q, et al. Inorg. Chim. Acta, 2015, 434:252-257 doi: 10.1016/j.ica.2015.05.026
10. [10]
  Canaj A B, Siczek M, Otrba M, et al. Dalton Trans., 2016, 45:18591-18602 doi: 10.1039/C6DT02932A
11. [11]
  Wang F, Xu Y L, Aderinto S O, et al. J. Photochem. Photobiol. A, 2017, 332:273-282 doi: 10.1016/j.jphotochem.2016.09.004
12. [12]
  Wu H L, Bai Y C, Zhang Y H, et al. J. Coord. Chem., 2014, 67:3054-3066 doi: 10.1080/00958972.2014.959507
13. [13]
  Wu H L, Pan G L, Bai Y C, et al. Res. Chem. Intermed., 2015, 41:3375-3388 doi: 10.1007/s11164-013-1440-5
14. [14]
  Yu B, Li C Y, Sun Y X, et al. Spectrochim. Acta Part A, 2017, 184:249-254 doi: 10.1016/j.saa.2017.05.012
15. [15]
  Chai L Q, Zhang K Y, Tang L J, et al. Polyhedron, 2017, 130:100-107 doi: 10.1016/j.poly.2017.04.010
16. [16]
  Chai L Q, Tang L J, Chen L C, et al. Polyhedron, 2017, 122:228-240 doi: 10.1016/j.poly.2016.11.032
17. [17]
  Zhou L, Hu Q, Chai L Q, et al. Polyhedron, 2019, 158:102-116 doi: 10.1016/j.poly.2018.10.052
18. [18]
  Chai L Q, Hu Q, Zhang K Y, et al. J. Lumin., 2018, 203:234-246 doi: 10.1016/j.jlumin.2018.06.058
19. [19]
  Chai L Q, Huang J J, Zhang H S, et al. Spectrochim. Acta Part A, 2014, 131:526-531 doi: 10.1016/j.saa.2014.04.127
20. [20]
  Chai L Q, Zhang J Y, Chen L C, et al. Res. Chem. Intermed., 2016, 42:3473-3488 doi: 10.1007/s11164-015-2226-8
21. [21]
  Chai L Q, Mao K H, Zhang J Y, et al. Inorg. Chim. Acta, 2017, 457:34-40 doi: 10.1016/j.ica.2016.12.004
22. [22]
  Chai L Q, Zhang H S, Huang J J, et al. Spectrochim. Acta Part A, 2015, 137:661-669 doi: 10.1016/j.saa.2014.08.084
23. [23]
  SUN Yin-Xia, LI Chun-Yu, YANG Cheng-Juan, et al. Chinese J. Inorg. Chem., 2016, 32:327-335
24. [24]
  SUN Yin-Xia, ZHAO Ya-Yuan, LI Chun-Yu, et al. Chinese J. Inorg. Chem., 2016, 32:913-920 doi: 10.11862/CJIC.2016.118
25. [25]
  Sun Y X, Gao X H. Synth. React. Inorg., Met.-Org. Nano-Met. Chem., 2011, 41:973-978 doi: 10.1080/15533174.2011.591329
26. [26]
  Jia H R, Li J, Sun Y X, et al. Crystals, 2017, 7:247 doi: 10.3390/cryst7080247
27. [27]
  Jia H R, Chang J, Zhang H J, et al. Crystals, 2018, 8:272 doi: 10.3390/cryst8070272
28. [28]
  Li J, Zhang H J, Chang J, et al. Crystals, 2018, 8:176 doi: 10.3390/cryst8040176
29. [29]
  Chin T K, Endud S, Jamil S, et al. Catal. Lett., 2013, 143:282-288 doi: 10.1007/s10562-012-0959-1
30. [30]
  Bella S D, Fragala I. Synth. Met., 2000, 115:191-196 doi: 10.1016/S0379-6779(00)00354-4
31. [31]
  Song X Q, Liu P P, Xiao Z R, et al. Inorg. Chim. Acta, 2015, 438:232-244 doi: 10.1016/j.ica.2015.09.022
32. [32]
  Wang P, Zhao L. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2016, 46:1095-1101 doi: 10.1080/15533174.2015.1004416
33. [33]
  Tao C H, Ma J C, Zhu L C, et al. Polyhedron, 2017, 128:38-45 doi: 10.1016/j.poly.2017.02.040
34. [34]
  Zhang Y, Liu L Z, Pan Y Q, et al. Crystals, 2018, 8:259 doi: 10.3390/cryst8070259
35. [35]
  Dong X Y, Zhao Q, Kang Q P, et al. Crystals, 2018, 8:230 doi: 10.3390/cryst8050230
36. [36]
  Dong X Y, Akogun S F, Zhou W M, et al. J. Chin. Chem. Soc., 2017, 64:412-419 doi: 10.1002/jccs.2017.64.issue-4
37. [37]
  Zhang L W, Li X Y, Kang Q P, et al. Crystals, 2018, 8:173 doi: 10.3390/cryst8040173
38. [38]
  Li X Y, Kang Q P, Liu L Z, et al. Crystals, 2018, 8:43 doi: 10.3390/cryst8010043
39. [39]
