Citation: LIANG Chu-Xin, LIU Zheng, LIANG Qiu-Qun, TANG Qun, LI Hai-Ying, HUANG He-Xiang, ZHANG Shu-Fen. Syntheses, Crystal Structures and Properties of Bis-Schiff Bases Containing Carboxyl and Their Copper(Ⅱ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1130-1138. doi: 10.11862/CJIC.2019.154 shu

Syntheses, Crystal Structures and Properties of Bis-Schiff Bases Containing Carboxyl and Their Copper(Ⅱ) Complexes

1.
College of Chemical and Biological Engineering, Guilin University of Technology, Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, Guilin, Guangxi 541004, China
2.
Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: LIU Zheng, lisa4.6@163.com TANG Qun, tangq@glut.edu.cn
Received Date: 8 October 2018
Revised Date: 24 April 2019

Figures(7)

Based on o-carboxybenzaldehyde-1, 3-diaminopropane bis-Schiff base (L1) and o-carboxybenzaldehyde-ethylenediamine bis-Schiff base (L2), two copper(Ⅱ) complexes, namely[Cu(L1)(CH₃OH)] (1) and[Cu₂(L)₂]·2H₂O·CH₃OH (2), have been prepared by solvothermal synthesis method, where methyl phthalate ethylenediamine bis-Schiff base (L) was formed by the addition reaction of ligand L2 with methanol. The crystal structure of ligand L2 and complex 1, 2 was characterized by X-ray single crystal diffraction. The structural analysis indicates that L2 is o-carboxybenzaldehyde ethylenediamine bis-Schiff base ligand, which belongs to monoclinic system, I2/a space group. Complex 1 belongs to the orthorhombic system, Pbca space group, and Cu(Ⅱ) is coordinated with the bis-Schiff base ligand L1 and a methanol molecule to form a penta-coordinated tetragonal[CuO₃N₂] configuration. Complex 2 belongs to the triclinic system, P1 space group, and Cu(Ⅱ) is coordinated with two nitrogen atoms and three oxygen atoms of the ligand L to form a penta-coordinated twisted triangular bipyramid[CuO₃N₂] configuration, and the di-nuclear copper structure is formed by bridging a carboxyl oxygen atom. Complexes 1, 2 both have a 3D structure construed by highly stable hydrogen bonds. The structure characterization and properties of ligands L1, L2 and complexes 1, 2 were studied by IR, elemental analyses, UV, fluorescence and thermogravimetry. The results indicate that bis-Schiff base L1, L2 and complexes 1, 2 have good fluorescence properties and thermal stability. Moreover, complexes 1 and 2 showed strong fluorescence emission at 327 and 323 nm, respectively.
- Schiff base,
- copper complex,
- crystal structure,
- fluorescence property,
- thermal stability
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沈阳化工大学材料科学与工程学院沈阳 110142