Citation: WANG Yi, SHEN Qian-Qian, GUAN Rong-Feng, ZHAO Bin, XUE Jin-Bo, JIA Hu-Sheng, XU Bing-She. Application and Mechanism of PVA in Improving Photocatalytic Activity and Photo-Corrosion Resistance of TiO₂/CdSe Heterojunction[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1221-1229. doi: 10.11862/CJIC.2019.153 shu

Application and Mechanism of PVA in Improving Photocatalytic Activity and Photo-Corrosion Resistance of TiO₂/CdSe Heterojunction

WANG Yi ^1,2 ,
SHEN Qian-Qian ¹ ,
GUAN Rong-Feng ³ ,
ZHAO Bin ^1,4 ,
XUE Jin-Bo ^1,, ,
JIA Hu-Sheng ^1,2,, ,
XU Bing-She ¹

1.
Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China
2.
College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
3.
Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China
4.
State Key Laboratory of Fluid Power and Mechatronic Systems, Zhejiang University, Hangzhou 310027, China

Corresponding author: XUE Jin-Bo, xuejinbo@tyut.edu.cn JIA Hu-Sheng, jia_husheng@126.com
Received Date: 2 March 2019
Revised Date: 25 April 2019

Figures(12)

TiO₂/CdSe heterojunction was synthesized by anodic oxidation method and electrochemical deposition method. Then dehydrated polyvinyl alcohol films were spin coated on TiO₂/CdSe films with the annealing process. The crystal structure, morphology, photoelectrochemical and photocatlytic properties of the samples were investigated by XRD, SEM, FTIR, UV-Vis, PL, electrochemical and rhodamine B (RhB) degradation test. The photo-corrosion resistance of the nanocomposites were also evaluated by measuring the concentration of Cd²⁺ produced in the RhB degradation process. The results show that TiO₂/CdSe/PVA nanocomposites possess more excellent photocatalytic activity and good stability and photo-corrosion resistant properties compared to TiO₂/CdSe under visible light irradiation. Meanwhile, PVA can restrain Cd²⁺ the secondary pollutants in photocatalytic reaction.
- TiO₂/CdSe heterojunction,
- PVA,
- photocatalyst,
- photo-corrosion
1. [1]
  Fujishima A, Honda K. Nature, 1972, 238:37-38 doi: 10.1038/238037a0
2. [2]
  Chen X B, Mao S S. Chem. Rev., 2007, 7:2891-2959
3. [3]
  Diebold U. Surf. Sci. Rep., 2003, 48:53-229 doi: 10.1016/S0167-5729(02)00100-0
4. [4]
  Qin W P, Zhang D S, Zhao D, et al. Chem. Commun., 2010, 46:2304-2306 doi: 10.1039/b924052g
5. [5]
  LI Yue-Jun, CAO Tie-Ping, MEI Ze-Min, et al. Chinese J. Inorg. Chem., 2019, 35(1):82-88
6. [6]
  O Regan B, Grtzel M. Nature, 1991, 353:737740
7. [7]
  Macák J M, Tsuchiya H, Ghicov A, et al. Electrochem. Commun., 2005, 7:1133-1137 doi: 10.1016/j.elecom.2005.08.013
8. [8]
  LIU Bing, FU Rong-Rong, GAO Shan-Min, et al. Chinese J. Inorg. Chem., 2016, 32(2):223-232
9. [9]
  GUO Lei, CAI Xiao-Jing, CHEN Li, et al. Chinese J. Inorg. Chem., 2007, 23(9):1577-1581 doi: 10.3321/j.issn:1001-4861.2007.09.014
10. [10]
  CUI En-Tian, LÜ Gong-Xuan. Chinese J. Inorg. Chem., 2010, 26(12):2143-2149
11. [11]
  Meissner D, Memming R, Kastening B. J. Phys. Chem., 1988, 92:3476-3483 doi: 10.1021/j100323a032
12. [12]
  Van Dijken A, Janssen A H, Smitsmans M H P, et al. Chem. Mater., 1998, 10:3513-3522 doi: 10.1021/cm980715p
13. [13]
  Boonserm A, Kruehong C, Seithtanabutara V, et al. Appl. Surf. Sci., 2017, 419:933-941 doi: 10.1016/j.apsusc.2017.05.093
14. [14]
  Xian J J, Li D Z, Chen J, et al. ACS Appl. Mater. Interfaces, 2014, 6:13157-13166 doi: 10.1021/am5029999
15. [15]
  Yan T J, Tian J, Guan W F, et al. Appl. Catal. B, 2017, 202:84-94 doi: 10.1016/j.apcatb.2016.09.017