  YANG Yu-Hua, HAO Jing, DONG Yin-Juan, et al. Chinese J. Inorg. Chem., 2017, 33:1280-1292 doi: 10.11862/CJIC.2017.150
40. [40]
  Hao J, Liu L Z, Dong W K, et al. J. Coord. Chem., 2017, 70:1936-1952 doi: 10.1080/00958972.2017.1324152
41. [41]
  Dong W K, Ma J C, Zhu L C, et al. New J. Chem., 2016, 40:6998-7010 doi: 10.1039/C6NJ00855K
42. [42]
  PENG Yun-Dong, WANG Fei, GAO Lei, et al. Chinese J. Inorg. Chem., 2018, 65:893-899
43. [43]
  Dong W K, Ma J C, Dong Y J, et al. Polyhedron, 2016, 115:228-235 doi: 10.1016/j.poly.2016.05.017
44. [44]
  Chen L, Dong W K, Zhang H, et al. Cryst. Growth Des., 2017, 17:3636-3648 doi: 10.1021/acs.cgd.6b01860
45. [45]
  Li L H, Dong W K, Zhang Y, et al. Appl. Organomet. Chem., 2017, 31:e3818 doi: 10.1002/aoc.v31.12
46. [46]
  Ren Z L, Hao J, Hao P, et al. Z. Naturforsch. B, 2018, 73:203-210 doi: 10.1515/znb-2017-0191
47. [47]
  Wang B J, Dong W K, Zhang Y, et al. Sens. Actuators B, 2017, 247:254-264 doi: 10.1016/j.snb.2017.02.154
48. [48]
  Hao J, Li X Y, Zhang Y, et al. Materials, 2018, 11:523 doi: 10.3390/ma11040523
49. [49]
  Wang F, Gao L, Zhao Q, et al. Spectrochim. Acta Part A, 2018, 190:111-115 doi: 10.1016/j.saa.2017.09.027
50. [50]
  Dong W K, Li X L, Wang L, et al. Sens. Actuators B, 2016, 229:370-378 doi: 10.1016/j.snb.2016.01.139
51. [51]
  Dong W K, Akogun S F, Zhang Y, et al. Sens. Actuators B, 2017, 238:723-734 doi: 10.1016/j.snb.2016.07.047
52. [52]
  Zheng S S, Dong W K, Zhang Y, et al. New J. Chem., 2017, 41:4966-4973 doi: 10.1039/C6NJ04090J
53. [53]
  Sun S S, Stern C L, Nguyen S T, et al. J. Am. Chem. Soc., 2004, 126:6314-6326 doi: 10.1021/ja037378s
54. [54]
  Sheldrick G M. Acta Crystallogr. Sect. C:Cryst. Struct. Commun., 2015, C71:3-8
55. [55]
  Yu B, Sun Y X, Yang C J, et al. Z. Anorg. Allg. Chem., 2017, 643:689-698 doi: 10.1002/zaac.v643.11
56. [56]
  GUO Jian-Qian, SUN Yin-Xia, YU Bing, et al. Chinese J. Inorg. Chem., 2017, 33:1481-1488 doi: 10.11862/CJIC.2017.181
57. [57]
  Li J, Zhang H J, Chang J, et al. Crystals, 2018, 8:176 doi: 10.3390/cryst8040176
58. [58]
  ZHANG Hong-Jia, CHANG Jian, JIA Hao-Ran, et al. Chinese J. Inorg. Chem., 2018, 34:2261-2270 doi: 10.11862/CJIC.2018.261
59. [59]
  CHANG Jian, ZHANG Hong-Jia, JIA Hao-Ran, et al. Chinese J. Inorg. Chem., 2018, 34:2097-2107 doi: 10.11862/CJIC.2018.256
60. [60]
  Zhang L W, Liu L Z, Wang F, et al. Molecules, 2018, 23:1141 doi: 10.3390/molecules23051141
61. [61]
  Zhang H, Dong W K, Zhang Y, et al. Polyhedron, 2017, 133:279-293 doi: 10.1016/j.poly.2017.05.051
62. [62]
  Zhao Q, Wei Z L, Kang Q P, et al. Spectrochim. Acta Part A, 2018, 203:472-480 doi: 10.1016/j.saa.2018.06.007
63. [63]
  Wang F, Liu L Z, Gao L, et al. Spectrochim. Acta Part A, 2018, 203:56-64 doi: 10.1016/j.saa.2018.05.088
64. [64]
  Gao L, Liu C, Wang F, et al. Crystals, 2018, 8:77 doi: 10.3390/cryst8020077
65. [65]
  WANG Li, KANG Quan-Peng, HAO Jing, et al. Chinese J. Inorg. Chem., 2018, 65:893-899
66. [66]
  Dong X Y, Kang Q P, Li X Y, et al. Crystals, 2018, 8:139 doi: 10.3390/cryst8030139
67. [67]
  Kang Q P, Li X Y, Zhao Q, et al. Appl. Organomet. Chem., 2018, 32:e4379 doi: 10.1002/aoc.v32.7
68. [68]
  McKinnon J J, Jayatilaka D, Spackman M A. Chem. Commun., 2007:3814-3816
69. [69]
  Martin A D, Hartlieb K J, Sobolev A N, et al. Cryst. Growth Des., 2010, 10:5302-5306 doi: 10.1021/cg1011605
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