16. [16]
  Zhen W L, Ning X F, Yang B J, et al. Appl. Catal. B, 2018, 221:243-257 doi: 10.1016/j.apcatb.2017.09.024
17. [17]
  Zhang H, Zhu Y F. J. Phys. Chem. C, 2010, 114:5822-5826 doi: 10.1021/jp910930t
18. [18]
  Liu L, Ding L, Liu Y G. Appl. Catal. B, 2017, 201:92-104 doi: 10.1016/j.apcatb.2016.08.005
19. [19]
  Wang C, Hu Z Y, Zhao H, et al. J. Colloid Interface Sci., 2018, 521:1-10 doi: 10.1016/j.jcis.2018.02.072
20. [20]
  Ning X F, Zhen W L, Wu Y Q, et al. Appl. Catal. B, 2018, 226:373-383 doi: 10.1016/j.apcatb.2017.12.067
21. [21]
  Ning X F, Li J, Yang B J, et al. Appl. Catal. B, 2017, 212:129-139 doi: 10.1016/j.apcatb.2017.04.074
22. [22]
  Zhen W L, Ning X F, Yang B J, et al. Appl. Catal. B, 2018, 221:243-257 doi: 10.1016/j.apcatb.2017.09.024
23. [23]
  Wang D S, Bao C, Luo Q Z, et al. J. Environ. Chem. Eng., 2015, 3:1578-1585 doi: 10.1016/j.jece.2015.05.013
24. [24]
  Muktha B, Madras G, Guru Row T N, et al. J. Phys. Chem. B, 2007, 111:7994-7998 doi: 10.1021/jp071096n
25. [25]
  Wang D S, Sun H T, Luo Q Z, et al. J. Mater. Sci., 2012, 47:2136-2145 doi: 10.1007/s10853-011-6014-6
26. [26]
  Prosanov I Y. Phys. Solid State, 2011, 53:883-886 doi: 10.1134/S1063783411040299
27. [27]
  Serpone N, Texier I, Emeline A V, et al. J. Photochem. Photobiol. A, 2000, 136(3):145-155 doi: 10.1016/S1010-6030(00)00348-8
28. [28]
  Zhao Y, Eley C, Hu J P, et al. Angew. Chem. Int. Ed., 2012, 51:3846-3849 doi: 10.1002/anie.v51.16
29. [29]
  Bezrodna T, Puchkovska G, Shymanovska V, et al. J. Mol. Struct., 2004, 700:175-181 doi: 10.1016/j.molstruc.2003.12.057
30. [30]
  Su W G, Zhang J, Feng Z C, et al. J. Phys. Chem. C, 2008, 112:7710-7716 doi: 10.1021/jp7118422
31. [31]
  Stern M, Geary A L. J. Electrochem. Soc., 1957, 104:56-63 doi: 10.1149/1.2428496
32. [32]
  Chang C H, Huang T C, Peng C W. Carbon, 2012, 50:5044-5051 doi: 10.1016/j.carbon.2012.06.043
1. [1]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
2. [2]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
3. [3]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
4. [4]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
5. [5]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
6. [6]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
7. [7]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
8. [8]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
9. [9]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
10. [10]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
11. [11]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
12. [12]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
13. [13]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
14. [14]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
15. [15]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
16. [16]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
17. [17]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
18. [18]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
19. [19]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
20. [20]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(838)
HTML views(143)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Application and Mechanism of PVA in Improving Photocatalytic Activity and Photo-Corrosion Resistance of TiO2/CdSe Heterojunction

Metrics

通讯作者: 陈斌, bchen63@163.com

Application and Mechanism of PVA in Improving Photocatalytic Activity and Photo-Corrosion Resistance of TiO₂/CdSe Heterojunction